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Synthesis and crystal structure of the octahedral cyano-bridged cluster complex β-[{Ni(NH3)5}2{Re6Te8(CN)6}]·4H2O

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Abstract

The rhenium cyano-bridged cluster complex with a composition of β-[{Ni(NH3)5}2{Re6Te8(CN)6}]−4H2O is obtained and structurally characterized. The compound pound crystallizes in the P \( P\bar 1 \) triclinic space group with the unit cell parameters: a = 9.997(2) Å, b = 10.423(2) Å, c = 11.714(2) Å, α = 100.92(3)°, β = 111.87(3)°, γ = 98.05(3)°, V = 1082.1(4) Å3, Z = 1, d calc = 4.072 g/cm3. The rhenium atoms of the {Re6Te8} cluster core are coordinated by CN ligands to form the [Re6Te8(CN)6]4− cluster; two nitrogen atoms of CN ligands trans-positioned with respect to each other are coordinated to Ni atoms in the {Ni(NH3)5}2+ fragments to form the molecular complexes of [{Ni(NH3)5}2}Re6Te8(CN)6}]. The crystal structure is the H-bonded packing of these molecular complexes and crystallization water molecules.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    K. A. Brylev, Yu. V. Mironov & V. E. Fedorov

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  1. K. A. Brylev
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  2. Yu. V. Mironov
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  3. V. E. Fedorov
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Correspondence to K. A. Brylev.

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Original Russian Text Copyright © 2009 by K. A. Brylev, Yu. V. Mironov, and V. E. Fedorov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 6, pp. 1249–1252, November–December, 2009.

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Brylev, K.A., Mironov, Y.V. & Fedorov, V.E. Synthesis and crystal structure of the octahedral cyano-bridged cluster complex β-[{Ni(NH3)5}2{Re6Te8(CN)6}]·4H2O. J Struct Chem 50, 1197–1200 (2009). https://doi.org/10.1007/s10947-009-0178-9

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  • DOI: https://doi.org/10.1007/s10947-009-0178-9

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