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Synthesis of SKOP oligopiperylene rubber on vanadium catalytic systems

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Specific features of cationic polymerization of 1,3-pentadiene under the action of modified catalytic systems based on vanadium oxytrichloride were studied. The most effective agents controlling the molecular characteristics in synthesis of poly-1,3-pentadiene on vanadium catalysts are tert-butyl chloride and a combination of tert-butyl chloride with diisopropyl ether. The suggested catalytic systems allow virtually complete conversion of the monomer to be reached within a technologically acceptable time. The developed vanadium catalytic systems are recommended for commercial production of Oligopiperylene Rubber SKOP.

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Authors and Affiliations

  1. Institute of Volga Basin Ecology, Russian Academy of Sciences, ul. Komzina 10, Togliatti, Samara oblast, 445003, Russia

    V. A. Rozentsvet, V. G. Kozlov, N. A. Korovina, O. A. Stotskaya & I. A. Pronina

  2. Lebedev Research Institute of Synthetic Rubber, Gapsal’skaya ul. 1, St. Petersburg, 198035, Russia

    L. V. Agibalova & E. Yu. Maretina

Authors
  1. V. A. Rozentsvet
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  2. V. G. Kozlov
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  3. N. A. Korovina
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  4. O. A. Stotskaya
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  5. I. A. Pronina
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  6. L. V. Agibalova
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  7. E. Yu. Maretina
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Corresponding author

Correspondence to V. A. Rozentsvet.

Additional information

Original Russian Text © V.A. Rozentsvet, V.G. Kozlov, N.A. Korovina, O.A. Stotskaya, I.A. Pronina, L.V. Agibalova, E.Yu. Maretina, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 11, pp. 1606−1612.

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Rozentsvet, V.A., Kozlov, V.G., Korovina, N.A. et al. Synthesis of SKOP oligopiperylene rubber on vanadium catalytic systems. Russ J Appl Chem 88, 1820–1826 (2015). https://doi.org/10.1134/S10704272150110130

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  • DOI: https://doi.org/10.1134/S10704272150110130

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