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Novel Dispersions of Iron in Amorphous Glasslike Carbons: Exploratory Magnetic Studies

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Amorphous Magnetism

Abstract

One of us (LNM) reported extensive studies on the super-paramagnetic behavior of dispersions of iron species (atoms, ions) in the silicate1–3 and zeolite type matrices4. In a search for novel methods for dispersing iron, this author noticed the possibility of dispersing Fe species in a diamagnetic carbon host lattice. As such this exploratory work was undertaken. A number of samples of amorphous glasslike carbon containing iron were supplied to us by Professor R. Kammareck++ and Dr. Nakamizo. A schematic of their synthesis is shown in the following diagram.

Work supported by the Advanced Research Projects Agency [ARPA-DAH15 17 C 0290]

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References

  1. D.W. Collins and L.N. Mulay, J. Amer. Ceram. Soc. 64, 69 (1971); 54, 52 (1971); 53, 74 (1970).

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  2. D.W. Collins, L.N. Mulay and W.F. Fisher, Bull. Amer. Soc. 44, 343 (1965); Jap. J. Appl. Phys. 6, 1342 (1967).

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  3. D.W. Collins, J.T. Dehn and L.N. Mulay, “Superparamagnetism and Mössbauer Spectroscopy”, in Mössbauer Methodology, Vol. III, Ed. I.J. Gruverman, Plenum Press, New York, 1967.

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  4. Another paper on the dispersion of iron in zeolite appears in this Proceedings volume.

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  5. R.A. Butera, R.S. Craig and L.R. Cherry, Rev. Sci. Instr. 32, 708 (1961).

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© 1973 Plenum Press

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Thompson, A.W., Walker, P.L., Mulay, L.N. (1973). Novel Dispersions of Iron in Amorphous Glasslike Carbons: Exploratory Magnetic Studies. In: Hooper, H.O., de Graaf, A.M. (eds) Amorphous Magnetism. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4568-8_10

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  • DOI: https://doi.org/10.1007/978-1-4613-4568-8_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4570-1

  • Online ISBN: 978-1-4613-4568-8

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