NEW CONCEPT FOR THE METAL-AIR BATTERIES USING COMPOSITES: CONDUCTING POLYMERS / EXPANDED GRAPHITE AS CATALYSTS

Barsukov, V.Z.; Khomenko, V.G.; Katashinskii, A.S.; Motronyuk, T.I.

doi:10.1007/1-4020-4812-2_8

V.Z. Barsukov⁵,
V.G. Khomenko⁵,
A.S. Katashinskii⁵ &
…
T.I. Motronyuk⁶

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 229))

3969 Accesses
1 Citations

Abstract

The mechanisms and reasons of catalytic activity of polyaniline (PANI)-type conducting polymers toward oxygen reduction in acidic and saline solutions are investigated by electrochemical and quantum-chemical methods. The PANI/thermally expanded graphite compositions were developed for realization of fully functional air gas-diffusion electrodes. Principally new concept for creation of rechargeable metal-air batteries with such type of catalysts is proposed. The mockups of primary and rechargeable metal-air batteries with new type of polymer composite catalysts were developed and tested.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Chapter: USD 29.95; Price excludes VAT (USA)

eBook: USD 259.00; Price excludes VAT (USA)

Softcover Book: USD 329.99; Price excludes VAT (USA)

Hardcover Book: USD 329.99; Price excludes VAT (USA)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

REFERENCES

Alan G. MacDiamid and Heeger, J. Semiconduction and Metallic Polimer: The Fourth Generation of Polymeric Materials. J. Phys. Chem. 2001; B105:8475–8491.
Google Scholar
Bazong Zhao, Neon K.G., Liu F.T., at.al., Interactions Between Polianiline and Viologens. Synthetic Metals 2001;123:263–266
Article CAS Google Scholar
Alan G.MacDiamid, “Syntethetic <etals”: A Novel role for Organic Polymers. Current Applied Phys 2001; 1: 269–279.
Article Google Scholar

Download references

Author information

Authors and Affiliations

Electrochemical Power Engineering & Chemistry Department, Kiev National University of Technologies and Design, 2 Nemorovich-Danchenko str., Kiev, 02001, Ukraine
V.Z. Barsukov, V.G. Khomenko & A.S. Katashinskii
National Technical University of Ukraine “KPI”, 37 Pobedy prosp., Kiev, 03056, Ukraine
T.I. Motronyuk

Authors

V.Z. Barsukov
View author publications
You can also search for this author in PubMed Google Scholar
V.G. Khomenko
View author publications
You can also search for this author in PubMed Google Scholar
A.S. Katashinskii
View author publications
You can also search for this author in PubMed Google Scholar
T.I. Motronyuk
View author publications
You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

Superior Graphite Co., Chicago, IL, U.S.A.
Igor V. Barsukov
Argonne National Laboratory, Argonne, IL, U.S.A.
Christopher S. Johnson
Dontech Global, Inc., Lake Forest, IL, U.S.A.
Joseph E. Doninger
Kiev National University of Technologies and Design, Kiev, Ukraine
Vyacheslav Z. Barsukov

Rights and permissions

Reprints and permissions

Copyright information

About this paper

Cite this paper

Barsukov, V., Khomenko, V., Katashinskii, A., Motronyuk, T. (2006). NEW CONCEPT FOR THE METAL-AIR BATTERIES USING COMPOSITES: CONDUCTING POLYMERS / EXPANDED GRAPHITE AS CATALYSTS. In: Barsukov, I.V., Johnson, C.S., Doninger, J.E., Barsukov, V.Z. (eds) New Carbon Based Materials for Electrochemical Energy Storage Systems: Batteries, Supercapacitors and Fuel Cells. NATO Science Series II: Mathematics, Physics and Chemistry, vol 229. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4812-2_8

Download citation

DOI: https://doi.org/10.1007/1-4020-4812-2_8
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-4810-4
Online ISBN: 978-1-4020-4812-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)

Publish with us

Policies and ethics