Abstract
Methods for the syntheses of a series of high-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitroethyl derivatives of polynitrohexaazaisowurtzitanes were developed. The enthalpy of formation, molecular crystalline density, sensitivity to mechanical impact, and thermal stability were experimentally determined for two compounds.
Similar content being viewed by others
References
O. A. Luk´yanov, N. I. Shlykova, G. V. Pokhvisneva, T. V. Ternikova, S. V. Nikitin, G. A. Smirnov, Yu. V. Nelubina, P. V. Dorovatovsky, T. S. Kon´kova, N. V. Muravyev, A. N. Pivkina, Russ. Chem. Bull., 2017, 66, 1066.
E. A. Miroshnichenko, T. S. Kon´kova, Ya. O. Inozemtsev, Yu. N. Matyushin, Russ. Chem. Bull., 2010, 59, 890.
V. V. Pepekin, Yu. N. Matyushin, G. G. Rozantsev, S. A. Shevelev, A. Ya. Apin, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972, 21, 2634.
STANAG 4489, Explosives, Impact Sensitivity Tests, NATO, Brussels, 1999.
STANAG 4489, Explosives, Friction Sensitivity Tests, NATO, Brussels, 2002.
N. V. Muravyev, K. A. Monogarov, A. A. Bragin, I. V. Fomenkov, A. N. Pivkina, Thermochim. Acta, 2016, 631, 1.
G. M. Shedrick, Acta Cristallogr., 2008, A64, 112.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0110–0115, January, 2019.
Rights and permissions
About this article
Cite this article
Luk′yanov, O.A., Shlykova, N.I., Pokhvisneva, G.V. et al. High-energy 4(10)-2-fluoro-2,2-dinitroethyl and 4(10)-2,2-dinitropropyl derivatives of polynitrohexaazaisowurtzitanes. Russ Chem Bull 68, 110–115 (2019). https://doi.org/10.1007/s11172-019-2424-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-019-2424-4
Key words
- 4-(2-fluoro-2,2-dinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane
- 4-(2-fluoro-2,2-dinitroethyl)-10-(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane
- 4,10-bis(2-fluoro-2,2-dinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane
- 4-(2-fluoro-2,2- dinitroethyl)-10-(2,2-dinitropropyl)-2,6,8,12-tetranitrohexaazaisowurtzitane
- 4-(2,2-di nitropropyl)- 2,6,8,10,12-pentanitrohexaazaisowurtzitane
- 4-(2,2-dinitropropyl)-10-(2,2,2-tri nitroethyl)- 2,6,8,12-tetranitrohexaazaisowurtzitane
- 4,10-bis(2,2-dinitropropyl)-2,6,8,12-tetranitrohexaazaisowurtzitane
- enthalpy of formation
- density
- sensitivity to mechanical impact
- thermal stability