Abstract
The water gas shift reaction is catalyzed by numerous metals and oxides. Thus, in any environment containing CO and H2O, or CO2 and H2, the water gas shift reaction,
, or its reverse, the water gas reaction, may occur. The water gas shift is used to regulate H2 and CO concentrations in synthesis gas, and it occurs as part of synthesis gas reactions such as the Fischer-Tropsch synthesis, in which CO and H2 are starting materials, and CO2 and H2O may be products. At typical synthesis gas reaction temperatures, the equilibrium constant for the water gas shift is close enough to unity and the reaction proceeds rapidly enough that all four species can be expected to be present. The economics of synthesis gas reactions usually require that oxygen rejection be via H2O rather than CO2; therefore, control of the oxygen-carrying product through the water gas shift may be desirable.
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Rofer-DePoorter, C.K. (1984). Untangling the Water Gas Shift from Fischer-Tropsch: A Gordian Knot?. In: Herman, R.G. (eds) Catalytic Conversions of Synthesis Gas and Alcohols to Chemicals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2737-0_6
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