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Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine

  • Coordination Compounds
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Abstract

Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ⋅ H2O, [C4H8N2H4]SO3 ⋅ H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ⋅ H2O, [O(C2H4)2NH2]2SO4 ⋅ H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy.

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Author information

Authors and Affiliations

  1. Physicochemical Institute for Environment and Human Protection, National Academy of Sciences of Ukraine, Odessa, 65082, Ukraine

    R. E. Khoma & A. A. Ennan

  2. Odessa National University, Odessa, 65082, Ukraine

    R. E. Khoma & T. V. Koksharova

  3. Odessa National Medical University, Odessa, 65082, Ukraine

    V. O. Gel’mbol’dt

  4. Institute of Single Crystals, National Academy of Sciences of Ukraine, Kharkov, 61001, Ukraine

    V. N. Baumer & A. N. Puzan

  5. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, 65080, Ukraine

    A. V. Mazepa

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  1. R. E. Khoma
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  2. V. O. Gel’mbol’dt
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  3. A. A. Ennan
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  4. V. N. Baumer
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  6. T. V. Koksharova
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Correspondence to R. E. Khoma.

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Original Russian Text © R.E. Khoma, V.O. Gel’mbol’dt, A.A. Ennan, V.N. Baumer, A.N. Puzan, T.V. Koksharova, A.V. Mazepa, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 6, pp. 751–760.

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Khoma, R.E., Gel’mbol’dt, V.O., Ennan, A.A. et al. Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine. Russ. J. Inorg. Chem. 62, 736–745 (2017). https://doi.org/10.1134/S0036023617060109

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  • DOI: https://doi.org/10.1134/S0036023617060109

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