Skip to main content

Applications of the Mössbauer Effect in Electrolysis

  • Chapter
Industrial Applications of the Mössbauer Effect

Abstract

During electrolysis ions are removed from the electrolytic Solution as the electrolytic processes occur at the electrode-electrolyte interfaces. The processes are heterogeneous reactions accompanied by the transfer of electric Charge across the interface. As a consequence of these generally complicated multistep cathodic and anodic reactions, neutral atoms or molecules are formed on the electrode surfaces. Recently Mössbauer spectroscopy has been successfully applied to the study of these products not only under ex situ, but also under in situ conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. H. Leidheiser, Jr., A. Vèrtes, M. L. Varsànyi, I. Nagy-Czakò, J. Electrochem. Soc. 126, 391 (1979).

    Article  Google Scholar 

  2. M. Antler, in “Gold Plating Technology”, F. H. Reid and W. Goldie, eds., Electrochemistry Publications, Ltd. Ayr, Scotland, pp. 259–294 (1974).

    Google Scholar 

  3. W. A. Styert and R. D. Taylor, Phys. Rev. 134, A716 (1964).

    Article  Google Scholar 

  4. C. F. Steen, D. G. Howard, and R. H. Nussbaum, Solid State Commun. 9, 865 (1971).

    Article  Google Scholar 

  5. G. W. Simmons, E. Kellerman, and H. Leidheiser, Jr., J. Electrochem. Soc. 123, 1276 (1976).

    Article  Google Scholar 

  6. Y. Okinaka and S. Nakahara, J. Electrochem. Soc. 123, 1284 (1976).

    Article  Google Scholar 

  7. Y. Okinaka, F.B. Koch, C. Wolowodiuk, and D. R. Blessington, J. Electrochem. Soc. 125, 348C (1978).

    Article  Google Scholar 

  8. R. L. Cohen, K. W. West, M. Antler, J. Electrochem. Soc. 124, 342 (1977).

    Article  Google Scholar 

  9. R. L. Cohen, F. B. Koch, L. N. Schoenberg, K. W. West, J. Electrochem. Soc. 126, 1608 (1979).

    Article  Google Scholar 

  10. R. Schubert, J. Electrochem. Soc. 128, 126 (1981).

    Article  Google Scholar 

  11. T. Adaniya, M. Ohmura, Metall. 31, 1100 (1977).

    Google Scholar 

  12. T. Adaniya, Steel Metal Indus. Iner. 55, 73 (1978).

    Google Scholar 

  13. H. Leidheiser, Jr., A Vèrtes, M. L. Varsànyi, J. Electrochem. Soc. 128, 1456 (1981).

    Article  Google Scholar 

  14. H. Leidheiser, Jr., G. W. Simmons, S. Nagy, S. Music, J. Electrochem. Soc. 129, 1658 (1982).

    Article  Google Scholar 

  15. R. Bocker and W. Döring, “Ferromagnetism”, Springer, Berlin, 1939.

    Google Scholar 

  16. R. M. Bozorth, “Ferromagnetism”, D. van Nostrand Co., Princeton, NJ, 1951.

    Google Scholar 

  17. S. Chikazumi, “Physics of Magnetism”, J. Wiley and Sons, New York City, 1964.

    Google Scholar 

  18. F. Denise, H. Leidheiser, Jr., J. Electrochem. Soc. 100, 490 (1953).

    Article  Google Scholar 

  19. L. Takàcs, A. Vertes, H. Leidheiser, Jr., Physica Status Solidi 74, K45 (1982).

    Article  Google Scholar 

  20. A. Vèrtes, Zs. Kajcsos, Cs. Szeles, I. Czakò-Nagy, M. Lakatos-Varsànyi, H. Leidheiser, Jr., Proceedings of the Sixth International Conference on Positron Annihilation, Arlington, Texas, (USA) April 2–7, 1982.

    Google Scholar 

  21. A. Vèrtes, Zs. Kajcsos, I. Czakò-Nagy, M. Lakatos-Varsànyi, L. Csordäs, G. Brauer, H. Leidheiser, Jr., Nuclear Instruments and Methods 199, 353 (1982).

    Article  Google Scholar 

  22. H. Leidheiser, Jr., A. Vèrtes, I.Czakò-Nagy, M. Lakatos-Varsànyi, L. Csordàs, Zs. Kajcsos, 33rd Meeting of the International Society of Electrochemistry, Lyon, France, September 6–10, 1982.

    Google Scholar 

  23. N. Parkinson, C. S. Britton, and R. Angles, Sheet Met. Ind. 28, 1 (1951).

    Google Scholar 

  24. M. Clarke and C. S. Britton, Corr. Sei. 3, 207 (1963).

    Article  Google Scholar 

  25. M. Antler, M. Feder, C. F. Hornig, and J. Bohland, Plating Surf. Finish. 63, 30 (1976).

    Google Scholar 

  26. H. Leidheiser, Jr., I. Czakö-Nagy, M. L. Varsänyi, A. Vertes, J. Electrochem. Soc. 126, 204 (1979).

    Article  Google Scholar 

  27. J. W. Cuthbertson, N. Parkinson, and H. P. Rooksby, J. Electrochem. Soc. 100, 107 (1953).

    Article  Google Scholar 

  28. C. P. Thwaites, Trans. Inst. Metal Finish, 3, 203 (1959).

    Google Scholar 

  29. J. Silver, C. A. Mackay, F. D. Donaldson, J. Materials Science 11, 836 (1976).

    Article  Google Scholar 

  30. J. Jaèn, M. L. Varsànyi, Kovàcs, I. Czakò-Nagy, A. Buzàs, A. Vèrtes, and L. Kiss, Electrochim. Acta 29, 1119 (1986).

    Article  Google Scholar 

  31. A Vèrtes, J. Jaèn, M. L. Varsànyi, Radioanal, and Nucl. Chem. 90, 383 (1985).

    Article  Google Scholar 

  32. O. K. Kudra, V. S. Galinker, and M. N. Nasonova, Ukr. Chim. Zhurn, 38, 875 (1972).

    Google Scholar 

  33. V. S. Galinker, O. K. Kudra, and M. N. Nasonova, Zashcita Metallov 8, 221 (1972).

    Google Scholar 

  34. J. Jaèn, A. Vèrtes, K. M. Tjutina, L. V. Kasmodamianskaya, L. Kiss, and L. V. Shepeleva, Electrochim. Acta 30, 535 (1985).

    Article  Google Scholar 

  35. A. Vèrtes, S. Nagy, M. Lakatos-Varsànyi, International Conference on the Application of Mössbauer Spectroscopy, Jaipur, India, December 14–18, 1981.

    Google Scholar 

  36. R. L. Cohen, C. J. Raub, T. Muramaki, J. Electrochem. Soc. 125, 34 (1978).

    Article  Google Scholar 

  37. H. Mehner and A. Vertes, Proceedings of the Int. Conf. on the Application of the Mössbauer Effect, pp. 780–781, Jaipur, India, December 14–18, 1981.

    Google Scholar 

  38. A. Vèrtes, S. Nagy, M. Z. Awad, Nuclear Instruments and Methods 199, 367 (1982).

    Article  Google Scholar 

  39. J. Jaèn, A. Pashovsky, G. Raichevsky, I. Czakò-Nagy, L. Kiss, and A. Vèrtes, Radiochem. Radioanal. Letters 58, 111 (1983).

    Google Scholar 

  40. A. T. Tsinman and A. N. Katrevich, Zashchita Metallov 5, 517 (1969).

    Google Scholar 

  41. A. T. Tsinman, L. M. Pischik, V. M. Brusentsova, L. E. Zanarenkova, Zashchita Metallov 7, 700 (1971).

    Google Scholar 

  42. Ya. M. Kolotirkin, G. G. Kossii, Zashchita Metallov 1, 272 (1965).

    Google Scholar 

  43. L. Kiss, D. N. Lien, and M. L. Varsànyi, Coli. Czechosl. Chem. Com. 36, 914 (1971).

    Google Scholar 

  44. G. W. Simmons, A. Vèrtes, M. L. Varsänyi, and H. Leidheiser, Jr., Electrochem. Soc. 126, 188 (1979).

    Google Scholar 

  45. W. E. O’Grady, J. Electrochem. Soc. 127, 555 (1980).

    Article  Google Scholar 

  46. M. C. Lin, R. G. Barnes, and T. E. Furtak, AIP Conference Proceedings No. 84, F. C. Schwerer, ed., American Institute of Physics, New York, 1982.

    Google Scholar 

  47. G. N. Markosyan, L. Sziràki, A. I. Molodov, L. M. Versànyi, V. V. Losev, J. Jaèn, A. Vèrtes, and L. Kiss, to be published in Elektrokhimiya (1986).

    Google Scholar 

  48. F. H. Chibirova, T. V. Revina, V. A. Makarov, and S. I. Reiman, Zaschcita Metallov 18, 905 (1982).

    Google Scholar 

  49. Y. Geronov, T. Tomov, S. Georgiev, J. Appl. Electrochem. 5, 351 (1975).

    Article  Google Scholar 

  50. J. Blomquist, U. Helgeson, L. C. Moberg, L. Y. Johansson, and R. Larson, Electrochim. Acta 21, 1445 (1982) and 27, 1453 (1982).

    Article  Google Scholar 

  51. D. Scherson, S. B. Yao, E. B. Yeager, J. Eldridge, M. E. Kordesch, and R. W. Hoffman, J. Phys. Chem. 87, 932 (1983).

    Article  Google Scholar 

  52. D. Scherson, C. Fierro, E. B. Yeager, M. E. Kordesch, J. Eldridge, and R. W. Hoffman, International Soc. of Electrochemistry 34th Meeting, Erlangen, Germany, September 18–23, 1983.

    Google Scholar 

  53. R. Korr, J. Soc. Chem. Ind. 57, 405 (1938).

    Google Scholar 

  54. D. Bianchi, Chim. Ind. 29, 295 (1947).

    Google Scholar 

  55. S. E. S. El Wakkad, A. M. Shams El Din, and J. A. El Sayd, J. Chem. Soc. 3103 (1954).

    Google Scholar 

  56. M. Katoh, Bull. Chem. Soc. Japan 35, 1711 (1962).

    Article  Google Scholar 

  57. S. N. Shah and D. E. Davies, Electrochim. Acta 8, 663 (1963).

    Article  Google Scholar 

  58. A. M. Shams El Din and F. M. A. El Wakab, Electrochim. Acta 9, 883 (1963).

    Article  Google Scholar 

  59. N. A. Hampson and N. E. Spencer Br., Corrosion J. 3, 1 (1986).

    Google Scholar 

  60. D. E. Davies and S. N. Shah, Electrochim. Acta 8, 703 (1963).

    Article  Google Scholar 

  61. M. Pugh, L. M. Warner, and D. R. Gabe, Corrosion Science 7, 807 (1967).

    Article  Google Scholar 

  62. A. Vèrtes, H. Leidheiser, Jr., M. L. Varsànyi, G. W. Simmons, and L. Kiss, J. Electrochem. Soc. 125, 1946 (1978).

    Article  Google Scholar 

  63. R. L. Cohen, C. J. Raub, and T. Muramaki, J. Electrochem. Soc. 125, 34 (1978).

    Article  Google Scholar 

  64. S. D. Kapusta and N. Hackerman, Electrochim. Acta 25, 1625 (1980).

    Article  Google Scholar 

  65. M. L. Varsànyi, J. Jaèn, A. Vèrtes, and L. Kiss, to be published in Electrochim. Acta (1986).

    Google Scholar 

  66. W. D. Honnick and J. J. Zuckerman, Inorg. Chem. 15, 3034 (1976).

    Article  Google Scholar 

  67. J. Jaèn, Ph.D. Dissertation, Eötvös University, Budapest, 1984.

    Google Scholar 

  68. H. Mehner, J. Juhàsz, M. Suba, and A. Vèrtes, Radiochem. Radioanal. Letters 56, 57 (1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Plenum Press, New York

About this chapter

Cite this chapter

Vèrtes, A., Czakò-Nagy, I., Varsànyi, M.L. (1986). Applications of the Mössbauer Effect in Electrolysis. In: Long, G.J., Stevens, J.G. (eds) Industrial Applications of the Mössbauer Effect. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1827-9_39

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-1827-9_39

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9021-6

  • Online ISBN: 978-1-4613-1827-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics