Abstract
This review is on the use of differential scanning calorimetry as a method of monitoring and investigating the kinetics of epoxy resin curing reactions. Some instrumental and experimental aspects are discussed, including methods of analysing the kinetic data. A brief survey is made of epoxy resin curing reactions and results of DSC studies are reviewed. These results are concerned with the use of carboxylic acid anhydrides, primary and secondary amines, dicyanodiamide, and imidazoles as curing agents.
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Mackenzie, R. C.: Thermochim. Acta 28, 1 (1979)
Mackenzie, R. C.: Anal. Proc. 217 (1980)
Watson, E. S. O'Neill, M. J. Justin, J., Brenner, N.: Anal. Chem. 36, 1233 (1964)
O'Neill, M. J.: Anal. Chem. 36, 1238 (1964)
Boersma, S. L.: J. Amer. Ceramic Soc. 38, 281 (1955)
Lee, J. D., Levy, P. F.: North American Thermal Anal. Soc., Proc., 11th Conf. (1981)
Wendlandt, W. W., Gallagher, P. K.: Thermal Characterisation of Polymeric Materials (ed.) Turi, E. A., Chapter 1, New York N.Y., Academic Press (1981)
Mraw, S. C.: Rev. Sci. Instr. 53, 228 (1982)
Dallek, S., Kabacoff, L.: Thermochim. Acta 57, 99 (1982)
Hohne, G. W. H., Breuer, K. H., Eysel, W.: Thermochim. Acta 69, 145 (1983)
Richardson, M. J., Savill, N. G.: Polymer 16, 753 (1975)
Flynn, J. H.: Thermochim. Acta 8, 69 (1974)
Nielsen, L. E.: J. Macromol. Sci., Revs. Macromol. Chem. C3, 69 (1969)
Nielsen, L. E.: Mechanical Properties of Polymers and Composites, Vol. 1, New York, N.Y., Marcel Dekker (1974)
Chompff, A. J.: Polymer Networks (ed.) Chompff, A. J., Newman, S., p. 145, New York, N.Y., Plenum Press (1971)
Widmann, G.: Proc. 4th International Conference on Thermal Analysis (ed.) Buzas, I., Vol. 3, p. 359, Budapest, Akademiai Kiado (1975)
Barton, J. M.: Thermochim. Acta 71, 337 (1983)
Barrett, K. E. J.: J. Appl. Polym. Sci. 11, 1617 (1967)
Freeman, E. S., Carroll, B.: J. Phys. Chem. 62, 394 (1958)
Ellerstein, S. M.: Analytical Calorimetry (eds.) Porter, R. S., Johnson, J. O., p. 279, New York, N.Y., Plenum Press (1968)
Crane, L. W., Dynes, P. J., Kaelble, D. H.: J. Polym. Sci., Polym. Letters 11, 533 (1973)
Rogers, R. N., Smith, L. C.: Thermochim. Acta 1, 1 (1970)
Kissinger, H.: Anal. Chem. 21, 1702 (1957)
Doyle, C. D.: J. Appl. Polym. Sci. 6, 639 (1962)
Doyle, C. D.: Techniques and Methods of Polymer Evaluation (ed.) Slade, P. E., Jenkins, L. T., Vol. 1, Thermal Analysis Chapter 4, p. 173, New York, N.Y., Marcel Dekker (1966)
Horowitz, H. H., Metzger, G.: Anal. Chem. 35, 1464 (1963)
Coates, A. W., Redfern, J. P.: Nature 201, 68 (1964)
Ozawa, T.: Bull. Chem. Soc. Japan 38, 1881 (1965)
Ozawa, T.: J. Thermal Anal. 2, 301 (1970)
Ozawa, T.: J. Thermal. Anal. 7, 601 (1975)
Swarin, S. J., Wims, A. M.: Anal. Calorimetry 4, 155 (1976)
Draper, A. L.: Third Toronto Symposium on Thermal Analysis, Proceedings p. 63 (1970)
MacCallum, J. R., Tanner, J.: Nature 225, 1127 (1970)
Fevre, A. Murat, M., Comel, C.: J. Thermal Anal. 12, 193 (1977)
Prime, R. B.: Analytical Calorimetry 2, 201 (1970)
Prime, R. B.: Polym. Eng. Sci. 13, 365 (1973)
Barton, J. M., Shepherd, P. M.: Makromol. Chem. 176, 919 (1975)
Hill, R. A.: Nature 227, 703 (1970)
Simmons, E. L., Wendlandt, W. W.: Thermochim. Acta 3, 498 (1972)
Gyulai, G., Greenhow, E. J.: Thermochim. Acta: 5, 481 (1973)
Sestak, J., Kratochvil, J.: J. Thermal Anal. 5, 429 (1973)
Tanaka, Y., Mika, T. F.: Epoxide curing reactions, in: Epoxy Resins (ed.) May, C. A., Tanaka, Y., Chapter 3, New York, N.Y., Marcel Dekker 1973
Mika, T. F.: Curing agents and modifiers, in: Epoxy Resins, (
Fisch, W., Hofmann, W.: J. Polym. Sci. 12, 497 (1954)
Fisch, W., Hofmann, W.: Makromol. Chem. 44–46, 8 (1961)
Tanaka, Y., Kakiuchi, H.: J. Appl. Polym. Sci. 7, 1063 (1963)
Tanaka, Y., Kakiuchi, H.: J. Polym. Sci., Part A, 2, 3405 (1964)
Tanaka, Y., Kakiuchi, H.: J. Macromol. Chem. 1, 307 (1966)
Luston, J., Manasek, Z.: J. Macromol. Sci., Chem. A, 12, 983 (1978)
Luston, J., Manasek, Z., Kulichova, M.: J. Macromol. Sci., Chem. A, 12, 995 (1978)
Matejka, L., Lovy, J., Pokorny, S., Bouchal, K., Dusek, K.: J. Polym. Sci., Polym. Chem. Ed. 21, 2873 (1983)
Stevens, G. C.: J. Appl. Polym. Sci. 26, 4259 (1981)
Stevens, G. C.: J. Appl. Polym. Sci. 26, 4279 (1981)
Antoon, M. K., Koenig, J. L.: J. Polym. Sci., Polym. Chem. Ed. 19, 549, (1981)
Schechter, L., Wynstra, J., Kurkjy, R. P.: Ind. Eng. Chem. 48, 94 (1956)
Enikolopiyan, N. S.: Pure and Appl. Chem. 48, 317 (1976)
Smith, I. T.: Polymer 2, 95 (1961)
King, J. J., Bell, J. P.: in: Epoxy Resin Chemistry (ed.) Bauer R. S., ACS Symposium Series, No. 114, Chapter 16, Amer. Chem. Soc. (1979)
Saunders, T. F., Levy, M. F., Serefino, J. F.: J. Polym. Sci. A-1, 5, 1609 (1967)
Sacher, E.: Polymer 14, 91 (1973)
Schneider, N. S., Sprouse, J. F., Hagnauer, G. L., Gillham, J. K.: Polym. Eng. Sci. 19, 304 (1979)
Son, P., Weber, C. D.: J. Appl. Polym. Sci. 17, 1305 (1973)
LaLiberte, B. R., Bornstein, J., Sacher, R. E.: Ind. Eng. Chem. Prod. Res. Dev. 22, 261 (1983)
Farkas, A., Strohm, P. F.: J. Appl. Polym. Sci. 12, 159 (1968)
Fava, R. A.: Polymer 9, 137 (1968)
Peyser, P., Bascom, W. D.: Analytical Calorimetry 3, 537 (1974)
Peyser, P., Bascom, W. D.: J. Appl. Polym. Sci. 21, 2359 (1977)
Mohler, H., Schwab, M.: Kunststoffe 71, 245 (1981)
Malavasic, T., Moze, A., Vizovisek, I., Lapanje, S.: Angew. Makromol. Chemie 44, 89 (1975)
Stevens, G. C., Richardson, M. J.: Polymer 24, 851 (1983)
Duswalt, A. A.: Thermochim. Acta 8, 57 (1974)
Abolafia, O. R.: SPE Ann. Tech. Conf., Proc. 15, 610 (1969)
Prime, R. B.: Analytical Calorimetry 2, 201 (1970)
Acitelli, M. A., Prime, R. B., Sacher, E.: Polymer 12, 335 (1971)
Prime, R. B., Sacher, E.: Polymer 13, 455 (1972)
Prime, R. B.: Polym. Eng. Sci. 13, 365 (1973)
Barton, J. M.: Makromol. Chem. 171, 247 (1973)
Barton, J. M.: J. Macromol. Sci.-Chem. A8, 25 (1974)
Cizmecioglu, M., Gupta, A.: SAMPE Qtly. April, 16 (1982)
Levy, N.: Analysis of an epoxy resin curing reaction by differential scanning calorimetry, in: Computer Applications in Applied Polymer Science, p. 313, ACS Symp. Ser. 197, Washington D.C., Amer. Chem. Soc. 1975
Cizmecioglu, M., Hong, S. D., Moacanin, J., Gupta, A.: ACS Polymer Preprints 22, (2), 224 (1981)
Severini, F., Gallo, R., Marullo, R.: J. Thermal Anal. 25, 515 (1982)
Horie, K., Hiura, H., Sawada, M., Mita, I., Kambe, H.: J. Polym. Sci., Part A-1 8, 1357 (1970)
Klute, C. H., Viehmann, W.: J. Appl. Polym. Sci. 5, 86 (1961)
Kamal., M. R., Sourour, S., Ryan, M.: SPE 31st Ann. Tech. Conf., Proc. 187 (1973)
Sourour, S., Kamal., M. R.: Thermochim. Acta 14, 41 (1976)
Ryan, M. E., Dutta, A.: Polymer 20, 203 (1979)
Flammersheim, H., Horhold, H., Bellstedt, K., Klee, J.: Makromol. Chem. 184, 113 (1983)
Barton, J. M.: Unpublished work
Lunak, S., Dusek, K.: J. Polym. Sci., Polym. Symp. No. 53, 45 (1975)
Lunak, S., Vladyka, J., Dusek, K.: Polymer 19, 931 (1978)
Dobas, I., Eichler, J.: Coll. Czech. Chem. Commun. 38, 2602 (1973)
Dobas, I., Eichler, J.: Coll. Czech. Chem. Commun. 38, 3279 (1973)
Dobas, I., Eichler, J., Klaban, J.: Coll. Czech. Chem. Commun. 40, 2989 (1975)
Johncock, P., Tudgey, G. F.: Brit. Polym. J. 15, 14 (1983)
Johncock, P., Porecha, L., Tudgey, G. F.: J. Polym. Sci., Polym. Chem. Ed. 23, 291 (1985)
Mones, E. T., Morgan, R. J.: ACS Polymer Preprints 22, 249 (1981)
Hagnauer, G. L., Pearce, P. J., LaLiberte, B. R., Roylance, M. E.: ACS Div. Org. Coat. Plast. Chem., Preprints 47, 429 (1982)
Gupta, A., Cizmecioglu, D., Coulter, R., Liang, R. H., Yavrouian, A., Tsay, F. D., Moacanin, J.: J. Appl. Polym. Sci. 28, 1011 (1983)
Apicella, A., Nicolais, L., Iannone, M., Passerini, P.: J. Appl. Polym. Sci. 29, 2083 (1984)
Mijovic, J., Kim, J., Slaby, J.: J. Appl. Polym. Sci. 20, 1449 (1984)
Morgan, R. J., Happe, J. A., Mones, E. T.: Paper presented at the 28th Nat. SAMPE Symposium, Annaheim, Calif., April (1983)
Zukas, W. X.: Ph. D Dissertation, Chem. Eng. Dept., Univ. of Mass., USA (1983)
Zukas, W. X., Schneider, N. S., MacKnight, W. J.: Paper presented at Fall Meeting, ACS, Washington DC (1983)
Lee, W. I., Loos, A. C., Springer, G. S.: J. Comp. Mat. 16, 510 (1982)
Gordon, M., Simpson, W.: Polymer 2, 303 (1961)
Barton, J. M.: Polymer 21, 603 (1980)
Olcese, T., Spelta, O., Vargiu, S.: J. Polym. Sci., Polym. Symp. No. 53, 113 (1975)
Miller, R. L., Oebser, M. A.: Thermochim. Acta 36, 121 (1980)
Barton, J. M.: Brit. Polym. J. 11, 115 (1979)
Barton, J. M.: Unpublished work
Barton, J. M.: Thermochim. Acta 71, 337 (1983)
Grentzer, T. H., Holsworth, R. M., Provder, T., Kline, S.: ACS Polymer Preprints 22, (1), 318 (1981)
Walkup, C. M., Morgan, R. J., Hoheisel, T. H.: ACS Polymer Preprints 25, (1), 187 (1984)
Riccardi, C. C., Adabbo, H. E., Williams, R. J. J.: J. Appl. Polym. Sci. 29, 2841 (1984)
Foun, C. C., Moroni, A., Pearce, E. M., Mijovic, J.: Polym. Mater. Sci. Eng. 51, 411 (1984)
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Barton, J.M. (1985). The application of differential scanning calorimetry (DSC) to the study of epoxy resin curing reactions. In: Epoxy Resins and Composites I. Advances in Polymer Science, vol 72. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-15546-5_5
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DOI: https://doi.org/10.1007/3-540-15546-5_5
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