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Halogen Bonding in Supramolecular Synthesis

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Halogen Bonding I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 358))

Abstract

Supramolecular synthesis is typically limited to one-pot reactions because of the reversibility of non-covalent bonds, and to overcome this restriction we need to be able to rank the relative structural importance of such interactions and build synthetic methods to utilize synthons which can operate side-by-side without interference. Halogen bonds have characteristics (strength and directionality) which potentially make them prime candidates as critical components of effective, transferable, and versatile supramolecular synthetic strategies. In this chapter, several halogen-bond driven crystal engineering strategies for the assembly of specific architectures in molecular solids are described in detail, and the utility of halogen bonds for the synthesis of co-crystals are addressed. Finally, the structural compatibility or competition between of halogen- and hydrogen bonds in the context of supramolecular synthesis are examined.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Kansas State University, Manhattan, KS, 66506, USA

    Christer B. Aakeröy & Christine L. Spartz

Authors
  1. Christer B. Aakeröy
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  2. Christine L. Spartz
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Editor information

Editors and Affiliations

  1. Dipartimento di Chimica, Polytechnic University of Milan, Milano, Italy

    Pierangelo Metrangolo

  2. Dipartimento di Chimica, Polytechnic University of Milan, Milano, Italy

    Giuseppe Resnati

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Aakeröy, C.B., Spartz, C.L. (2014). Halogen Bonding in Supramolecular Synthesis. In: Metrangolo, P., Resnati, G. (eds) Halogen Bonding I. Topics in Current Chemistry, vol 358. Springer, Cham. https://doi.org/10.1007/128_2014_567

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