Skip to main content
SpringerLink
Log in

Crystal structure and thermal chemical properties of 2-(2,4-dimethylanilino)-3-methyl-6-diethylaminofluorane

  • Published:
Chemical Papers Aims and scope Submit manuscript

Abstract

The crystal structure of 2-(2,4-dimethylanilino)-3-methyl-6-diethylaminofluorane has been determined by single crystal X-ray diffraction method. The crystal belongs to triclinic system, space group P-1 with unit cell constants a = 11.2877(9) Å, b = 11.9539(9) Å, c = 12.2365(9) Å, α = 97.2580(10)°, β = 116.2850(10)°, γ = 106.3710(10)°, V = 1358.48(18) Å 3, Z = 2, D c = 1.234 g/cm3, μ = 0.079 mm−1, F(000) = 536, R and w(R) are 0.0718 and 0.2055, respectively, for 5239 unique reflections with 3745 observed reflections (I > 2σ(I)).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Manivannan, G., Gangkakoti, R., Lessard, R. A., Maillot, G., and Bolte, M., J. Phys. Chem. 97, 7228 (1993).

    Article  CAS  Google Scholar 

  2. Eaton, D. F., in Advances in Photochemistry, Vol. 13. (Volman, D. H., Hammond, G. S., and Gollnick, K., Editors.), P. 427. Wiley—Interscience, New York, 1986.

    Google Scholar 

  3. Naciri, J. and Weiss, R. G., Macromolecules 22, 3938 (1989).

    Article  Google Scholar 

  4. He, Z., Hammond, G. S., and Weiss, R. G., Macromolecules 25, 502 (1992).

    Google Scholar 

  5. Peres, V. and Nagem, T. J., Phytochemistry 44, 191 (1996).

    Article  Google Scholar 

  6. Peres, V., Nagem, T. J., and de Oliveira, F. F., Phytochemistry 55, 683 (2000).

    Article  PubMed  CAS  Google Scholar 

  7. Ho, C.-K., Huang, Y.-L., and Chen, C.-C., Planta Med. 68, 975 (2002).

    Article  PubMed  CAS  Google Scholar 

  8. Rocha, L., Marston, A., Kaplan, M. A. C., Stoeckli-Evans, H., Thull, U., Testa, B., and Hostettmann, K., Phytochemistry 36, 1381 (1994).

    Article  PubMed  CAS  Google Scholar 

  9. Minami, H., Kinoshita, M., Fukuyama, Y., Kodama, M., Yoshizawa, T., Sugiura, M., Nakagawa, K., and Tago, H., Phytochemistry 36, 501 (1994).

    Article  CAS  Google Scholar 

  10. Malet-Cascon, L., Romero, F., Espliego-Vazquez, F., Gravalos, D., and Fernandez-Puentes, J. L., J. Antibiot. 56, 219 (2003).

    PubMed  CAS  Google Scholar 

  11. Lin, C. N., Chung, M. I., Liou, S. J., Lee, T. H., and Wang, J. P., J. Pharm. Pharmacol. 48, 532 (1996).

    PubMed  CAS  Google Scholar 

  12. Groweiss, A., Cardellina II, J. H., and Boyd, M. R., J. Nat. Prod. 63, 1537 (2000).

    Article  PubMed  CAS  Google Scholar 

  13. Zhou, W. H., Liu, J. M., Li, M. Z., and Wang, E. J., Dyes Pigments 36, 295 (1998).

    Article  CAS  Google Scholar 

  14. Zhou, W. H., Liu, J. M., Wu, Z. R., and Wang, E. J., J. Photochem. Photobiol., A 112, 173 (1998).

    Article  CAS  Google Scholar 

  15. Panunzi, A., Giordano, F., Orabona, I., and Ruffo, F., Inorg. Chim. Acta 358, 1217 (2005).

    Article  CAS  Google Scholar 

  16. Sheldrick, G. M., SHELXS-97, Program for X-Ray Crystal Structure Solution. Göttingen University, Germany, 1997; Sheldrick, G. M., SHELXS-97, Program for X-Ray Crystal Structure Refinement. Göttingen University, Germany, 1997.

    Google Scholar 

  17. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G., and Taylor, R., J. Chem. Soc., Perkin Trans. 2 1987, S1.

    Google Scholar 

  18. Ding, C.-F., Tian, B.-Q., Li, X.-M., Liu, Q., Zhang, S.-S., Xu, H., and Ouyang, P.-K., Asian J. Chem. 18, 1430 (2006).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China

    X. M. Li, C. F. Ding, B. Q. Tian, Q. Liu & S. S. Zhang

  2. College of Science and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, 210009, P. R. China

    C. F. Ding, H. Xu & P. K. Ouyang

Authors
  1. X. M. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. F. Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Q. Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Q. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. S. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. H. Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. P. K. Ouyang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. S. Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, X.M., Ding, C.F., Tian, B.Q. et al. Crystal structure and thermal chemical properties of 2-(2,4-dimethylanilino)-3-methyl-6-diethylaminofluorane. Chem. Pap. 60, 220–223 (2006). https://doi.org/10.2478/s11696-006-0039-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s11696-006-0039-3

Keywords

Search

Navigation