Abstract
The inorganic analogs of carbon fullerenes and nanotubes, like MoS2 and BN, are reviewed. It is argued that nanoparticles of 2D layered compounds are inherently unstable in the planar configuration and prefer to form closed cage structures. The progress in the synthesis of these nanomaterials, and, in particular, the large-scale synthesis of BN, WS2 and V2O5 nanotubes, are described. Some of the electronic, optical and mechanical properties of these nanostructures are reviewed. The red-shift of the energy gap with shrinking nanotube diameter is discussed as well as the suggestion that zigzag nanotubes exhibit a direct gap rather than an indirect gap, as is prevalent in many of the bulk 2D materials. Some potential applications of these nanomaterials are presented as well, most importantly the superior tribological properties of WS2 and MoS2 nested fullerene-like structures (onions).
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References
H. W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl, R. E. Smalley, Nature (London) 318, 162–163 (1985)
S. Iijima, Nature (London) 354, 56–58 (1991)
R. Tenne, L. Margulis, M. Genut, G. Hodes, Nature (London) 360, 444–445 (1992)
Y. Feldman, Wasserman E., D. J. Srolovitz, R. Tenne, Science 267, 222–225 (1995)
B. C. Satishkumar, A. Govindaraj, E. M. Vogel, L. Basumallick, C. N. R. Rao, J. Mater. Res. 12, 604–606 (1997)
W. Tremel, Angew. Chem. Intl. Ed. 38, 2175–2179 (1999)
M. E. Spahr, P. Bitterli, R. Nesper, F. Kruumeick, H. U. Nissen, et al., Angew. Chem. Int. Ed. 37, 1263–1265 (1998)
A. Rothschild, G. L. Frey, M. Homyonfer, M. Rappaport, R. Tenne, Mater. Res. Innov. 3, 145–149 (1999)
A. Rothschild, J. Sloan, R. Tenne, J. Amer. Chem. Soc. 122, 5169–5179 (2000)
J. Cumings, A. Zettl, Chem. Phys. Lett. 316, 211 (2000)
A. Rubio, J. L. Corkill, M. L. Cohen, Phys. Rev. B 49, 5081–5084 (1994)
N. G. Chopra, A. Zettl, Solid State Commun. 105, 490–496 (1998)
A. Rothschild, S. R. Cohen, R. Tenne, Appl. Phys. Lett. 75, 4025–4027 (1999)
L. Pauling, Proc. Nat. Acad. Sci. 16, 578–582 (1930)
W. M. Gelbart, A. Ben-Shaul, D. Roux (Eds.), Micelles, Membranes, Microemulsions and Monolayers (Springer, New York 1994)
W. Shenton, T. Douglas, M. Young, G. Stubbs, S. Mann, Adv. Mater. 11, 253–256 (1999)
X. Blase, A. Rubio, S. G. Louie, M. L. Cohen, Europhys. Lett. 28, 335 (1994)
M. Remskar, Z. Skraba, F. Cléton, R. Sanjinés, F. Lévy, Appl. Phys. Lett. 69, 351–353 (1996)
M. Remskar, Z. Skraba, M. Regula, C. Ballif, R. Sanjinés, F. Lévy, Adv. Mater. 10, 246–249 (1998)
M. Remskar, Z. Skraba, F. Cléton, R. Sanjinés, F. Lévy, Surf. Rev. Lett. 5, 423–426 (1998)
M. Remskar, Z. Skraba, C. Ballif, R. Sanjinés, F. Lévy, Surf. Sci. 435, 637–641 (1999)
M. Remskar, Z. Skraba, R. Sanjinés, F. Lévy, Appl. Phys. Lett. 74, 3633–3635 (1999)
C. M. Zelenski, P. K. Dorhout, J. Am. Chem. Soc. 120, 734–742 (1998)
Z. Weng-Sieh, K. Cherrey, N. G. Chopra, X. Blase, Y. Miyamoto, A. Rubio, M. L. Cohen, S. G. Louie, A. Zettl, R. Gronsky, Phys. Rev. B 51, 11229 (1995)
N. G. Chopra, J. Luyken, K. Cherry, V. H. Crespi, M. L. Cohen, S. G. Louie, A. Zettl, Science 269, 966 (1995)
C. R. Martin, Acc. Chem. Res. 28, 61–68 (1995)
J. Sloan, J. L. Hutchison, R. Tenne, Y. Feldman, M. Homyonfer, T. Tsirlina, J. Solid State Chem. 144, 100–117 (1999)
E. Iguchi, J. Solid State Chem. 23, 231–239 (1978)
L. Margulis, G. Salitra, R. Tenne, M. Talianker, Nature 365, 113–114 (1993)
H. Nakamura, Y. Matsui, J. Am. Chem. Soc. 117, 2651–2652 (1995)
M. E. Spahr, P. Stoschitzki-Bitterli, R. Nesper, O. Haas, P. Novak, J. Electrochem. Soc. 146, 2780–2783 (1994)
F. Krumeich, H.-J. Muhr, M. Niederberger, F. Bieri, B. Schnyder, R. Nesper, J. Am. Chem. Soc. 121, 8324–8331 (1999)
P. M. Ajayan, O. Stephan, P. Redlich, C. Colliex, Nature 375, 564–567 (1995)
A. Leist, S. Stauf, S. Löken, E. W. Finckh, S. Lüdtke, K. K. Unger, W. Assenmacher, W. Mader, W. Tremel, J. Mater. Chem. 8, 241–244 (1998)
M. Homyonfer, Y. Mastai, M. Hershfinkel, V. Volterra, J. L. Hutchison, R. Tenne, J. Am. Chem. Soc. 118, 7804–7808 (1996)
Y. Mastai, M. Homyonfer, A. Gedanken, G. Hodes, Adv. Mater. 11, 1010–1013 (1999)
K. S. Suslick, S.-B. Choe, A. A. Cichovlas, M. W. Grinstaff, Nature 353, 414–416 (1991)
T. J. Mason, J. P. Lorimer, D. J. Walton, Ultrasonics 28, 333–337 (1990)
A. Durant, J. L. Deplancke, R. Winand, and J. Reisse, Tetrahedron Lett. 36, 4257–4260 (1995)
R. Tenne, M. Homyonfer, Y. Feldman, Chem. Mater. 10, 3225–3238 (1998)
S. Avivi, Y. Mastai, G. Hodes, A. Gedanken, J. Am. Chem. Soc. 121, 4196–4199 (1999)
K. S. Suslick, D. A. Hammerton, R. E. Cline, Jr, J. Am. Chem. Soc. 108, 5641–5642 (1986)
S. Avivi, Y. Mastai, A. Gedanken, J. Am. Chem. Soc. 122, 4331–4334 (2000)
Y. Rosenfeld-Hacohen, E. Grunbaum, R. Tenne, J. Sloan, J. L. Hutchison, Nature (London) 395, 336 (1998)
W. Stöber, A. Fink, E. Bohn, J. Colloid Interface Sci. 26, 62–69 (1968)
H. Nakamura, Y. Matsui, J. Amer. Chem. Soc. 117, 2651–2652 (1995)
T. Kasuga, M. Hiramatsu, A. Hoson, T. Sekino, K. Niihara, Langmuir 14, 3160–3163 (1998)
C. N. R. Rao, B. C. Satishkumar, A. Govindaraj, Chem. Commun. 1581–1582 (1997)
M. R. Ghadiri, J. R. Granja, R. A. Milligan, D. E. McRee, N. Khazanovich, Nature (London) 366, 324–327 (1993)
A. Loiseau, F. Willaime, N. Demoncy, G. Hug, H. Pascard, Phys. Rev. Lett. 76, 4737 (1996)
M. Terrones, W. K. Hsu, H. Terrones, J. P. Zhang, S. Ramos, J. P. Hare, K. Prassides, A. K. Cheetham, H. W. Kroto, D. R. M. Walton, Chem. Phys. Lett. 259, 568–573 (1996)
F. Banhart et al., Chem. Phys. Lett. 269, 349 (1996)
K. Suenaga, C. Colliex, N. Demoncy, A. Loiseau, H. Pascard, F. Willaime, Science 278, 653 (1997)
Y. Zhang, K. Suenaga, S. Iijima, Science 281, 973 (1998)
A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y. H. Lee, S. G. Kim, A. G. Rinzler, D. T. Colbert, G. E. Scuseria, D. Tománek, J. E. Fischer, R. E. Smalley, Science 273, 483–487 (1996)
D. P. Yu et al., Appl. Phys. Lett. 72, 1966 (1998)
J. C. Charlier, S. Iijima, chapter 4 in this volume
Y. K. Kwon, Y. H. Lee, S. G. Kim, P. Jund, D. Tománek, R. E. Smalley, Phys. Rev. Lett. 79, 2065 (1997)
O. Stephan, P. M. Ajayan, C. Colliex, Ph. Redlich, J. M. Lambert, P. Bernier, P. Lefin, Science 266, 1683 (1994)
J. Kouvetakis, T. Sasaki, C. Chen, R. Hagiwara, M. Lerner, K. M. Krishnan, N. Bartlett, Synthetic Mater. 34, 1 (1989)
M. Homyonfer, B. Alperson, Yu. Rosenberg, L. Sapir, S. R. Cohen, G. Hodes, R. Tenne, J. Am. Chem. Soc. 119, 2693–2698 (1997)
P. A. Lee (Ed.), Physics and Chemistry of Materials with Low Dimensional Structures, (Reidel, Dordrecht, New York 1976) p. 447
J. A. Wilson, A. D. Yoffe, Adv. Phys. 18, 193–335 (1969)
J. Moser, F. Lévy, F. Busy, J. Vac. Sci. Technol. A 12, 494–500 (1994)
L. Margulis, P. Dluzewski, Y. Feldman, R. Tenne, J. Microscopy 181, 68–71 (1996)
R. Tenne, Adv. Mater. 7, 965–995 (1995)
P. A. Parilla, A. C. Dillon, K. M. Jones, G. Riker, D. L. Schulz, D. S. Ginley, M. J. Heben, Nature (London) 397, 114 (1999)
Y. Miyamoto, A. Rubio, S. G. Louie, M. L. Cohen, Phys. Rev. B 50, 18360 (1994)
Y. Miyamoto, A. Rubio, M. L. Cohen, S. G. Louie, Phys. Rev. B 50, 4976–4979 (1994)
Y. Miyamoto, A. Rubio, S. G. Louie, M. L. Cohen, Phys. Rev. B 50, 18360–18366 (1994)
F. Jensen, H. Toftlund, Chem. Phys. Lett. 201, 95–98 (1993)
O. Stéphan, Y. Bando, A. Loiseau, F. Willaime, N. Shramcherko, T. Tamiya, T. Sato, Appl. Phys. A 67, 107–111 (1998)
S. Louie, chapter 6 in this volume
M. Cote, M. L. Cohen, D. J. Chadi, Phys. Rev. B 58, R4277–R4280 (1998)
G. Seifert, H. Terrones, M. Terrones, G. Jungnickel, T. Frauenheim, Solid State Commun. 114, 245–248 (2000)
E. Bucher, in Physics and Chemistry of Materials with Layered Structures, Vol. 14, A. Aruchamy (Ed.) (Kluwer Academic, New York 1992) pp. 1–8 1992
G. L. Frey, S. Elani, M. Homyonfer, Y. Feldman, R. Tenne, Phys. Rev. B 57, 6660–6671 (1998)
G. L. Frey, R. Tenne, M. J. Matthews, M. S. Dresselhaus, G. Dresselhaus, J. Mater. Res. 13, 2412–2417 (1998)
F. Consadori, R. F. Frindt, Phys. Rev. B 2, 4893–4896 (1970)
M. W. Peterson, A. J. Nozik, in Physics and Chemistry of Materials with Low Dimensional Structures, Vol. 14, A. Aruchamy (Ed.) (Kluwer Academic, New York 1992) pp. 297–317
G. L. Frey, R. Tenne, M. J. Matthews, M. S. Dresselhaus, G. Dresselhaus, Phys. Rev. B 60, 2883–2893 (1999)
D. J. Srolovitz, S. A. Safran, M. Homyonfer, R. Tenne, Phys. Rev. Lett. 74, 1779–1782 (1995)
Y. Feldman, G. L. Frey, M. Homyonfer, V. Lyakhovitskaya, L. Margulis, H. Cohen, J. L. Hutchison, R. Tenne, J. Am, Chem. Soc. 118, 5362–5367 (1996)
I. L. Singer, in Fundamentals of Friction: Macroscopic and Microscopic Processes, I. L. Singer, H. M. Pollock (Eds.) (Kluwer, Dordrecht 1992) p. 237
F. P. Bowden, D. Tabor, in Friction: An Introduction to Tribology (Anchor, New York 1973)
L. Rapoport, Yu. Bilik, Y. Feldman, M. Homyonfer, S. R. Cohen, R. Tenne, Nature (London) 387, 791–793 (1997)
Y. Golan, C. Drummond, M. Homyonfer, Y. Feldman, R. Tenne, J. Israelachvily, Adv. Mater. 11, 934–937 (1999)
L. Rapoport, Y. Feldman, M. Homyonfer, H. Cohen, J. Sloan, J. L. Hutchinson, R. Tenne, Wear 225–229, 975–982 (1999)
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Tenne, R., Zettl, A.K. (2001). Nanotubes from Inorganic Materials. In: Dresselhaus, M.S., Dresselhaus, G., Avouris, P. (eds) Carbon Nanotubes. Topics in Applied Physics, vol 80. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-39947-X_5
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