Abstract
We discuss bridging between a grafted layer and an opposing plate which adsorbs the polymer. The case of end adsorption is considered, as well as the case where all monomers adsorb. We predict that with increasing adsorption an exclusion zone grows in the vicinity of the adsorbing plate, this slows down the kinetics. For end adsorption we study the kinetics and argue that two main processes are involved: the exploration of the brush by a free end and its adsorption through the exclusion zone.
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References
Napper, D.H Polymeric Stabilization of Colloidal Dispersions Academic Press London, 1983.
de Gennes, P.G. Macromolecules 1980, 13, 1069.
Alexander, S. J. Phys. (Paris) 1977, 38, 983.
de Gennes, P.G. “Solid State Physics” Seitz and Turnbull Eds. Academic Press N.Y. Sppl. 1 1978.
Milner, S., Witten, T. Cates, M Macromolecules 1988, 21, 2610
Zhulina, Ye Pryamitsin, V.A. and Borisov, O.V. Polymer Science (USSR) 198 31, 205.
Semenov, Sov. Phys. JETP 1985, 61, 733.
JI, H. Hone, D. Pincus, P. Rossi, G. Macromolecules 1990, 23, 698.
Milner, S. Witten, T.A. Preprint 1992.
Ligoure, C. Leibler, L. in preparation
Dai, L. Topralccioglu, C. Europhys. Lett. 1991, 16, 331.
Dai, L. Topralccioglu, C. Preprint 1992.
Doi, M Edwards, S.F. The Theory of Polymer Dynamics Clarendon Press: Oxford 1986.
de Gennes, P.G. “first Toyota conf.“ Studies in polymer Science 2, 315,1988. Academic Press N.Y. Sppl. 1 1978.
Varoqui, R. Pefferkorn, E. Journal of Colloid and Interface Science 1985, 109, 520.
Ligoure, C. Leibler, L. J. Phys. (Paris) 1990, 51, 1313.
Milner, S. Preprint 1992.
Johner, A. Joanny, J.F. Macromolecules 1990, 23, 5299.
Klushin, L.I. Skvortzov, A.M. Macromolecules 1991, 24, 1549.
Murat, M Crest, G. Macromolecules 1989, 22, 4054.
Lai, P.Y. Binder,K. preprint 1992.
Eisenriegler, E. Binder, K. Kremer, K. J. Chem. Phys. 1982, 77, 6296.
Pincus, P. de Gennes, P.G. Phys. Lett. 1983, 44, 241.
de Gennes, P.G. “Scaling Concepts in Polymer Physics Cornell Ythaca 1985.
de Gennes, P.G. Rep. Prog. Phys. 1987, 32, 187.
Milner, S. Zhen Gang Wang and Witten, T. Macromolecules 1989, 22, 489.
Johner, A. Joanny, J.F. Europhys. Lett. 1991, 15, 265.
Johner, A. Joanny, J.F. J. Chem. Phys. 1992, 96, 6257.
Van Kampen, N.G. Stochastic Processes in Physic and Chemistry North Holland 1981.
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© 1993 Springer-Verlag
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Johner, A. (1993). Bridging in grafted layers : Statics and kinetics. In: Garrido, L. (eds) Complex Fluids. Lecture Notes in Physics, vol 415. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3540563962_76
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DOI: https://doi.org/10.1007/3540563962_76
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