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A selective colorimetric and fluorescence chemosensing sensor for Cr3+ based on a rhodamine base derivative

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Abstract

A rhodamine-conjugated coumarin (L) was used in designing a selective fluorescence chemosensor for the determination of trace amounts of Cr3+ ions in acetonitrile–water (MeCN/H2O (90:10, %v/v) solutions. The intensity of the fluoresce emission of the chemosensor is intensified upon addition of Cr3+ ions in MeCN/H2O (90:10, %v/v) solutions, due to the formation of a selective 1:1 complex between L and Cr3+ ions. The fluorescence enhancement versus Cr3+ concentration has been found to be linear from 1.0 × 10−7 to 1.8 × 10−5 M and a detection limit of 7.5 × 10−8 M. The proposed fluorescent probe proved to be highly selective towards Cr3+ ions as compared to other common metal ions and could be successfully applied to the determination of Cr3+ concentrations in some water and wastewater samples.

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Acknowledgements

The authors thank the research Council of University of Tehran (Grant 28645/01/02) for financial support of this work.

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Authors and Affiliations

  1. Department of Life Science Engineering, Faculty of New Sciences and Technologies, University of Tehran, Tehran, Iran

    Morteza Hosseini

  2. Department of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research Center, Tehran University of Medical Sciences, Tehran, 14176, Iran

    Mehdi Khoobi & Roghayeh Tarasi

  3. Department of Pharmaceutical Biomaterials and Medical Biomaterials Research Center, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran, Iran

    Morteza Hosseini, Mehdi Khoobi & Roghayeh Tarasi

  4. Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Mohammad Reza Ganjali

  5. Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

    Mohammad Reza Ganjali

Authors
  1. Morteza Hosseini
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  2. Mehdi Khoobi
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  4. Mohammad Reza Ganjali
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Correspondence to Morteza Hosseini.

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Hosseini, M., Khoobi, M., Tarasi, R. et al. A selective colorimetric and fluorescence chemosensing sensor for Cr3+ based on a rhodamine base derivative. Res Chem Intermed 44, 5031–5042 (2018). https://doi.org/10.1007/s11164-018-3407-z

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  • DOI: https://doi.org/10.1007/s11164-018-3407-z

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