Abstract
Supramolecular compounds [Mn(H2O)4(C36H36N24O12)]2[Re4Te4(CN)12]·12.5H2O (1), (H3O)2[{Mn(H2O)4 (C36H36N24O12)}{Mn(H2O)4} 2{Re4Te4(CN)12}2]·3.5H2O (2) and [{Mn(H2O)3Cl} 2(C36H36N24O12)]Cl2·6H2O (3) were obtained by crystallization at room temperature from water solutions containing macrocyclic cavitand cucurbituryl (C36H36N24O12), aqua complex of manganese(II) (1–3) and chalcocyanide cluster complex [Re4Te4(CN)12]4− (1, 2). From XRD analysis, the cucurbituryl molecule is bound with one (1, 2) or two atoms of manganese (3) through oxygen atoms of carbonyl groups. Compound 2 has a chain structure where cluster complexes of rhenium are linked through bridge manganese atoms into a polymeric ribbon. Compounds 1 and 3 have the island-like type of structure.
Similar content being viewed by others
References
D. G. Samsonenko, O. A. Geras’ko, and V. P. Fedin, Usp. Khim., No. 9, 841–860 (2002).
Y. M. Jeon, J. Kim, D. Whang, and K. Kim, J. Am. Chem. Soc., 118, 9790/9791 (1996).
D. Whang, J. Heo, J. H. Park, and K. Kim, Angew. Chem. Int. Ed., 37, 78–80 (1998).
J. Heo, S.-Y. Kim, D. Whang, and K. Kim, ibid., 38, 641–643 (1999).
J. Heo, J. Kim, D. Whang, and K. Kim, Inorg. Chim. Acta., 297, 307–312 (2000).
W. A. Freeman, W. L. Mock, and N.-Y. Shih, J. Am. Chem. Soc., 103, 7367/7368 (1981).
W. A. Freeman, Acta Crystallogr., B40, 382–387 (1984).
D. G. Samsonenko, A. A. Sharapova, M. N. Sokolov, et al., Koordinats. Khim., 27, No. 1, 12–17 (2001).
O. A. Geras’ko, A. V. Viriovets, D. G. Samsonenko, et al., Izv. Ross. Akad. Nauk, Ser. Khim., No. 3, 562–569 (2003).
D. G. Samsonenko, J. Lipkowski, O. A. Gerasko, et al., Eur. J. Inorg. Chem., No. 9, 2380–2388 (2002).
D. G. Samsonenko, O. A. Geras’ko, Ya. Lipkovski, et al., Izv. Ross. Akad. Nauk, Ser. Khim., No. 10, 1763–1765 (2002).
D. G. Samsonenko, M. N. Sokolov, O. A. Geras’ko, A. V. Virovets, et al., ibid., 2020–2027 (2003).
D. G. Samsonenko, M. N. Sokolov, A. V. Virovets, et al., Eur. J. Inorg. Chem., No. 1, 167–172 (2001).
D. G. Samsonenko, O. A. Geras’ko, T. V. Mit’kina, et al., Koordinats. Khim., 29, No. 3, 178–186 (2003).
P. Cintas, J. Inclus. Phenom., 17, 205–220 (1994).
W. L. Mock, in: Comprehensive Supramolecular Chemistry., V. 2., F. Vögtle (ed.), Pergamon, Oxford (1996), pp. 477–493.
Yu. V. Mironov, A. V. Virovets, S. B. Artemkina, and V. Ye. Feforov, Zh. Strukt. Khim., 40, No. 2, 374–379 (1999).
Yu. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Inorg. Chem., 36, 944–946 (1997).
G. M. Sheldrick, XPREP Version 5.04., Siemens Analytical X-ray Instruments Inc., Madison (1995).
G. M. Sheldrick, SADABS, Absorption Corrections for Area Detector Data, Univ. Göttingen, Germany (1997).
G. M. Sheldrick, SHELX-97. Release 97-2., Univ. Göttingen, Germany (1998).
Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, et al., Eur. J. Inorg. Chem., No. 14, 2591–2595 (2003).
Yu. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers, Z. Kristallogr., 212, 308 (1997).
Yu. V. Mironov and V. E. Fedorov, Izv. Ross. Akad. Nauk, Ser. Khim., No. 4, 529–539 (2002).
Yu. V. Mironov, A. V. Virovets, W. S. Sheldrick, and V. E. Fedorov, Polyhedron., 20, 969–974 (2001).
F. H. Allen, Acta Crystallogr., B58, 380–388 (2002).
D. G. Samsonenko, Synthesis and Structure of Supramolecular Compounds of Cucurbituryl with Mono-and Polynuclear Aqua Complexes of Metals [in Russian], Candidate of Chemistry Dissertation, Institute of Inorganic Chemistry, Novosibirsk (2002).
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by D. G. Samsonenko, Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, O. A. Gerasko, V. P. Fedin, V. E. Fedorov, and W. S. Sheldrick
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, Supplement, pp. S119–S126, 2005.
Rights and permissions
About this article
Cite this article
Samsonenko, D.G., Mironov, Y.V., Efremova, O.A. et al. Synthesis and crystal structure of supramolecular compounds of cucurbituryl with the chalcocyanide cluster complex [Re4Te4(CN)12]4− and a manganese(II) aqua complex. J Struct Chem 46 (Suppl 1), S121–S129 (2005). https://doi.org/10.1007/s10947-006-0162-6
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-006-0162-6