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Kinetics of Degenerate Nucleophilic Exchange Of C(3)-Hydroxy Group in 1-Methyl-3-Hydroxy-5-Phenyl-7-Cloro-2H-1,4-Benzodiazepin-2-One

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Recent Developments in Mass Spectrometry in Biochemistry and Medicine

Abstract

Recently (1–3) we studied configurational stability of the chiral centre and mechanisms of the acid-catalysed solvolytic racemization in C(3)-oxy 5-phenyl-7-cloro-2H-1,4-benzodiazepin-2- -ones 1-3 - see general formula.

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References

  1. M. Štromar, V. Šunjic, T. Kovać, L. Klasinc and F. Kajfež, Croat. Chem. Acta, 1974, 46, 267.

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  2. V. Šunjić, R. Dejanović, A. Palković, L. Klasinc and F. Kajfež, Tetrahedron Lett., 1976, p. 4493.

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  3. V. Šunjić, A. Lisini, T. Kovać, B. Belin, F. Kajfež and L. Klasinc, Croat. Chem. Acta, 1977, 49, 505.

    Google Scholar 

  4. D. Thon and W. Schneider, Chem. Ber., 1976, 109, 2743.

    Google Scholar 

  5. G. Toth, G. Hornyak and K. Lempert, Chem. Ber. 1977, 110, 1492.

    Article  Google Scholar 

  6. V. Šunjic, F. Kajfež, D. Kolbah and N. Blaževic, Croat. Chem. Acta, 1971, 43, 205.

    Google Scholar 

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© 1979 Plenum Press, New York

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Srzić, D., Klasinc, L., Belin, B., Kajfež, F., Šunjić, V. (1979). Kinetics of Degenerate Nucleophilic Exchange Of C(3)-Hydroxy Group in 1-Methyl-3-Hydroxy-5-Phenyl-7-Cloro-2H-1,4-Benzodiazepin-2-One. In: Frigerio, A. (eds) Recent Developments in Mass Spectrometry in Biochemistry and Medicine. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3018-9_12

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  • DOI: https://doi.org/10.1007/978-1-4613-3018-9_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3020-2

  • Online ISBN: 978-1-4613-3018-9

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