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Activation of C-O Bonds: Stoichiometric and Catalytic Reactions

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Activation of Unreactive Bonds and Organic Synthesis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 3))

Abstract

The C-O bond cleavage promoted by transition metal complexes is becoming an important process in organic synthesis. A survey of the stoichiometric reactions involving activation of the C-O bond by transition metal complexes as well as their synthetic applications is provided. After a survey of recent reports on the cleavage of allylic C-O bond that has been extensively utilized in organic synthesis the review focuses on the cleavage of single C-O bonds in esters, ethers, and anhydrides activated by transition metals. The cleavage of C-O multiple bonds is also discussed.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Science and Engineering, Advanced Research Center for Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo, 169-8555, Japan

    Yong-Shou Lin & Akio Yamamoto

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  1. Yong-Shou Lin
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  2. Akio Yamamoto
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  1. Department of Applied Chemistry Faculty of Engineering, Osaka University, Yamadaoka 2-1, Suita shi, Osaka, 565-0817

    Shinji Murai

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Lin, YS., Yamamoto, A. (1999). Activation of C-O Bonds: Stoichiometric and Catalytic Reactions. In: Murai, S., et al. Activation of Unreactive Bonds and Organic Synthesis. Topics in Organometallic Chemistry, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68525-1_7

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  • DOI: https://doi.org/10.1007/3-540-68525-1_7

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