Abstract
We have measured the quantum efficiency for carrier generation as a function of photon energy and the electroabsorption spectrum in poly (phenyl methyl silane). The experimental data are consistent with a band gap of about 4.6 eV. A strong absorption peak which is observed at 3.7 eV is shown to be an exciton band.
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R. D. Miller and J. Michl, Chem. Rev. 89, 1359 (1989).
L. A. Harrah and J. M. Zeigler, Macromolecules 20, 601 (1987).
R. G. Kepler, J. M. Zeigler, L A. Harrah and S. R. Kurtz, Phys. Rev. B 35, 2818 (1987).
M. Abkowitz, F. E. Knier, H. -J. Yuh, R. J. Weagley and M. Stolka, Sol. St. Comm. 62, 547 (1987).
F. Kajzar, J. Messier and C. Rosilio, J. Appl. Phys. 60, 3040 (1986); J. C. Baumert, G. C. Bjorklund, D. H. Jundt, M. C. Jurich, H. Looser, R. D. Miller, J. Rabolt, R. Sooriyakumaran, J. D. Swalen and R. J. Twieg, J. Appl. Phys. Lett. 53, 1147 (1988).
J. M. Zeigler, Poly. Prepr. Am. Chem. Soc. Div. Polm. Chem. 27(1), 109 (1986).
R. G. Kepler and J. M. Zeigler in Proc. of the International Workshop “Advances in Silcon Based Polymer Technology,” edited by J. M. Zeigler and G. Fearon, to be published; R. G. Kepler and J. M. Zeigler, Mol. Cryst. and Liq. Cryst. 175, 85 (1989); R. G. Kepler, Synth. Met.. 28, C573 (1989).
See for example L Sebastian, G. Weiser and H. Bassler, Chem. Phys. 61, 125 (1981).
L Sebastian and G. Weiser, Phys Rev. Lett. 46, 1156 (1981); Y. Tokura, Y. Oowaki and T. Koda, Chem. Phys. 88, 437 (1984).
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Kepler, R.G., Zeigler, J.M. Band-To-Band Transitions in Poly (Phenyl Methyl Silane). MRS Online Proceedings Library 173, 453–457 (1989). https://doi.org/10.1557/PROC-173-453
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DOI: https://doi.org/10.1557/PROC-173-453