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Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry and Catalysis

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Homogeneous Catalysis with Metal Phosphine Complexes

Part of the book series: Modern Inorganic Chemistry ((MICR))

Abstract

The prospect of predictably manipulating the chemo- and stereoselectivity of metal catalysts is both aesthetically and economically attractive. The most straightforward way to affect the chemical behavior of a given metal ion is through changes in its ligands. It is well recognized that changes within the first coordination sphere of a metal ion can have a relatively dramatic impact on the properties of the entire complex. On the other hand, modifications of the ligand superstructure and substituents have subtler and somewhat more predictable effects. Such ligand modifications as applied to the coordination chemistry of tertiary phosphines have begun to receive increasing attention because of the applicability of this technology to catalysis. In this chapter, I discuss several studies which have concerned the coordination chemistry of tertiary phosphine ligands which bear chemically active substituents. This review is not comprehensive, rather the ligand systems discussed were selected because of the novel properties they impart to their complexes, the usefulness of their complexes in mechanistic or catalytic studies, or their synthetic versatility. Areas related to the theme of this review which were intentionally de-emphasized are di- and polyphosphines, chiral phosphines, and polymer-bound phosphines. These topics are covered more fully in other chapters of this book.

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Authors and Affiliations

  1. School of Chemical Sciences, University of Illinois, Urbana-Champaign, 61801, Illinois, USA

    Dr. Thomas B. Rauchfuss

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  1. Dr. Thomas B. Rauchfuss
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Editors and Affiliations

  1. University of Minnesota, Minneapolis, Minnesota, USA

    Louis H. Pignolet

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© 1983 Plenum Press, New York

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Rauchfuss, T.B. (1983). Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry and Catalysis. In: Pignolet, L.H. (eds) Homogeneous Catalysis with Metal Phosphine Complexes. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3623-5_7

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  • DOI: https://doi.org/10.1007/978-1-4613-3623-5_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3625-9

  • Online ISBN: 978-1-4613-3623-5

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