Abstract
Exclusion chromatography (GPC) has been applied to a number of solute-solvent pairs previously identified as “reversed micellar” systems. Observed retention times are short relative to those expected for free solute species, especially when initial solute concentrations are high. This effect can be ascribed to the reduced permeation of aggregates present during chromatography.
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The experimental work reported here was done at Dynapol, Palo Alto, Calif, and at Memorex Corp., Santa Clara, Calif.
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Dubin, P.L. (1982). Observation of Amphiphilic Association in Nonaqueous Solvents by Exclusion Chromatography. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3494-1_6
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DOI: https://doi.org/10.1007/978-1-4613-3494-1_6
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