Abstract
Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional aggregates with a regular architecture, whereas the choice of alkynyl ligands determines their luminescent properties.
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Tunik, S.P., Russ. Chem. Bull., 2004, vol. 53, no. 12, p. 2657. doi https://doi.org/10.1007/s11172-005-0172-0
Farrar, D.H., Grachova, E.V., Lough, A., Patirana, C., Poë, A.J., and Tunik, S.P., J. Chem. Soc. Dalton Trans., 2001, no. 13, p., 2015. doi https://doi.org/10.1039/b010109p
Gracheva, E.V. and Linti, G., Russ. J. Gen. Chem., 2010, vol. 80, p. 414. doi https://doi.org/10.1134/S1070363210030072
Monakhov, K.Y., Grachova, E.V., Starova, G.L., Zessin, T., and Linti, G., J. Organomet. Chem., 2012, vol. 714, p. 22. doi https://doi.org/10.1016/j.jorganchem.2012.03.003
Grachova, E.V., Heaton, B.T., Iggo, J.A., Podkorytov, I.S., Smawfield, D.J., Tunik, S.P., and Whyman, R., J. Chem. Soc. Dalton Trans., 2001, no. 22, p. 3303. doi https://doi.org/10.1039/b101962g
Farrar, D.H., Grachova, E.V., Haukka, M., Heaton, B.T., Iggo, J.A., Pakkanen, T.A., Podkorytov, I.S., and Tunik, S.P., Inorg. Chim. Acta, 2003, vol. 354, p. 11. doi https://doi.org/10.1016/S0020-1693(03)00315-3
Grachova, E.V., Haukka, M., Heaton, B.T., Nordlander, E., Pakkanen, T.A., Podkorytov, I.S., and Tunik, S.P., Dalton Trans., 2003, no. 12, p. 2468. doi https://doi.org/10.1039/b211790h
Ponomarenko, V.I., Krupenya, D.V., Grachova, E.V., Gindin, V.A., Selivanov, S.I., Koshevoy, I.O., Tunik, S.P., Haukka, M., Pursiainen, J., and Pirilä, P., Z. Anorg. Allg. Chem., 2009, vol. 635, no. 15, p. 2515. doi https://doi.org/10.1002/zaac.200900259
Andreev, I.A., Grachova, E.V., Tunik, S.P., Oparina, L.A., Sukhov, B.G., Malysheva, S.F., Kinoshita, I., and Nishioka, T., Russ. Chem. Bull., 2007, vol. 56, no. 7, p. 1343. doi https://doi.org/10.1007/s11172-007-0205-y
Heaton, B.T., Grachova, E.V., Tunik, S.P., and Podkorytov, I.S., Dalton Trans., 2015, vol. 44, no. 37, p. 16611. doi https://doi.org/10.1039/c5dt01099c
Tunik, S.P., Grachova, E.V., Denisov, V.R., Starova, G.L., Nikol’skii, A.B., Dolgushin, F.M., Yanovsky, A.I., and Struchkov, Y.T., J. Organomet. Chem, 1997, vols. 536–537, p. 339. doi https://doi.org/10.1016/S0022-328X(96)06719-8
Ponomarenko, V.I., Pilyugina, T.S., Khripun, V.D., Grachova, E.V., Tunik, S.P., Haukka, M., and Pakkanen, T.A., J. Organomet. Chem., 2006, vol. 691, nos. 1–2, p. 111. doi https://doi.org/10.1016/j.jorganchem.2005.08.007
Ponomarenko, V.I., Gracheva, E.V., Koshevoi, I.O., Gindin, V.A., Tunik, S.P., Pursiainen, I., and Haukka, M., Russ. J. Gen. Chem, 2010, vol. 80, p. 408. doi https://doi.org/10.1134/S1070363210030060
Gracheva, E.V., Krupenya, D.V., Pilyugina, T.S., Tunik, S.P., Pursiainen, J., and Haukka, M., Russ. J. Gen. Chem., 2006, vol. 76, p. 682. doi https://doi.org/10.1134/S1070363206050033
Tunik, S.P., Khripun, V.D., Balova, I.A., Nordlander, E., Haukka, M., Pakkanen, T.A., and Raithby, P.R., Organometallics, 2001, vol., 20, no. 18, p. 3854. doi https://doi.org/10.1021/OM010400A
Dolgushin, F.M., Grachova, E.V., Heaton, B.T., Iggo, J.A., Koshevoy, I.O., Podkorytov, I.S., Smawfield, D.J., Tunik, S.P., Whyman, R., and Yanovskii, A.I., J. Chem. Soc. Dalton Trans., 1999, no. 10, p. 1609. doi https://doi.org/10.1039/a809118h
Koshevoy, I.O., Grachova, E.V., Tunik, S.P., Haukka, M., Pakkanen, T.A., Heaton, B.T., Iggo, J.A., and Podkorytov, I.S., Dalton Trans., 2004, no. 22, p. 3893. doi https://doi.org/10.1039/b410216a.
Koshevoy, I.O., Tunik, S.P., Jääskeläinen, S., Haukka, M., and Pakkanen, T.A., J. Chem. Soc. Dalton Trans., 2001, no., 20, p. 2965. doi https://doi.org/10.1039/b108224h
Koshevoy, I.O., Haukka, M., Pakkanen, T.A., and Tunik, S.P., Dalton Trans., 2006, no. 47, p. 5641. doi https://doi.org/10.1039/B609253E
Grachova, E.V., Jutzi, P., Neumann, B., Schebaum, L.O., Stammler, H.-G., and Tunik, S.P., J. Chem. Soc. Dalton Trans., 2002, no. 3, p. 302. doi https://doi.org/10.1039/b109327d
Grachova, E.V., Jutzi, P., Neumann, B., and Stammler, H.-G., Dalton Trans., 2005, no. 22, p. 3614. doi https://doi.org/10.1039/b513015h
Grachova, E.V., Linti, G., Stammler, H.-G., Neumann, B., Tunik, S.P., and Wadepohl, H., Eur. J. Inorg. Chem., 2007, no. 1, p. 140. doi https://doi.org/10.1002/ejic.200600705
Grachova, E.V. and Linti, G., Eur. J. Inorg. Chem., 2007, no. 22, p. 3561. doi https://doi.org/10.1002/ejic.200700198
Schmidbaur, H., Chem. Soc. Rev., 1995, vol. 24, no. 6, p. 391. doi https://doi.org/10.1039/cs9952400391
Yam, V.W.-W. and Lo, K.K.-W., Chem. Soc. Rev., 1999, vol. 28, no. 5, p. 323. doi https://doi.org/10.1039/a804249g
Shakirova, J.R., Grachova, E.V., Gurzhiy, V.V., Koshevoy, I.O., Melnikov, A.S., Sizova, O.V., Tunik, S.P., and Laguna, A., Dalton Trans., 2012, vol. 41, no. 10, p. 2941. doi https://doi.org/10.1039/c2dt11710j
Shakirova, J.R., Grachova, E.V., Melekhova, A.A., Krupenya, D.V., Gurzhiy, V.V., Karttunen, A.J., Koshevoy, I.O., Melnikov, A.S., and Tunik, S.P., Eur. J. Inorg. Chem., 2012, no. 25, p. 4048. doi https://doi.org/10.1002/ejic.201200362
Dau, T.M., Shakirova, J.R., Doménech, A., Jänis, J., Haukka, M., Grachova, E.V., Pakkanen, T.A., Tunik, S.P., and Koshevoy, I.O., Eur. J. Inorg. Chem., 2013, no. 28, p. 4976. doi https://doi.org/10.1002/ejic.201300615
Shakirova, J.R., Grachova, E.V., Melnikov, A.S., Gurzhiy, V.V., Tunik, S.P., Haukka, M., Pakkanen, T.A., Koshevoy, I.O., Organometallics, 2013, vol. 32, no. 15, p. 4061. doi https://doi.org/10.1021/om301100v
Jobbágy, C. and Deák, A., Eur. J. Inorg. Chem., 2014, vol. 2014, no. 27, p. 4434. doi https://doi.org/10.1002/ejic.201402249
Ramazanov, R.R., Kononov, A.I., Nesterenko, A.M., Shakirova, J.R., Grachova, E.V., Koshevoy, I.O., and Tunik, S.P., J. Phys. Chem. (C), 2016, vol. 120, p. 25541. doi https://doi.org/10.1021/acs.jpcc.6b0871
Shakirova, J.R., Grachova, E.V., Gurzhiy, V.V., Thangaraj, S.K., Jänis, J., Melnikov, A.S., Karttunen, A.J., Tunik, S.P., and Koshevoy, I.O., Angew. Chem. Int. Ed., 2018, vol. 57, no. 43, p. 14154. doi https://doi.org/10.1002/anie.201809058
Chen, Y.-T., Krytchankou, I.S., Karttunen, A.J., Grachova, E.V., Tunik, S.P., Chou, P.-T., and Koshevoy, I.O., Organometallics, 2017, vol. 36, no. 2, p. 480. doi https://doi.org/10.1021/acs.organomet.6b00866
Kritchenkov, I.S., Gitlina, A.Y., Koshevoy, I.O., Melnikov, A.S., and Tunik S.P., Eur. J. Inorg. Chem., 2018, vol., 2018, no. 34, p. 3822. doi https://doi.org/10.1002/ejic.201800631
Krytchankou, I.S., Koshevoy, I.O., Gurzhiy, V.V., Pomogaev, V.A., and Tunik, S.P., Inorg. Chem., 2015, vol. 54, no. 17, p. 8288. doi https://doi.org/10.1021/acs.inorgchem.5b00239
Koshevoy, I.O., Haukka, M., Selivanov, S.I., Tunik, S.P., and Pakkanen, T.A., Chem. Commun., 2010, vol. 46, no. 47, p. 8926. doi https://doi.org/10.1039/c0cc03953e
Shakirova, J.R., Grachova, E.V., Karttunen, A.J., Gurzhiy, V.V., Tunik, S.P., and Koshevoy, I.O., Dalton Trans., 2014, vol. 43, no. 16, p. 6236. doi https://doi.org/10.1039/c3dt53645a
Shakirova, J.R., Grachova, E.V., Sizov, V.V., Starova, G.L., Koshevoy, I.O., Melnikov, A.S., Gimeno, M.C., Laguna, A., and Tunik, S.P., Dalton Trans., 2017, vol. 46, no. 8, p. 2516. doi https://doi.org/10.1039/C6DT04126D
Koshevoy, I.O., Chang, Y.-C., Karttunen, A.J., Selivanov, S.I., Jänis, J., Haukka, M., Pakkanen, T.A., Tunik, S.P., and Chou P.-T., Inorg. Chem., 2012, vol. 51, no. 13, p. 7392. doi https://doi.org/10.1021/ic300856h
Koshevoy, I.O., Chang, Y.-C., Chen, Y.-A., Karttunen, A.J., Grachova, E.V., Tunik, S.P., Jänis, J., Pakkanen, T.A., and Chou, P.-T., Organometallics, 2014, vol. 33, no. 9, p. 2363. doi https://doi.org/10.1021/om5002952
Strelnik, I.D., Gurzhiy, V.V., Sizov, V.V., Musina, E.I., Karasik, A.A., Tunik, S.P., and Grachova, E.V., CrystEngComm., 2016, vol. 18, no. 39, p. 7629. doi https://doi.org/10.1039/C6CE01272H
Strelnik, I.D., Musina, E.I., Grachova, E.V., Karasik, A.A., and Sinyashin, O.G., Phosphorus, Sulfur, Silicon, Relat. Elem., 2016, vol. 191, nos. 11–12, p. 1518. doi https://doi.org/10.1080/10426507.2016.1212346
Dau, M.T., Shakirova, J.R., Karttunen, A.J., Grachova, E.V., Tunik, S.P., Melnikov, A.S., Pakkanen, T.A., and Koshevoy, I.O., Inorg. Chem., 2014, vol. 53, no. 9, p. 4705. doi https://doi.org/10.1021/ic500402m
Dau, T.M., Chen, Y.-A., Karttunen, A.J., Grachova, E.V., Tunik, S.P., Lin, K.-T., Hung, W.-Y., Chou, P.-T., Pakkanen, T.A., and Koshevoy, I.O., Inorg. Chem., 2014, vol. 53, no. 24, p. 12720. doi https://doi.org/10.1021/ic501470v
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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 6, pp. 879–892.
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This work was financially supported by the Russian Scientific Foundation (grant no. 16-13-10064) with the use of equipment of the Scientific park of St. Petersburg state university and also of the Analytical center of nano- and biotechnologies of St. Petersburg polytechnic university.
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Grachova, E.V. Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands. Russ J Gen Chem 89, 1102–1114 (2019). https://doi.org/10.1134/S1070363219060045
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DOI: https://doi.org/10.1134/S1070363219060045