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Transparent Electrically Conductive Composites by In-Situ Crystallization of (TSet)2Cl in a Polymer Matrix

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Advances in New Materials

Part of the book series: Contemporary Topics in Polymer Science ((CTPS,volume 7))

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Abstract

A new chemical pathway was found which offers access to the thermostable, highly conductive tetraselenotetracene chloride radical cation salt (TSeT)2Cl. This pathway allows the in-situ crystallization of (TSeT)2Cl in a vitrifying polymer matrix. So highly conductive films (σ= 1–5 Scm-1) with networks of (TSeT)2Cl crystallites of a 1: 1000 aspect ratio could be prepared at a fairly low percolation threshold of 0.4 – 1.6 % w/w. These films show metallic conductivity behavior in the 60 – 400 K range.

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References

  1. M. Kryszewski, J. K. Jeszka, J. Ulanski and A. Tracz, Pure Appl. Chem. 56 (1984) 355–368

    Article  CAS  Google Scholar 

  2. Eur. Pat. Appl. EP 285564 Al (1988) to Ciba Geigy AG, Inv. J. Finter, B. Hilti, C. W. Mayer, E. Minder and J. Pfeifer

    Google Scholar 

  3. A. Tracz and M. Kryszewski, Makromol. Chem. Suppl. 15 (1989) 219–231

    Article  CAS  Google Scholar 

  4. J. Finter, C. W. Mayer, J. Ansermet, B. Hilti, E. Minder, D. Neuschäfer, Proc. VII. Intl. Conf. Sci. Techn. Synth. Metals, (1990) to be published

    Google Scholar 

  5. D. Neuschäfer, J. Finter, D. Goltz, B. Hilti, H. Spahni, Proc. VII. Intl. Conf. Sci. Techn. Synth. Metals (1990), to be published

    Google Scholar 

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Author information

Author notes

  1. Ch. Kröhnke

    Present address: Additives Division, CIBA-GEIGY AG, R-1038.5.09, CH-4002, Basle, Switzerland

Authors and Affiliations

  1. Central Research Laboratories, UK

    Ch. Kröhnke, J. Finter & C. W. Mayer

  2. Materials Research, CIBA-GEIGY AG, CH-4002, Basle, Switzerland

    J. Ansermet, H. Bleier, B. Hilti, E. Minder & D. Neuschäfer

Authors
  1. Ch. Kröhnke
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  2. J. Finter
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  3. C. W. Mayer
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  4. J. Ansermet
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  5. H. Bleier
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  6. B. Hilti
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  7. E. Minder
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  8. D. Neuschäfer
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Editor information

Editors and Affiliations

  1. University of Massachusetts, Lowell, Massachusetts, USA

    J. C. Salamone

  2. Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA

    Judy S. Riffle

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© 1992 Springer Science+Business Media New York

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Kröhnke, C. et al. (1992). Transparent Electrically Conductive Composites by In-Situ Crystallization of (TSet)2Cl in a Polymer Matrix. In: Salamone, J.C., Riffle, J.S. (eds) Advances in New Materials. Contemporary Topics in Polymer Science, vol 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3456-3_18

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  • DOI: https://doi.org/10.1007/978-1-4615-3456-3_18

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6530-3

  • Online ISBN: 978-1-4615-3456-3

  • eBook Packages: Springer Book Archive

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