Abstract
The kinetics of cellular precipitation at the grain boundaries in a Cu-3 w/o Ti alloy was investigated using the Johnson–Mehl–Avrami (JMA) model. The experimental results are well described by Cahn’s site saturation model, showing that the initiation of cellular colony precipitation is limited by the availability of the nucleation sites. Orientation imaging microscopy (OIM) and transmission electron microscopy (TEM) analyses show that not all high angle grain boundaries contain preferred nucleation sites. It was observed that grain boundaries in aged alloys that do not have cellular colonies tend to have a special coincident site lattice (CSL) relationship.
Similar content being viewed by others
References
Matsuoka S, Mangan MA, Shiflet GJ (1994) In: Johnson WC (ed) Solid–solid phase transformations. The Minerals, Metals and Materials Society, Warrendale, PA, p 521
Vaughan D (1968) Acta Metall 16:563
Hornbogen E (1972) Met Trans 3:2717
Manna I, Pabi SK, Gust W (1991) J Mater Sci 26:4888. doi:https://doi.org/10.1007/BF00549866
Porter DA, Easterling KE (1992) Phase transformation in metals and alloys. Chapman and Hall, New York
Christian JW (1975) The theory of transformations in metals and alloys: part I, equilibrium and general kinetic theory. Pergamon Press, New York
Bunge HJ (1982) Texture analysis in materials science. Butterworths, London
Cahn JW (1956) Acta Metall 4:449
Mackenzie K (1958) Biometrika 45:229
Adams BL, Zhao J, Grimmer H (1990) Acta Cyrst A 46(7):620
Brandon D (1966) Acta Metall 14:1479
Butler EP, Swann PR (1976) Acta Metall 24:343
Unwin PNT, Nicholson RB (1969) Acta Metall 17:1379
Acknowledgements
NB thanks the Office of the Civil Service Commission, Bangkok, Thailand for partial support during the performance of the research. We also thank the U.S. Department of Energy and the University of California, Lawrence Livermore National Laboratory under Contract No. W-7405-Eng-48 for partial financial support during the fiscal year 2007.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Boonyachut, N., Laughlin, D.E. Influence of boundary structure on cellular nucleation in Cu-3 w/oTi age-hardening alloys. J Mater Sci 44, 449–456 (2009). https://doi.org/10.1007/s10853-008-3073-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-008-3073-4