Abstract
Self-organized assemblies originate in an aqueous solution because of the tendency of a biological macromolecule to expose its hydrophilic part to water and to keep the hydrophobic portion away from water.1 Examples of such assemblies range from the unique biologically active structure (native form) of a protein and the DNA double helix to many supramolecules, guest-host complexes and aggregates of amphiphilic molecules (e.g. lipids, micelles). Structures of some organized assemblies are shown in Fig. 1.1. They play a key role in molecular recognition, bio-catalysis, targeted drug delivery,2 and in many emerging areas such as, dynamic combinatorial chemistry,3 and adaptive chemistry.4
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1.7. References
L. Maibaum, A. R. Dinner, D. Chandler, Micelle formation and the hydrophobic effect, J. Phys. Chem. B 104, (2004) (in press).
A. Muller, D. F. O’Brien, Supramolecular materials via polymerization of mesophases of hydrated amphiphiles, Chem. Rev. 102(3), 727–758 (2002).
J. R. Nitschke, J.-M. Lehn, Self-organization by selection: Generation of a metallosupramolecular grid architecture by selection of components in a dynamic library of ligands, Proc. Natl. Acad. Sci. USA 100(21), 11970–11974 (2003).
S. Fernandez-Lopez, H.-S. Kim, E. C. Choi, M. Delgado, J. R. Granja, A. Khasanov, K. Kraehenbuehl, G. Long, D. A. Weinberger, K. M. Wilcoxen, M. R. Ghadiri, Antibacterial agents based on the cyclic D,L-α-peptide architecture, Nature 412(6845), 452–456 (2001).
S. W. Rick, S. J. Stuart, B. J. Berne, Dynamical fluctuating charge force fields: applications to liquid water, J. Chem. Phys. 101(7), 6141–6156 (1994).
J. R. Lakowicz, Principles of Fluorescence Spectroscopy, (Kluwer/Plenum, New York, 1999).
K. Bhattacharyya, Study of organized media using time-resolved fluorescence spectroscopy, J. Fluorescence 11(3), 167–176 (2001).
T. Simonson, G. Archontis, M. Karplus, Free energy simulations come of age: Protein-ligand recognition, Acc. Chem. Res. 35(6), 430–437 (2002).
A. Warshel, Molecular dynamic simulations of biological reactions, Acc. Chem. Res. 35(6), 385–395 (2002).
T. Simonson, Gaussian fluctuations and linear response in an electron transfer protein, Proc. Natl. Acad. Sc. USA 99(10), 6544–6549 (2002).
B. Bagchi, Water solvation dynamics in the bulk and in the hydration layer of protein and self-assemblies, Annu. Rep. Prog. Chem., Sect. C. 99, 127–175 (2003).
K. Bhattacharyya, Solvation dynamics and proton transfer in supramolecular assemblies, Acc. Chem. Res. 36(2), 95–101 (2003).
N. Nandi, K. Bhattacharyya, B. Bagchi, Dielectric relaxation and solvation dynamics of water in complex chemical and biological systems, Chem. Rev. 100(6), 2013–2045 (2000).
K. Bhattacharyya, B. Bagchi, Slow dynamics of constrained water in complex geometries, J. Phys. Chem. A 104(46), 10603–10613 (2000).
E. L. Quitevis, A. H. Marcus, M. D. Fayer, Dynamics of ionic lipophilic probes in micelles: picosecond fluorescence depolarization measurements, J. Phys. Chem. 97(21), 5762–5769 (1993).
N. W. Wittouck, R. M. Negri, F. C. De Schryver, AOT reversed micelles investigated by fluorescence anisotropy of cresyl violet, J. Am. Chem. Soc. 116(23), 10601–10611 (1994).
N. C. Maiti, M. M. G. Krishna, P. J. Britto, N. Periasamy, Fluorescence dynamics of dye probes in micelles, J. Phys. Chem. B 101(51), 11051–11060 (1997).
S. Sen, D. Sukul, P. Dutta, K. Bhattacharyya, Fluorescence anisotropy decay in-polymer-surfactant aggregates, J. Phys. Chem. A 105(32), 7495–7500 (2001).
For instance, D1 of amino benzoic acid is 8 × 10−10 m2/s−1; Handbook of Chemistry and Physics, (CRC Press, Boca Raton, Fl, 1990) p. 6–151.
Ref 6, p. 211–233.
M. Maroncelli, The dynamics of solvation in polar liquids, J. Mol. Liq. 57, 1–37 (1993).
J. Barthel, K. Bachuber, R. Buchner, H. Hetzenauer, Dielectric spectra of some common solvents in the microwave region. Water and lower alcohols, Chem. Phys. Lett. 165(4), 369–373 (1990).
U. Kaatze, Dielectric relaxation of H2O/D2O mixtures, Chem. Phys. Lett. 203(1), 1–4 (1993).
W. Jarzeba, G. C. Walker, A. E. Johnson, M. A. Kahlow, P. F. Barbara, Femtosecond microscopic solvation dynamics in aqueous solution, J. Phys. Chem. 92(25), 7039–7041 (1988).
R. Jimenez, G. R. Fleming, P. V. Kumar, M. Maroncelli, Femtosecond solvation dynamics in water, Nature 369(6480), 471–473 (1994).
N. Nandi, S. Roy, B. Bagchi, Ultrafast solvation dynamics in water: Isotope effects and comparison with experimental results, J. Chem. Phys. 102(3), 1390–1397 (1995).
E. H. Grant, R. J. Sheppard, G. P. South, Dielectric Behavior of Biological Molecules (Clarendon, Oxford, 1978).
Protein-Solvent Interactions, edited by R. B. Gregory (Marcel Dekker, New York, 1995).
G. Otting, E. Liepinsh, K. Wüthrich, Protein hydration in aqueous solution, Science 254(5034), 974–980 (1991).
K. Modig, E. Liepinsh, G. Otting, B. Halle, Dynamics of protein and peptide hydration, J. Am. Chem. Soc. 126(1), 102–114 (2004).
A. Maitra. Determination of size parameters of water-Aerosol OT-oil reverse micelles from their nuclear magnetic resonance data, J. Phys. Chem. 88(21), 5122–5125 (1984).
S. P. Moulik, G. C De, B. B. Bhowmik, A. K. Panda, Physicochemical studies on microemulsions. 6. Phase behavior, dynamics of percolation, and energetics of droplet clustering in water/AOT/n-heptane system influenced by additives (sodium cholate and sodium salicylate), J. Phys. Chem. B 103(34), 7122–7129 (1999).
S. Sen, D. Sukul, P. Dutta, K. Bhattacharyya, Solvation dynamics in the water pool of aerosol sodium dioctylsulfosuccinate microemulsion. Effect of polymer, J. Phys. Chem. A 106(25), 6017 (2002).
J. Zhang, F.V. Bright, Nanosecond reorganization of water within the interior of reversed micelles revealed by frequency-domain fluorescence spectroscopy, J. Phys. Chem. 95(20), 7900–7907 (1991).
N. Sarkar, K. Das, S. Das, A. Datta, K. Bhattacharyya, Solvation dynamics of coumarin 480 in reverse micelles. Slow relaxation of water molecules, J. Phys. Chem. 100(25), 10523–10527 (1996).
R. E. Riter, D. M. Willard, N. E. Levinger, Water immobilization at surfactant interfaces in reverse micelles, J. Phys. Chem. B 102(15), 2705–2714 (1998).
K. Bhattacharyya, K. Hara, N. Kometani, Y. Uozu, O. Kajimoto, Solvation dynamics in a microemulsion in near-critical propane, Chem. Phys. Lett. 361(1–2), 136–142 (2002).
P. Dutta, P. Sen, S. Mukherjee, A. Haider, K. Bhattacharyya, Solvation dynamics in the water pool of an aerosol-OT microemulsion. Effect of sodium salicylate and sodium cholate, J. Phys. Chem. B 107(39), 10815–10822 (2003).
M.-L. Horng, J. A. Gardecki, M. Maroncelli, Rotational dynamics of coumarin 153: Time-dependent friction, dielectric friction, and other non-hydrodynamic effects, J. Phys. Chem. A 101(6), 1030–1047 (1997).
C. Ju, C. Bohnne, Dynamics of probe complexation to bile salt aggregates, J. Phys. Chem. 100(9), 3847–3854 (1996).
A. P. Demchenko, The red-edge effects: 30 years of exploration, Luminescence 17(1), 19–42 (2002).
H. Raghuraman, A. Chattopadhyay, Organization and dynamics of melittin in environments of graded hydration. A fluorescence approach, Langmuir 19(24), 10332–10341 (2003).
T. Satoh, H. Okuno, K. Tominaga, K. Bhattacharyya, Excitation wavelength dependence of solvation dynamics in a water pool of a reverse micelle, Chemistry Letters (submitted).
S. Senapati, A. Chandra, Dielectric constant of water confined in a nanocavity, J. Phys. Chem. B 105(22), 5106–5109 (2001).
J. Faeder, M. V. Albert, B. M. Ladanyi, Molecular dynamics simulations of the interior of aqueous reverse micelles: A comparison between sodium and potassium counterions, Langmuir 19(6), 2514–2520 (2003).
S. Senapati, M. L. Berkowitz, Water structure and dynamics in phosphate fluorosurfactant based reverse micelle: A computer simulation study, J. Chem. Phys. 118(4), 1937–1944 (2003).
S. S. Berr, Solvent isotope effects on alkytrimethylammonium bromide micelles as a function of alkyl chain length, J. Phys. Chem. 91(18), 4760–4765 (1987).
N. Sarkar, A. Datta, S. Das, K. Bhattacharyya, Solvation dynamics of coumarin 480 in micelles, J. Phys. Chem. 100(38), 15483–15486 (1996).
K. Hara, H. Kuwabara, O. Kajimoto, Pressure effect on solvation dynamics in micellar environment, J. Phys. Chem. A, 105(30), 7174–7179 (2001).
S. Sen, P. Dutta, S. Mukherjee, K. Bhattacharyya, Solvation dynamics in bile salt aggregates, J. Phys. Chem. B 106(32), 7745–7750 (2002).
P. Sen, S. Mukherjee, A. Haider, K. Bhattacharyya, Temperature dependence of solvation dynamics in a micelle. 4-Aminophtalimide in triton X-100, Chem. Phys. Lett. 385(5–6), 357–361 (2004).
S. Pal, S. Balasubramanian, B. Bagchi, Identity, energy, and environment of interfacial water molecules in a micellar solution, J. Phys. Chem. B 107(22), 5194–5202 (2003).
S. Balasubramanian, B. Bagchi, Slow solvation dynamics near an aqueous micellar surface, J. Phys. Chem. B 105(50), 12529–12533 (2001).
S. Balasubramanian, S. Pal, B. Bagchi, Hydrogen bond dynamics near a micellar surface: origin of the universal slow relaxation at complex aqueous interfaces, Phys. Rev. Lett. 89(11), 115505–1 (2002).
D. Mandal, S. Sen, T. Tahara, K. Bhattacharyya, Femtosecond study of solvation dynamics of DCM in micelles, Chem. Phys. Lett. 359(1–2), 77–82 (2002).
C. D. Bruce, S. Senapati, M. L. Berkowitz, L. Perera, M. D. E. Forbes, Molecular dynamics simulations of sodium dodecyl sulfate micelle in water: The behavior of water, J. Phys. Chem. B 106(42), 10902–10907 (2002).
S. Vajda, R. Jimenez, S. J. Rosenthal, V. Fidler, G. R. Fleming, E. W. Castner Jr., Femtosecond to nanosecond solvation dynamics in water and inside the γ-cyclodextrin cavity, J. Chem. Soc. Faraday Trans. 91(5), 867–873 (1995).
S. Sen, D. Sukul, P. Dutta, K. Bhattacharyya, Slow solvation dynamics of dimethylformamide in a nanocavity. 4-Aminophthalimide in β-cyclodextrin, J. Phys. Chem. A 105(47), 10635–10639 (2001).
N. Nandi, B. Bagchi, Ultrafast solvation dynamics of an ion in the γ-cyclodextrin cavity: Role of restricted environment, J. Phys. Chem. 100(33), 13914–13919 (1996).
Hydration Processes in Biology: Theoretical and Experimental Approaches, Edited by M.-C. Bellisent-Funnel (IOS Press, Amsterdam, 1999).
Hydration Processes in Biological and Macromolecular Systems, Faraday Discuss. 103(1), 1–394 (1996).
N. Nandi, B. Bagchi, Dielectric relaxation of biological water, J. Phys. Chem. B 101(50), 10954–10962 (1997).
P. Marzola, E. Gratton, Hydration and protein dynamics: frequency domain fluorescence spectroscopy of proteins in reverse micelles, J. Phys. Chem. 95(23), 9488–9495 (1991).
D. Toptygin, R. S. Savichenko, N. D. Meadow, L. Brand, Homogeneous spectrally-and time-resolved fluorescence emission from single-tryptophan mutants of IIAGlc protein, J. Phys. Chem. B 105(10). 2043–2055 (2001).
S. K. Pal, A. H. Zewail, Dynamics of water in molecular recognition, Chem. Rev. 104(4), 2099–2124 (2004).
L. P. McMahon, H. T. Yu, M. A. Vela, G. A. Morales, L. Shui, F. R. Fronczek, M. L. McLaughlin, M. D. Barkley, Conformer interconversion in the excited state of constrained tryptophan derivatives, J. Phys. Chem. B 99(16), 3269–3280 (1997).
A. G. Szabo, D. M. Rayner, Fluorescence decay of tryptophan conformers in aqueous solution, J. Am. Chem. Soc. 102(2), 554–563 (1980).
J. S. Lundgren, M. P. Heitz, F. V. Bright, Dynamics of acrylodan-labeled bovine and human serum albumin sequestered within aerosol-OT reverse micelles, Anal. Chem. 67(20), 3775–3781 (1995).
D. Mandal, S. Sen, D. Sukul, K. Bhattacharyya, A. K. Mandal, R. Banerjee and S. Roy, Solvation dynamics of a probe covalently bound to a protein and in AOT microemulsion. 4 (N-bromoacetylamino)-phthalimide, J. Phys. Chem. B 106(41), 10741–10747 (2002).
L. D. Weber, A. Tulinsky, J. D. Johnson, M. A. El-Bayoumi, Expression of functionality of α-chymotrypsin. The structure of a fluorescent probe-α-chymotrypsin complex and the nature of its pH dependence, Biochemistry 18(7), 1297–1303 (1979).
T. Imoto, L. S. Forster, J. A. Rupley, F. Tanaka, Fluorescence of lysozyme: Emission from tryptophan residues 62 and 108 and energy migration, Proc. Natl. Acad. Sci. USA 69(5), 1151–1155 (1971).
J. F. Baugher, L. I. Grossweiner, J. Lewis, Intramolecular energy transfer in lysozyme-eosin complex, J. Chem. Soc. Faraday Trans. II 70, 1389–1398 (1974).
J. S. Bashkin, G. McLedon, S. Mukamel, J. Marohn, Influence of medium dynamics on solvation and charge separation reactions: comparison of a simple alcohol and a protein “solvent,” J. Phys. Chem. 94(12), 4757–4761 (1990).
D. W. Pierce, S. G. Boxer, Dielectric relaxation in a protein matrix, J. Phys. Chem. 96(13), 5560–5566 (1992).
S. K. Pal, D. Mandal, D. Sukul, S. Sen, K. Bhattacharyya, Solvation dynamics of DCM in human serum albumin, J. Phys. Chem. B 105(7), 1438–1441 (2001).
X. J. Jordanides, M. J. Lang, X. Song, G. R. Fleming, Solvation dynamics in protein environments studied by photon echo spectroscopy, J. Phys. Chem. B 103(37), 7995–8005 (1999).
P. Dutta, P. Sen, A. Haider, S. Mukherjee, S. Sen, K. Bhattacharyya, Solvation dynamics in a protein-surfactant complex, Chem. Phys. Lett. 377(1–2), 229–235 (2003).
P. Sen, S. Mukherjee, P. Dutta, A. Haider, D. Mandal, R. Banerjee, S. Roy, K. Bhattacharyya, Solvation dynamics in the molten globule state of a protein, J. Phys. Chem. 107(51), 14563–14568 (2003).
A. Warshel, Computer simulations of enzyme catalysis: Methods, progress, and insights, Annu Rev Biophys Biomol. Struct. 32, 425–443 (2003).
M. Levitt, R. Sharon, Accurate simulation of protein dynamics in solution, Proc. Natl. Acad. Sci. USA 85(20), 7557–7561 (1988).
V. Makrov, B. M. Petit, Solvation and hydration of protein and nucleic acids: A theoretical view of simulation and experiment, Acc. Chem. Res. 35(6), 376–384 (2002).
P. Dutta, P. Sen, S. Mukherjee, K. Bhattacharyya, Solvation dynamics in DMPC vesicle in the presence of a protein, Chem. Phys. Lett. 382(3–4), 426–433 (2003).
S. K. Pal, J. Peon, B. Bagchi, A. H. Zewail, Biological water: Femtosecond dynamics of macromolecular hydration, J. Phys. Chem. 107(48), 12376–12395 (2003).
E. B. Brauns, M. L. Madaras, R. S. Coleman, C. J. Murphy, M. A. Berg, Complex local dynamics in DNA on the picosecond and nanosecond time scales, Phys. Rev. Lett. 88(15), 158101–1 (2002).
L. A. Gearheart, M. M. Somoza, W. E. Rivers, C. J. Murphy, R. S. Coleman, M. A. Berg, Sodium-ion binding to DNA: Detection by ultrafast time-resolved Stokes-shift spectroscopy, J. Am. Chem. Soc. 125(39), 11812–11813 (2003).
S. K. Pal, L. Zhao, T. Xia, A. H. Zewail, Site-and sequence-selective ultrafast hydration of DNA, Proc. Natl. Acad. Sci. USA 100(24), 13746–13751 (2003).
N. Deo, S. Jockusch, N. J. Turro, P. Somasundaran, Surfactant interactions with zein protein, Langmuir 19(12), 5083–5088 (2003).
E. A. Lissi, E. Abuin, Aggregation numbers of sodium dodecyl sulfate micelles formed on poly(ethylene oxide) and poly(vinyl pyrrolidone) chains, J. Coll. Inter. Sci. 105(1), 1–6 (1985).
R. Narenberg, J. Kliger, D. Horn, Study of the interaction between poly(vinyl pyrrolidone) and sodium dodecyl sulfate by fluorescence correlation spectroscopy, Angew. Chem. Int. Ed. Engl. 38(11), 1626–1629 (1999).
S. Sen, D. Sukul, P. Dutta, K. Bhattacharyya, Solvation dynamics in aqueous polymer solution and in polymer-surfactant aggregate, J. Phys. Chem. B 106(15), 3763–3769 (2002).
P. Dutta, S. Sen, S. Mukherjee, K. Bhattacharyya, Solvation dynamics of TNS in polymer (PEG)-surfactant (SDS) aggregate, Chem. Phys. Lett. 359(1–2), 15–21 (2002).
P. Dutta, D. Sukul, S. Sen, K. Bhattacharyya, Solvation dynamics of 4-aminophthalimide in a polymer (PVP)-surfactant (SDS) aggregate, Phys. Chem. Chem. Phys. 5(21), 4875–4879 (2003).
L. Frauchiger, H. Shirota, K. E. Uhrich, E. W. Castner Jr., Dynamic fluorescence probing of the local environments within amphiphilic starlike macromolecules, J. Phys. Chem. B 106(30), 7463–7468 (2002).
R. A. Farrrer, J. T. Fourkas, Orientational dynamics of liquids confined in nanoporous sol-gel glasses studied by optical Kerr effect spectroscopy, Acc. Chem. Res. 36(8), 605–612 (2003).
S. K. Pal, D. Sukul, D. Mandal, S. Sen, K. Bhattacharyya, Solvation dynamics of coumarin 480 in sol-gel matrix, J. Phys. Chem. B 104(12) 2613–2616 (2000).
R. Bauman, C. Ferrante, F. W. Deeg, C. Brauchle, Solvation dynamics of nile blue in ethanol confined in porous sol-gel glasses, J. Chem. Phys. 114(13), 5781–5791 (2001).
A. Haider, S. Sen, A. Das Burman, A. Patra, K. Bhattacharyya, Solvation dynamics in dimyristoyl-phosphatidylcholine entrapped inside a sol-gel matrix, J. Phys. Chem. B 108(7), 2309–2312 (2004).
C. Reichardt, Solvatochromic dyes as solvent polarity indicators, Chem. Rev. 94(8), 2319–2358 (1994).
Z. R. Grabowski, K. Rotkiewicz, W. Rettig, Structural changes accompanying intramolecular electron transfer: Focus on twisted intramolecular charge-transfer states and structures, Chem. Rev. 103(10), 3899–4032 (2003).
S. Techert, F. Schotte, M. Wulff, Picosecond X-ray diffraction probed transient structural changes in organic solids, Phys. Rev. Lett. 86(10), 2030–2033 (2001).
K. Bhattacharyya, M. Chowdhury, Environmental and magnetic field effects on exciplex and twisted charge transfer emission, Chem. Rev. 93(1), 507–535 (1993).
J. M. Hicks, M. T. Vandersall, Z. Babarogic, K. B. Eisenthal, The dynamics of barrier crossings in solution: The effect of a solvent polarity-dependent barrier, Chem. Phys. Lett. 116(1), 18–24 (1985).
N. Sarkar, K. Das, D. Nath, K. Bhattacharyya, Twisted intramolecular charge transfer processes of nile red in homogeneous solutions and in zeolite, Langmuir 10(1), 326–329 (1994).
A. Datta, D. Mandal, S. K. Pal, K. Bhattacharyya, Intramolecular charge transfer in confined systems. Nile red in reverse micelles, J. Phys. Chem. B 101(49), 10221–10225 (1997).
A. Nag, K. Bhattacharyya, Twisted intramolecular charge transfer emission of dimethyl-aminobenzonitrile in α-cyclodextrin cavities, Chem. Phys. Lett. 151(4–5), 474–476 (1988).
A. Nag, R. Dutta, N. Chattopadhyay, K. Bhattacharyya, Effect of size of cyclodextrin cavity on twisted intramolecular charge transfer emission: Dimethylamino benzonitrile in β-cyclodextrin, Chem. Phys. Lett. 157(1–2), 83–86 (1989).
A. Douhal, Ultrafast guest dynamics in cyclodextrin nanocavities, Chem. Rev. 104(4), 1955–1976 (2004).
T. A. Fayed, J. A. Organero, I. Garcia-Ochoa, L. Tormo, A. Douhal, Ultrafast twisting motions and intramolecular charge-transfer reaction in a cyanine dye trapped in molecular nanocavities, Chem. Phys. Lett. 364(1–2), 108–114 (2002).
L. M. Tolbert, K. M. Solnstev, Excited-state proton transfer: From constrained systems to “super” photoacids to superfast proton transfer. Acc. Chem. Res. 35(1), 19–27 (2002).
M. Saeki, S.-I. Ishiuchi, M. Sakai. M. Fuji. Structure of l-naphthol:alcohol clusters studied by IR dip spectroscopy and ab-initio molecular orbital calculations, J. Phys. Chem. A 105(44), 10045–10053 (2001).
J. E. Hansen, E. Pines, G. R. Fleming, Excited state proton transfer in 1-aminopyrene complexed with β-cyclodextrin, J. Phys. Chem. 96(17), 6904–6910 (1992).
D. Mandal, S. K. Pal, K. Bhattacharyya, Excited state proton transfer of 1-naphthol in micelles. J. Phys. Chem. A 102(48), 9710–9714 (1998).
P. Dutta, A. Haider, S. Mukherjee, P. Sen, S. Sen, K. Bhattacharyya, Excited state proton transfer of 1-naphthol in a hydroxypropylcellulose/sodium dodecyl sulfate system, Langmuir 18(21), 7867–7871 (2002).
B. Cohen, D. Huppert, K. M. Solnstev, Y. Tsfadia, E. Nachliel, M. Gutman, Excited state proton transfer in reverse micelles, J. Am. Chem. Soc. 124(25), 7539–7547 (2002).
J. A. Organero, A. Douhal, Confinement effects on the photorelaxation of a proton-transfer phototautomer, Chem. Phys. Lett. 373(3–4), 426–431 (2003).
R. A. Marcus, Electron transfer reactions in chemistry: Theory and experiments (Nobel lecture), Angew. Chem. Int. ed. Engl. 32(8), 1111–1222 (1993).
G. J. Kavaranos, Fundamentals of Photoinduced Electron transfer (VCH, New York, 1993).
G. L. Closs, L. T. Calcaterra, N. J. Green, K. W. Penfield, J. R. Miller, Distance, stereoelectronic effects, and the Marcus inverted region in intramolecular electron transfer in organic radical anions, J. Phys. Chem. 90(16), 3673–3683 (1986).
S. K. Pal, D. Mandal, D. Sukul, K. Bhattacharyya, Photoinduced electron transfer between dimethyl aniline and oxazine 1 in micelles, Chem. Phys. 249(1), 63–71 (1999).
H. L. Tavernier, F. Laine, M. D. Fayer, Photoinduced intermolecular electron transfer in micelles: Dielectric and structural properties of micelle headgroup regions, J. Phys. Chem. A 105(39). 8944–8957 (2001).
M. Kumbhakar, S. Nath, H. Pal, A. V. Sapre, T. Mukherjee, Photoinduced electron transfer from aromatic amines to coumarin dyes in sodium dodecyl sulfate micellar solutions, J. Chem. Phys. 119(1), 388–399 (2003).
D. Chakraborty, A. Chakrabarty, D. Seth, N. Sarkar, Photoinduced electron transfer between coumarin dyes and electron donating solvents in cetyltrimethyl ammonium bromide micelles: Evidence for Marcus inverted region, Chem. Phys. Lett. 382(5–6), 508–517 (2003).
R. P. Feynman, R. B. Leighton, M. Sands, The Feynman Lectures in Physics (Addison-Wesley, MA, 1963) Vol. 1, p. 3.6.
M. Karplus, Molecular Dynamics Simulations of Biomolecules (guest editorial), Acc. Chem Res. 35(6), 321–323 (2002).
Ref. 6, p. 233.
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Bhattacharyya, K. (2005). Organized Assemblies Probed by Fluorescence Spectroscopy. In: Geddes, C.D., Lakowicz, J.R. (eds) Reviews in Fluorescence 2005. Reviews in Fluorescence, vol 2005. Springer, Boston, MA. https://doi.org/10.1007/0-387-23690-2_1
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