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Adsorption of lead, ethylenediaminetetraacetic acid and lead-ethylenediaminetetraacetic acid complex onto granular activated carbon

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Abstract

This study investigated simultaneous removal of lead and ethylenediaminetetraacetic acid from synthetic wastewater samples using granular activated carbon adsorption. Data from a 1 × 10−4 M lead-ethylenediaminetetraacetic acid adsorption isotherm study fitted well to Freundlich isotherm. Furthermore, for the pH-dependent 1 × 10−4 M lead-ethylenediaminetetraacetic acid study both lead and ethylenediaminetetraacetic acid adsorptions increased reaching values of 82 % and 93 % respectively at pH 5.8. However, a further increase in pH resulted in decreasing but near equal lead and ethylenediaminetetraacetic acid removals. Results for the 2 × 10−4 M lead-ethylenediaminetetraacetic acid system showed a behavior that was qualitatively similar to the 1 × 10−4 M lead-ethylenediaminetetraacetic acid findings. However, the 1×10−3 M lead-ethylenediaminetetraacetic acid study showed only a decreasing adsorption trend. An increasing-decreasing type lead/ethylenediaminetetraacetic acid adsorption behavior was also noted for the 1× 10−4 M lead/2 × 10−4 M ethylenediaminetetraacetic acid system. Nevertheless for the 2×10−4 M lead/1×10−4 M ethylenediaminetetraacetic acid system, lead removal at increased pH was comparatively higher. Furthermore, results from a continuous column study completed at 1 × 10−4 M lead and 0.75 × 10−4 M ethylenediaminetetraacetic acid showed high saturation times both for lead and ethylenediaminetetraacetic acid. Results from the present work show that a notable removal of aqueous phase lead and ethylenediaminetetraacetic acid could be achieved using activated carbon adsorption. The details related to the effect of pH and pollutants’ concentration on the overall adsorption efficiency, as reported in the present work, would be of much use for an effective carbon adsorption process design for the treatment of respective wastewaters.

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References

  • Abdel-Ghani, N. T.; Elchaghaby, G. A., (2007). Influence of operating conditions on the removal of Cu, Zn, Cd and Pb ions from wastewater by adsorption. Int. J. Environ. Sci. Tech., 4(4), 451–456 (6 pages).

    Article  CAS  Google Scholar 

  • Abdel-Ghani, N. T.; Hegazy, A. K.; El-Chaghaby, G. A., (2009). Typha domingensis leaf powder for decontamination of aluminium, iron, zinc and lead: Biosorption kinetics and equilibrium modeling. Int. J. Environ. Sci. Tech., 6(2), 243–248 (6 pages).

    CAS  Google Scholar 

  • Abdulkarim, M.; Abu Al-Rub, F., (2004). Adsorption of lead ions from aqueous solution onto activated carbon and chemically-modified activated carbon prepared from date pits. Adsorp. Sci. Tech., 22(2), 119–134 (15 pages).

    Article  CAS  Google Scholar 

  • Aghamohammadi, N.; Hamidi, A. A.; Hasnain, I. M.; Zinatizadeh, A. A.; Nasrollahzadeh Saravi, H.; Ghafari, Sh., (2007). Performance of a powdered activated carbon (PAC) augmented activated sludge process treating semi-aerobic leachate. Int. J. Environ. Res., 1(2), 96–103 (8 pages).

    CAS  Google Scholar 

  • Allison, J. D.; Brown, D. S.; Novo-Gradac, K. J., (1991). MINTEQA2/PRODEFA2, A Geochemical Assessment Model for Environmental Systems, Version 3.0 User’s Manual, U.S. Environmental Protection Agency, EPA/600/3-91/021, Athens, Georgia.

  • Amrate, S.; Akretche, D. E.; Innocent, C.; Seta, P., (2006). Use of cation-exchange membranes for simultaneous recovery of lead and EDTA during electrokinetic extraction. Desalination, 193(1–3), 405–410 (6 pages).

    Article  CAS  Google Scholar 

  • Aroua, M. K.; Yin, C. Y.; Lim, F. N.; Kan, W. L.; Daud, W. M. A. W., (2009). Effect of impregnation of activated carbon with chelating polymer on adsorption kinetics of Pb2+. J. Hazard. Mater., 166(2–3), 1526–1529 (4 pages).

    Article  CAS  Google Scholar 

  • Awwad, N. S.; Daifuallah, A. A. M.; Ali, M. M. S., (2008). Removal of Pb2+, Cd2+, Fe3+, and Sr2+ from aqueous solution by selected activated carbons derived from date pits. Solvent Extr. Ion Exc., 26(6), 764–782 (19 pages).

    Article  CAS  Google Scholar 

  • Bargar, J. R.; Persson, P.; Brown, G. E. Jr., (1999). Outer-sphere adsorption of Pb(II)EDTA on goethite. Geochim. Cosmochim. Ac., 63(19–20), 2957–2969 (13 pages).

    Article  CAS  Google Scholar 

  • Barton, S. S.; Evans, M. J. B.; Halliop, E.; MacDonald, J. A. F., (1997). Acidic and basic sites on the surface of porous carbon. Carbon, 35(9), 1361–1366 (6 pages).

    Article  CAS  Google Scholar 

  • Chen, J. P.; Wang, X., (2000). Removing copper, zinc, and lead ion by granular activated carbon in pretreated fixed-bed columns. Separ. Purif. Tech., 19(3), 157–167 (11 pages).

    Article  CAS  Google Scholar 

  • Chen, J. P.; Wu, S., (2004). Simultaneous adsorption of copper ions and humic acid onto an activated carbon. J. Coll. Inter.Sci., 280(2), 334–342 (9 pages).

    Article  CAS  Google Scholar 

  • Corapcioglu, M. O.; Huang, C. P., (1987). The surface acidity and characterization of some commercial activated carbons. Carbon, 25(4), 569–578 (10 pages).

    Article  CAS  Google Scholar 

  • Dudzinska, M. R.; Clifford, D. A., (1992). Anion exchange studies of lead-EDTA complexes. React.Polymer., 16(1), 71–80 (10 pages).

    Article  Google Scholar 

  • Faur-Brasquet, C.; Kadirvelu, K.; Le Cloirec, P., (2002). Removal of metal ions from aqueous solution by adsorption onto activated carbon cloths: Adsorption competition with organic matter. Carbon, 40(13), 2387–2392 (6 pages).

    Article  CAS  Google Scholar 

  • Gaur, N.; Dhankhar, R., (2009). Removal of Zn+2 ions from aqueous solution using Anabaena variabilis: Equilibrium and kinetic studies. Int. J. Environ. Res., 3(4), 605–616 (12 pages).

    CAS  Google Scholar 

  • Giraldo, L.; Moreno-Piraján, J. C., (2008). Pb2+ adsorption from aqueous solutions on activated carbons obtained from lignocellulosic residues. Brazil. J. Chem. Eng., 25(1), 143–151 (9 pages).

    Article  CAS  Google Scholar 

  • Goel, J.; Kadirvelu, K.; Rajagopal, C.; Garg, V. K., (2005). Investigation of adsorption of lead, mercury and nickel from aqueous solutions onto carbon aerogel. Journal of Chemical Technology and Biotechnology, 80(4), 469–476 (8 pages).

    Article  CAS  Google Scholar 

  • Gueu, S.; Yao, B.; Adouby, K.; Ado, G., (2007). Kinetics and thermodynamics study of lead adsorption on to activated carbons from coconut and seed hull of the palm tree. Int. J. Environ. Sci. Tech., 4(1), 11–17 (7 pages).

    Article  CAS  Google Scholar 

  • Igbinosa, E. O.; Okoh, A. I., (2009). Impact of discharge wastewater effluents on the physico-chemical qualities of a receiving watershed in a typical rural community. Int. J. Environ. Sci. Tech., 6(2), 175–182 (8 pages).

    CAS  Google Scholar 

  • Issabayeva, G.; Aroua, M. K.; Sulaiman, N. M. N., (2006). Removal of lead from aqueous solutions on palm shell activated carbon. Bioresour. Tech., 97(18), 2350–2355 (6 pages).

    Article  CAS  Google Scholar 

  • Jiraroj, D.; Unob, F.; Hagége, A., (2006). Degradation of Pb-EDTA complex by a H2O2/UV process. Water Res., 40(1), 107–112 (6 pages).

    Article  CAS  Google Scholar 

  • Juang, R. S.; Wang, S. W.; Lin, L. C., (1999). Simultaneous recovery of EDTA and lead(II) from their chelated solutions using a cation exchange membrane. J. Membr. Sci., 160(2), 225–233 (9 pages).

    Article  CAS  Google Scholar 

  • Kadirvelu, K.; Faur-Brasquet, C.; Le Cloirec, P., (2000). Removal of Cu(II), Pb(II), and Ni(II) by adsorption onto activated carbon cloths. Langmuir, 16(22), 8404–8409 (6 pages).

    Article  CAS  Google Scholar 

  • Kim, C.; Ong, S. K., (1999). Recycling of lead-contaminated EDTA wastewater. J. Hazard. Mater., 69(3), 273–286 (14 pages).

    Article  CAS  Google Scholar 

  • Kolodynska, D.; Skwarek, E.; Hubicki, Z.; Janusz, W., (2009). Effect of adsorption of Pb(II) and Cd(II) ions in the presence of EDTA on the characteristics of electrical double layers at the ion exchanger/NaCl electrolyte solution interface. J. Coll. Inter. Sci., 333(2), 448–456 (9 pages).

    Article  CAS  Google Scholar 

  • Krishnan, K. A.; Sheela, A.; Anirudhan, T., (2003). Adsorption of lead and lead chelates on activated carbons. J. Chem. Tech. Biotech., 78(6), 642–653 (12 pages).

    Article  CAS  Google Scholar 

  • Li, Y.-H.; Di, Z.; Ding, J.; Wu, D.; Luan, Z.; Zhu, Y., (2005). Adsorption thermodynamic, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Res., 39(4), 605–609 (5 pages).

    Article  CAS  Google Scholar 

  • Malakootian, M.; Nouri, J.; Hossaini, H., (2009). Removal of heavy metals from paint industries wastewater using Leca as an available adsorbent. Int. J. Environ. Sci. Tech., 6(2), 183–190 (7 pages).

    CAS  Google Scholar 

  • Oviedo, C.; Rodriguez, J., (2003). EDTA: The chelating agent under environmental scrutiny. Quim. Nova, 26(6), 901–905 (5 pages).

    Article  CAS  Google Scholar 

  • Palacios, H.; Iribarren, I.; Olalla, M. J.; Cala, V., (2002). Lead poisoning of horses in the vicinity of a battery recycling plant. Sci. Total Environ., 290(1–3), 81–89 (9 pages).

    Article  CAS  Google Scholar 

  • Reed, B. E.; Arunachalam, S., (1994). Use of granular activated carbon for lead removal. J.Environ. Eng., 120(2), 416–436 (21 pages).

    Article  CAS  Google Scholar 

  • Reed, B. E.; Arunachalam, S.; Thomas, B., (1994). Removal of lead and cadmium from aqueous waste streams using granular activated carbon (GAC) columns. Environ. Prog., 13(1), 60–64 (5 pages).

    CAS  Google Scholar 

  • Riley, R. G.; Zachara, J. M.; Wobber, F. J., (1992). Chemical contaminants on DOE lands and selection of contaminated mixtures for subsurface science research, U.S. Department of Energy, DOE/ER-0547T.

  • Shah, B. A.; Shah, A. V.; Singh R. R., (2009). Sorption isotherms and kinetics of chromium uptake from wastewater using natural sorbent material. Int. J. Environ. Sci. Tech., 6(1), 77–90 (14 pages).

    Article  CAS  Google Scholar 

  • Sreejalekshmi, K. G.; Anoop Krishnan, K.; Anirudhan, T. S., (2009). Adsorption of Pb(II) and Pb(II)-citric acid on sawdust activated carbon: Kinetic and equilibrium isotherm studies. J. Hazard. Mater., 161(2–3), 1506–1513 (8 pages).

    Article  CAS  Google Scholar 

  • Swanson, J. L., (1984). Organic complexant-enhanced mobility of toxic elements in low-level wastes, Pacific Northwest Lab., PNL-SA-12518, Washington.

    Book  Google Scholar 

  • Swanson, J. L., (1985). Organic complexant-enhanced mobility of toxic elements in low-level wastes, Pacific Northwest Lab., PNL-4965-8, Washington.

    Google Scholar 

  • Taylor, R. M.; Kuennen, R. W., (1994). Removing lead in drinking water with activated carbon. Environ. Prog., 13(1), 65–71 (7 pages).

    CAS  Google Scholar 

  • Vohra, M. S.; Davis, A. P., (1998). Adsorption of Pb(II), EDTA, and Pb(II)-EDTA onto TiO2. J. Coll. Intere Sci., 198, 18–26 (9 pages).

    Article  CAS  Google Scholar 

  • Vohra, M. S.; Davis, A. P., (2000). TiO2-assisted photocatalysis of lead-EDTA. Water Res., 34(3), 952–964 (13 pages).

    Article  CAS  Google Scholar 

  • Xia, W.; Gao, H.; Wang, X.; Zhou, C.; Liu, Y.; Fan, T.; Wang, X., (2009). Application of EDTA decontamination on soils affected by mining activities and impact of treatment on the geochemical partition of metal contaminants. J. Hazard. Mater., 164(2–3), 936–940 (5 pages).

    Article  CAS  Google Scholar 

  • Zhang, K.; Cheung, W. H.; Valix, M., (2005). Roles of physical and chemical properties of activated carbon in the adsorption of lead ions. Chemosphere, 60(8), 1129–1140 (12 pages).

    Article  CAS  Google Scholar 

  • Zhu, J.; Yang, J.; Deng, B., (2009). Ethylenediamine-modified activated carbon for aqueous lead adsorption. Environ. Chem. Lett., 12(2), 113–117 (5 pages).

    Google Scholar 

  • Zvinowanda, C. M.; Okonkwo, J. O.; Shabalala, P. N.; Agyei, N.M., (2009). A novel ad’sorbent for heavy metal remediation in aqueous environments. Int. J. Environ. Sci. Tech. 6(3), 425–434 (10 pages).

    Article  CAS  Google Scholar 

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  1. Environmental Engineering Program, Civil Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Kingdom of Saudi Arabia

    M. S. Vohra Ph.D. (Assistant Professor)

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  1. M. S. Vohra Ph.D.
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Vohra, M.S. Adsorption of lead, ethylenediaminetetraacetic acid and lead-ethylenediaminetetraacetic acid complex onto granular activated carbon. Int. J. Environ. Sci. Technol. 7, 687–696 (2010). https://doi.org/10.1007/BF03326178

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