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Boron Nitrides — Properties, Synthesis and Applications

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High Performance Non-Oxide Ceramics II

Part of the book series: Structure and Bonding ((STRUCTURE,volume 102))

Abstract

Boron nitride is a extraordinary topic in the area of materials science. Due to the special bonding behaviors of boron and nitrogen the BN exists in many different structures. The well-defined crystallographic structures are hexagonal BN (h-BN), rhombohedral BN (r-BN), wurtzitic BN (w-BN), and cubic BN (c-BN). Additionally, other crystalline and amorphous structures exist. Exceptional is that there are still discussions about the BN phase diagram. In the present stage c-BN is the stable phase at standard conditions but exact data about the phase transition line are not yet available. Synthesis of h-BN powders and coatings is described as well as applications of BN in ceramic materials and as lubricant. For c-BN the high-pressure high-temperature synthesis for powder production is discussed, and an overview about applications in wear resistant ceramics (polycrystalline c-BN) is given. The low-pressure methods for nano-cBN deposition (PVD and Plasma CVD) are described.

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  1. Institute for Chemical Technology of Inorganic Materials, University of Technology Vienna, Getreidemarkt 9/161, 1060, Vienna, Austria

    M. Wilhelm, R. Weissenbacher & B. Lux

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  1. R. Haubner
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  2. M. Wilhelm
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  1. Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, 70569, Stuttgart, Germany

    Martin Jansen

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Haubner, R., Wilhelm, M., Weissenbacher, R., Lux, B. (2002). Boron Nitrides — Properties, Synthesis and Applications. In: Jansen, M. (eds) High Performance Non-Oxide Ceramics II. Structure and Bonding, vol 102. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45623-6_1

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