Abstract
The effect of external pressure on the fluorescence spectra of perylene in n-octane at helium temperatures is investigated. It is shown that isobaric treatment of the sample considerably decreases the electronphonon interaction of the impurity molecules with the surroundings and gives rise to doublet structure of the spectra. The latter is explained in terms of the two-well adiabatic potential model
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. I. Personov, in:Selective Spectroscopy of Complex Molecules in Solutions and Its Applications. Spectroscopy and Dynamics of Excitations in Condensed Molecular Systems [in Russian], V. Agranovich and R. Hochstrasser (eds.), Nauka, Moscow (1987), p. 341.
I. S. Osad’ko, in:Advances in Polymer Science,114, 123 (1994).
O. N. Korotaev, I. P. Kolmakov, M. F. Shchanov, et al.,Pisma Zh. éksp. Teor. Fiz.,55, No. 7, 417–419 (1992).
O. N. Korotaev, M. F. Shchanov, V. P. Karpov, and I. P. Kolmakov,ibid,58, No. 9, 715–717 (1993).
U. Bogner, T. Attenberger, and R. Bauer,Spectral Hole-Burning and Luminescence Line Narrowing. Technical Digests, 22, 22–25 (1992).
T. B. Tamm, Ya. V. Kikas, and A. é. Sirk,Zh. Prikl. Spektrosk.,24, No. 2, 315–321 (1976).
Author information
Authors and Affiliations
Additional information
Translated fromZhumal Struktumoi Khimii, Vol. 38, No. 2, pp. 318–323, March–April, 1997.
Rights and permissions
About this article
Cite this article
Balashov, S.N., Ivanov, I.E., Karpov, V.P. et al. Pressure effect in the vibronic spectra of perylene inn-Octane. J Struct Chem 38, 257–261 (1997). https://doi.org/10.1007/BF02762654
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02762654