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The Influence of the Nature of Halogen on the Local Structure and Intercalation of Water in Oxyhalides Ba2InO3X (X = F, Cl, Br)

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Abstract

Oxyhalides Ba2InO3F, Ba2InO3Cl, and Ba2InO3Br are synthesized, and their phase homogeneity is confirmed by the method of X-ray diffraction. The influence of the nature of a halide ion on the crystal-lattice parameters and on the In–O bond lengths is established. The ability of the studied phases to undergo hydration and formation of oxygen–hydrogen groups in their structure is proven.

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Authors and Affiliations

  1. First President of Russia Boris Yeltsin Ural Federal University, Yekaterinburg, 620002, Russia

    N. A. Tarasova & I. E. Animitsa

Authors
  1. N. A. Tarasova
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  2. I. E. Animitsa
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Correspondence to N. A. Tarasova.

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Original Russian Text © N.A. Tarasova, I.E. Animitsa, 2018, published in Optika i Spektroskopiya, 2018, Vol. 124, No. 2, pp. 167–170.

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Tarasova, N.A., Animitsa, I.E. The Influence of the Nature of Halogen on the Local Structure and Intercalation of Water in Oxyhalides Ba2InO3X (X = F, Cl, Br). Opt. Spectrosc. 124, 163–166 (2018). https://doi.org/10.1134/S0030400X18020170

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  • DOI: https://doi.org/10.1134/S0030400X18020170

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