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Substitution Reactions of Labile Metal Complexes

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Mechanisms of Inorganic and Organometallic Reactions

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Abstract

Solvent exchange on metal ions is the simplest ligand substitution process, and in many respects it is the most important to mechanistic understanding as most ligand substitution processes involve the displacement of coordinated solvent. Accordingly much effort has been devoted to the determination of the mechanisms of solvent exchange on metal ions, and the activation volume, ΔV ≠, has emerged as the key indicator of mechanism. Hence a timely review by Merbach, in which he describes the outstanding work of his group in the variable-pressure study of solvent exchange, the construction of high-pressure NMR probes, the treatment of variablepressure kinetic data, and the mechanistic interpretation of ΔV ≠, is particularly interesting. (1) Given the importance of ΔV ≠ to mechanistic interpretation, it is not surprising that some 800 references to ΔV ≠ studies appear in a book(2) on the application of high pressure to the investigation of inorganic reaction mechanisms, and that ΔV ≠ data feature prominently in a review of recent developments in the mechanisms of reactions of metal complexes.(3)

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    M. V. Twigg

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    M. V. Twigg

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Twigg, M.V. (1989). Substitution Reactions of Labile Metal Complexes. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0827-0_9

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  • DOI: https://doi.org/10.1007/978-1-4613-0827-0_9

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