Abstract
Nitrogen sorbed phase on silicalite I undergoes two phase transitions. We have determined by neutron diffraction the structural properties of the three N2 sorbed phases involved in the transitions. The first one is a disordered mobile phase, the second one a lattice fluid phase and the third one a commensurate crystalline solid phase. The same three phases have been also observed by neutron diffraction during the sorption of N2 on ZSM-5 (Si / Al = 23).
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© 1996 Kluwer Academic Publishers
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Coulomb, J.P., Llewellyn, P., Martin, C., Grillet, Y., Rouquerol, J. (1996). Structural Analysis by Neutron Diffraction of Nitrogen Sorbed Phases on Silicalite I and ZSM-5 (Si / Al = 23) Zeolites. In: LeVan, M.D. (eds) Fundamentals of Adsorption. The Kluwer International Series in Engineering and Computer Science, vol 356. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1375-5_25
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DOI: https://doi.org/10.1007/978-1-4613-1375-5_25
Publisher Name: Springer, Boston, MA
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