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Gas Phase Studies of Catalytic Processes Involving Vmon Clusters and their Reaction with Alcohols, Alkenes, Nox, and Nh3 Using a Desk-Top Size Soft X-Ray Laser

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X-Ray Lasers 2008

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 130))

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Abstract

Reactions of neutral vanadium oxide clusters with (1) methanol, ethanol, (2) alkenes, and (3) NOx and NH3, in a flow tube reactor, are investigated by time of flight mass spectroscopy experiments and density functional theory (DFT). Single photon ionization through using a compact soft x-ray (46.9 nm, 26.5 eV) laser is employed to detect both neutral cluster distributions and reaction products. Results and insights to catalytic processes are presented.

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Author information

Authors and Affiliations

  1. NSF ERC for Extreme Ultraviolet Science and Technology, Colorado State University, USA

    S. Heinbuch, F. Dong, E. R. Bernstein & J. J. Rocca

  2. Department of Electrical and Computer Engineering, Colorado State University, USA

    S. Heinbuch & J. J. Rocca

  3. Department of Chemistry, Colorado State University, USA

    F. Dong & E. R. Bernstein

  4. Department of Physics, Colorado State University, USA

    J. J. Rocca

Authors
  1. S. Heinbuch
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  2. F. Dong
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  3. E. R. Bernstein
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  4. J. J. Rocca
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Editor information

Editors and Affiliations

  1. Department of Physics and Astronomy, Queen's University Belfast, University Road, Belfast, BT7 1NN, UK

    Ciaran L. S. Lewis  & Dave Riley  & 

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Heinbuch, S., Dong, F., Bernstein, E.R., Rocca, J.J. (2009). Gas Phase Studies of Catalytic Processes Involving Vmon Clusters and their Reaction with Alcohols, Alkenes, Nox, and Nh3 Using a Desk-Top Size Soft X-Ray Laser. In: Lewis, C.L.S., Riley, D. (eds) X-Ray Lasers 2008. Springer Proceedings in Physics, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9924-3_52

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