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Cathodes Based on Lico02 and Lini02

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Lithium Batteries

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Li-ion cells consisting of LiMe02 (Me: a 3d-transition metal element) and carbon materials have been of interest because of their capability to be safely operated for thousands of cycles whilst retaining a high energy density. Materials with the above formula more extensively examined for positive electrodes include LiCo02, LiNi02, LiCoi1-x Ni x O2 and LiMn02. Among these, more research has been done on LiCo02 because of its high energy density and good cycling performance. The electrochemical properties of cathodes based on LiCo02 are shown in Table 14.1.1–5 LiCo02 has served as an archetypal cathode material for secondary Li batteries ever since the discovery by Mizushima et al 6 that Li can be reversibly removed (deintercalated) from and reinserted (intercalated) into Li x Co02. The layered form of LiCoO2, which has a rhombohedral symmetry belonging to the space group R3m, is ideally suited to accommodate large changes of the Li content, x. This crystal structure consists of close-packed oxygen layers stacked in an ABCABC sequence with Co and Li ions residing in octahedral sites in alternating layers between the oxygen planes.7 Figure 14.1 illustrates the crystal structure of LiCo02. As the Li concentration is changed in Li x Co02, vacancies are either created or filled within the Li planes.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Research Center for Energy Conversion and Storage, Seoul National University, Seoul, Korea

    Byungwoo Park & Yong Jeong Kim

  2. Department of Applied Chemistry, Kumoh National Institute of Technology, Gumi, Korea

    Jaephil Cho

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  1. Byungwoo Park
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Editors and Affiliations

  1. General Motors R&D and Planning Center, MC 480-102-RCEL, 30500 Mound Road, Warren, MI 48090-9055, USA

    Gholam-Abbas Nazri

  2. Via G. Scalia, Rome, 1000136, Italy

    Gianfranco Pistoia

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Park, B., Kim, Y.J., Cho, J. (2009). Cathodes Based on Lico02 and Lini02 . In: Nazri, GA., Pistoia, G. (eds) Lithium Batteries. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-92675-9_14

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