Abstract
Synthetic organic polymers are predominantly based on chains of carbon atoms and have tremendous technological utility. The presence of transition metal elements in the main chain of a polymer is expected to lead to macromolecules which combine processability with novel physical or catalytic properties. To date the preparation of transition metal-based polymers in which the metal atoms are held in close proximity so as to promote interactions has been dominated by synthetic problems and examples of soluble, well-defined, and well-characterized materials of reasonable molecular weight (Mn > 104) are very rare.1
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Sheats, J. E.; Carraher, C. E.; Pittman, C. U. Metal Containing Polymer Systems; Plenum: New York, 1985.
Foucher, D. A.; Tang, B.-Z.; Manners, I. J. Am. Chem. Soc. 1992, 114, 6246–6248.
Manners, I. Adv. Organomet. Chem. 1995,37, 131.
Osborne, A. G.; Whiteley, R. H. J. Organomet. Chem. 1975, 101, C27.
Fischer, A. B.; Kinney, J. B.; Staley, R. H.; Wrighton, M. S. J. Am. Chem. Soc. 1979, 101, 6501–6506.
Stoeckli-Evans, H.; Osborne, A. G.; Whitely, R. H. Helv. Chim. Acta. 1976, 59, 2402–2406.
Schleyer, P. v. R.; Williams, J. E.; Blanchard, K. R. J. Am. Chem. Soc. 1970, 92, 2377–2386.
Foucher, D.; Ziembinski, R.; Petersen, R.; Pudelski, J.; Edwards, M.; Ni, Y.; Massey, J.; Jaeger, C. R.; Vancso, G. J.; Manners, I. Macromolecules 1994, 27, 3992–3999.
Foucher, D. A.; Ziembinski, R.; Tang, B.-Z.; Macdonald, P. M.; Massey, J.; Jaeger, C. R.; Vancso, G. J.; Manners, I. Macromolecules 1993, 26, 2878–2884.
Rasburn, J.; Petersen, R. J.; Jahr, T.; Rulkens, R.; Manners, I.; Vancso, G. J., unpublished results.
Rulkens, R.; Lough, A. J.; Manners, I. J. Am. Chem. Soc. 1994, 116, 797–798.
Hmyene, M.; Yassar, A.; Escorne, M.; Percheron-Guegan, A.; Gamier, F. Adv. Mater. 1994, 6, 564.
Withers, H. P.; Seyferth, D.; Fellmann, J. D.; Garrou, P. E.; Martin, S. Organometallics 1982, 1, 1283–1288.
Rulkens, R.; Ni, Y.; Manners, I. J. Am. Chem. Soc. 1994, 116, 12121.
Foucher, D. A.; Edwards, M.; Burrow, R. A.; Lough, A. J.; Manners, I. Organometallics 1994, 13, 4959.
Nelson, J. M.; Rengel, H.; Manners, I. J. Am. Chem. Soc. 1993, 115, 7035–7036.
Foucher, D. A.; Honeyman, C. H.; Nelson, J. M.; Tang, B.-Z.; Manners, I. Angew. Chem. Int. Ed. Engl. 1993, 32, 1709–1711.
Nelson, J. M.; Lough, A. J.; Manners, I. Angew. Chem. Int. Ed. Engl. 1994, 33, 989–991.
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© 1996 Springer Science+Business Media New York
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Pudelski, J.K., Foucher, D.A., Manners, I. (1996). Ring-Opening Polymerization (ROP) of Strained Metallocenophanes. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_2
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