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Artificial Photosynthesis: Hybrid Systems

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Biophotoelectrochemistry: From Bioelectrochemistry to Biophotovoltaics

Part of the book series: Advances in Biochemical Engineering/Biotechnology ((ABE,volume 158))

Abstract

Oxidoreductases are promising catalysts for organic synthesis. To sustain their catalytic cycles they require efficient supply with redox equivalents. Today classical biomimetic approaches utilizing natural electron supply chains prevail but artificial regeneration approaches bear the promise of simpler and more robust reaction schemes. Utilizing visible light can accelerate such artificial electron transport chains and even enable thermodynamically unfeasible reactions such as the use of water as reductant.

This contribution critically summarizes the current state of the art in photoredoxbiocatalysis (i.e. light-driven biocatalytic oxidation and reduction reactions).

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Acknowledgements

Financial support by the European Union (ERC consolidator grant No 648026) is gratefully acknowledged.

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Authors and Affiliations

  1. Delft University of Technology, Delft, The Netherlands

    Yan Ni & Frank Hollmann

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  1. Yan Ni
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  2. Frank Hollmann
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Correspondence to Frank Hollmann .

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  1. School of Biomedical Sciences, University of Leeds, Leeds, LS2 9JT, United Kingdom

    Lars J.C. Jeuken

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Ni, Y., Hollmann, F. (2016). Artificial Photosynthesis: Hybrid Systems. In: Jeuken, L. (eds) Biophotoelectrochemistry: From Bioelectrochemistry to Biophotovoltaics. Advances in Biochemical Engineering/Biotechnology, vol 158. Springer, Cham. https://doi.org/10.1007/10_2015_5010

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