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Mechanism of the Thermooxidative Destruction and Stabilization of Polymers

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Aging and Stabilization of Polymers

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Abstract

After A. N. Bakh [1] and K. O. Engler [2] formulated the peroxide theory of oxidation, a large number of studies appeared in which the oxidation of a number of hydrocarbons and various other organic substances was studied. It was found that many oxidation reactions are autocatalytically accelerated and are characterized by well-defined induction periods.

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Bibliography

  1. A. N. Bakh, Zhur. Russ. Fiz.-Khim. Obshchestva 29: 373, 1897.

    Google Scholar 

  2. K. O. Engler and A. Wild, Ber. 30: 1669, 1897.

    CAS  Google Scholar 

  3. N. N. Semenov, J. Phys. Chem. 2B: 161, 1929; Chem. Revs. 6:347, 1929.

    Google Scholar 

  4. N. N. Semenov, J. Phys. Chem. 2B: 464, 1931.

    Google Scholar 

  5. N. N. Semenov, Chain Reactions, Leningrad, State Press for Chemical Literature, 1934.

    Google Scholar 

  6. N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity, Moscow, Academy of Sciences USSR Press, 1958.

    Google Scholar 

  7. V. N. Kondrat’ev, Kinetics of Reactions in the Gas Phase, Moscow, Academy of Sciences USSR Press, 1959.

    Google Scholar 

  8. A. B. Nalbandyan and V. V. Voevodskii, Mechanism of the Oxidation and Combustion of Hydrogen, Moscow, Academy of Sciences USSR Press, 1949.

    Google Scholar 

  9. V. V. Azatyan, V. V. Voevodskii, and A. B. Nalbandyan, Kinetika i Kataliz 2: 340, 1961.

    CAS  Google Scholar 

  10. V. I. Panfilov, D. D. Tsvetkov, and V. V. Voevodskii, Kinetika i Kataliz 1: 233, 1960.

    Google Scholar 

  11. V. V. Azatyan, V. I. Panfilov, and A. B. Nalbandyan, Kinetika i Kataliz 2: 295, 1961.

    CAS  Google Scholar 

  12. V. V. Azatyan, L. A. Akopyan, A. B. Nalbandyan, and B. V. Ozherel’ev, Doklady Akad. Nauk 141: 129, 1961.

    CAS  Google Scholar 

  13. L. I. Avramenko and R. V. Kolesnikova, DokladyAkad. Nauk SSSR 140: 1100, 1961.

    CAS  Google Scholar 

  14. J. D. Bolland, Quart. Revs. (London) 3: 1, 1949.

    Article  CAS  Google Scholar 

  15. C. E. Frank, Chem. Revs. 46: 155, 1950.

    Article  CAS  Google Scholar 

  16. L. Bateman, Quart. Revs. (London) 8: 147, 1954.

    Article  CAS  Google Scholar 

  17. D. L. Knorre, Z. K. Maizus, L. K. Obukhova, and N. M. Emanuél’, Uspekhi Khim. 26: 416, 1957.

    CAS  Google Scholar 

  18. G. A. Russel, J. Chem. Educ. 36: 111, 1959.

    Article  Google Scholar 

  19. J. D. Bolland, Trans. Faraday Soc. 46: 358, 1950.

    Article  CAS  Google Scholar 

  20. T. A. Ingles and H. W. Melville, Proc. Roy. Soc. A218: 163, 175, 1953.

    CAS  Google Scholar 

  21. M. B. Neiman, Zhur. Fiz. Khim. 28: 1235, 1954.

    CAS  Google Scholar 

  22. I. V. Berezin, L. G. Berezkina, and T. A. Nosova, Collection: Oxidation of Hydrocarbons in the Liquid Phase, Moscow, Academy of Sciences USSR Press, 1959.

    Google Scholar 

  23. G. A. Razuvaev, N. S. Vyazankin, Yu. I. Dergunov, and O. S. D’yachkovskaya, Doklady Akad. Nauk 132: 364, 1960.

    CAS  Google Scholar 

  24. I. V. Berezin, I. F. Kazanskaya, and K. Martinek, Zhur. Fiz. Khim. 35: 2039, 1961.

    CAS  Google Scholar 

  25. I. V. Berezin and O. Dobish, Doklady Akad Nauk SSSR 142: 105, 1962.

    CAS  Google Scholar 

  26. I. V. Berezin and Go Chu, Doklady Akad Nauk SSSR 142: 383, 1962.

    CAS  Google Scholar 

  27. R. F. Vasil’ev, O. N. Karpukhin, and V. Ya. Shlyapintokh, Doklady Akad. Nauk SSSR 125: 106, 1959.

    Google Scholar 

  28. R. F. Vasil’ev, DokladyAkad. Nauk SSSR 144: 143, 1962.

    Google Scholar 

  29. O. N. Karpukhin, V. Ya. Shlyapintokh, and N. V. Zolotova, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, No. 7: 1325, 1963.

    Google Scholar 

  30. M. B. Neiman, A. A. Dobrinskaya, and V. I. Gnyubkin, Investigation of the Mechanism of the Oxidation of Butane, Moscow, N. D. Zelinskii University Press, 1939.

    Google Scholar 

  31. M. B. Neiman and V. S. Pudov, Neftekhimiya 2 (6): 918, 1962.

    Google Scholar 

  32. Z. K. Maizus, I. P. Skibida, and N. M. Emanuél’, Doklady Akad. Nauk SSSR 131: 880, 1960.

    CAS  Google Scholar 

  33. Yu. A. Shlyapnikov, V. B. Miller, and E. S. Torsueva, Izvest Akad.Nauk SSSR, Otdel. Khim. Nauk, p. 1966, 1961.

    Google Scholar 

  34. Z. K. Maizus, N. M. Emanuél’, and V. N. Yakovleva, Doklady Akad Nauk SSSR 143: 366, 1962.

    CAS  Google Scholar 

  35. L. S. Vartanyan, Z. K. Maizus, and N. M. Emanuel’, Zhur. Fiz. Khim. 30: 862, 1956.

    Google Scholar 

  36. D. G. Knorre, Z. K. Maizus, and N. M. Emanuel’, Doklady Akad. Nauk SSSR 112: 457, 1957.

    CAS  Google Scholar 

  37. N. M. Emanuel, S. K. Maizus, and L. G. Privalova, Intern. J. Appl. Radiation and Isotopes 7: 111, 1959.

    Article  CAS  Google Scholar 

  38. Z. K. Maizus, I. P. Skibida, N. M. Emanuél’, and V. N. Yakovleva, Kinetika i Kataliz 1: 55, 1960.

    CAS  Google Scholar 

  39. L. K. Obukhova and N. M. Emanuél’, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, p. 1544, 1960.

    Google Scholar 

  40. E. T. Denisov, Doklady Akad Nauk SSSR 130: 1055, 1960.

    CAS  Google Scholar 

  41. C. H. Bamford and M. J. S. Dewar, Proc. Roy. Soc. A198:252,

    Google Scholar 

  42. L. T. Koritskii, Yu. N. Molin, B. N. Shamshev, N. Ya. Buben, and V. V. Voevodskii, Vysokomolekulyarnye Soedineniya 1: 1182, 1959.

    Google Scholar 

  43. Yu. D. Tsvetkov, Ya. S. Lebedev, and V. V. Voevodskii, Vysokomolekulyarnye Soedineniya 1: 1519, 1959.

    CAS  Google Scholar 

  44. A. L. Buchachenko, K. Ya. Kaganskaya, M. B. Neiman, and A. A. Petrov, Kinetika i Kataliz 2: 44, 1961.

    CAS  Google Scholar 

  45. A. L. Buchachenko, K. Ya. Kaganskaya, and M. B. Neiman, Kinetika i Kataliz 2: 161, 1961.

    CAS  Google Scholar 

  46. Ya. S. Lebedev, V. F. Tsepalov, and V. Ya. Shlyapintokh, Doklady Akad.Nauk SSSR 139: 1084, 1961.

    Google Scholar 

  47. V. B. Miller, M. B. Neiman, V. S. Pudov, and L. I. Lafer, Vysokomolekulyarnye Soedineniya 1: 1696, 1959.

    CAS  Google Scholar 

  48. Z. Manyasek, D. Berek, M. Michko, M. Lazar, and Yu. Pavlinets, Vysokomolekulyarnye Soedineniya 3: 1104, 1961.

    Google Scholar 

  49. D. Ryshavy, L. Balaban, V. Slavin, and R. Ruzha, Vysokomolekulyarnye Soedineniya 3: 1110, 1961.

    CAS  Google Scholar 

  50. V. S. Pudov, B. A. Gromov, M. B. Neiman, and E. G. Sklyarova, Neftekhimiya 3: 743, 1963; V. S. Pudov and M. B. Neiman, Neftekhimiya 3:750, 1963.

    CAS  Google Scholar 

  51. V. Stannett and R. B. Mesrobian, J. Am. Chem. Soc. 72: 4125, 1950.

    Article  CAS  Google Scholar 

  52. Z. K. Maizus, I. P. Skibida, N. M. Emanuél’, and V. N. Yakovleva, Kinetika i Kataliz 1: 55, 1960.

    CAS  Google Scholar 

  53. Z. K. Maizus, I. P. Skibida, and N. M. Emanuél’, Doklady Akad. Nauk SSSR 131: 880, 1960.

    CAS  Google Scholar 

  54. M. B. Neiman and V. S. Pudov, Izvest.Akad. Nauk SSSR, Otdel. Khim. Nauk, No. 5: 932, 1962.

    Google Scholar 

  55. V. S. Pudov and M. B. Neiman, Neftekhimiya 2 (6): 918, 1962.

    CAS  Google Scholar 

  56. K. U. Ingold, J. Inst. Petrol. 47: 375, 1961.

    CAS  Google Scholar 

  57. J. A. Christiansen, J. Phys. Chem. 28: 145, 1924.

    Article  CAS  Google Scholar 

  58. H. Backstrom, J. Am. Chem. Soc. 49: 1460, 1927.

    Article  CAS  Google Scholar 

  59. M. B. Neiman, V. B. Miller, Yu. A. Shlyapnikov, and E. S. Torsueva, Doklady Akad. Nauk SSSR 136: 647, 1961.

    CAS  Google Scholar 

  60. N. M. Emanuél’, A. B. Gagarina, and Z. K. Maizus, Doklady Akad. Nauk SSSR 135: 354, 1960.

    Google Scholar 

  61. D. Ryshavy, Vysokomolekulyarnye Soedineniya 3: 464, 1961.

    Google Scholar 

  62. V. B. Miller, M. B. Neiman, V. S. Pudov, and L. I. Lafer, Vy-sokomolekulyarnye Soedineniya 1: 1696, 1959.

    CAS  Google Scholar 

  63. R. Goglev and M. B. Neiman, Vysokomolekulyarnye Soedineniya 5: 1050, 1963.

    Google Scholar 

  64. G. I. Likhtenshtein, M. B. Neiman, and N. Sysoeva, Tr. po Khim. i Khim. Tekhnol. p. 155, 1963.

    Google Scholar 

  65. N. M. Emanuél’ and Yu. I. Lyaskovskaya, Inhibition of Processes of Fat Oxidation, Moscow, State Press for the Food Industry, 1961.

    Google Scholar 

  66. M. B. Neiman, Zhur. Vses. Khim. Obshchestva im. D. I. Mendeleeva 7 (2): 166, 1962.

    Google Scholar 

  67. Yu. A. Shlyapnikov, V. B. Miller, M. B. Neiman, and E. S. Torsueva, Vysokomolekulyarnye Soedineniya 4 (8): 1228, 1962.

    CAS  Google Scholar 

  68. A. F. Lukovnikov, P. I. Levin, and A. G. Vasil’eva, Aging and Stabilization of Polymers, Moscow, Academy of Sciences USSR Press, 1963.

    Google Scholar 

  69. J. L. Bolland and P. Ten Have, Trans. Faraday Soc. 43: 201, 1947.

    Article  CAS  Google Scholar 

  70. V. A. Shushunov, B. A. Redoshkin, and L. V. Kodintseva, Tr. po Khim. i Khim. Tekhnol. p. 463, 1961.

    Google Scholar 

  71. Yu. A. Shlyapnikov, V. B. Miller, M. B. Neiman, and E. S. Torsueva, Vysokomolekulyarnye Soedineniya 5 (10): 1507, 1963.

    CAS  Google Scholar 

  72. G. W. Kennerly and W. L. Patterson, Ind. Eng. Chem. 48: 1917, 1956.

    Article  CAS  Google Scholar 

  73. A. F. Lukovnikov, P. I. Levin, M. B. Neiman, and M. S. Khloplyankina, Vysokomolekulyarnye Soedineniya 3: 1243, 1961.

    Google Scholar 

  74. A. F. Lukovnikov, P. I. Levin, and M. S. Khloplyankina, Summaries of the Conference on the Aging and Stabilization of Polymers, Moscow, Academy of Sciences USSR Press, 1961, p. 7.

    Google Scholar 

  75. G. I. Likhtenshtein, ibid., p. 5.

    Google Scholar 

  76. M. B. Neiman, A. S. Kuz’minskli, and L. G. Angert, Vestnik Akad. Nauk SSSR, 30 (11): 36, 1960.

    CAS  Google Scholar 

  77. K. U. Ingold, Chem. Revs. 61: 563, 1961.

    Article  CAS  Google Scholar 

  78. G. G. Knapp and H. D. Orloff, Ind. Eng. Chem. 53: 63, 1961.

    Article  CAS  Google Scholar 

  79. P. A. Kirpichnikov et al., Summaries of the Conference on the Aging and Stabilization of Polymers, Moscow, Academy of Sciences USSR Press, 1961.

    Google Scholar 

  80. A. A. Berlin, Z. V. Popova, and D. M. Yanovskii, Doklady Akad. Nauk SSSR 131: 563, 1961.

    Google Scholar 

  81. E. G. Rozantsev, L. A. Kalashnikova, and M. B. Neiman, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, p. 501, 1962.

    Google Scholar 

  82. J. R. Thomas, J. Am. Chem. Soc. 82: 5955, 1960.

    Article  CAS  Google Scholar 

  83. G. I. Likhtenshtein, Dissertation, Institute of Chemical Physics, Academy of Sciences USSR, 1962.

    Google Scholar 

  84. M. B. Neiman, Yu. G. Mamedova, and Z. G. Rozantsev, Khim. Zhur. AN Azerb.SSR, No. 6: 37, 1962.

    Google Scholar 

  85. G. I. Likhtenshtein, Zhur. Fiz. Khim. 36: 750, 1962.

    Google Scholar 

  86. W. Kern and H. Cherdron, Makromol. Chem. 40: 101, 1960.

    Article  CAS  Google Scholar 

  87. W. Kern, H. Cherdron, et al., Angew. Chem. 73 (6): 5177, 1961.

    Article  Google Scholar 

  88. N. S. Enikolopyan and M. S. Vardanyan, Zhur. Vses. Khim. Obshchestva im. D. I. Mendeleeva 7 (2): 194, 1962.

    CAS  Google Scholar 

  89. E. G. Rozantsev, L. A. Krinitskaya, and B. V. Rozynov, Plast. Mass. No. 11: 48, 1963.

    Google Scholar 

  90. Yu. A. Shlyapnikov, V. B. Miller, M. B. Neiman, and E. S. Torsyeva, Doklady Akad. Nauk SSSR 151: 148, 1963.

    CAS  Google Scholar 

  91. A. L. Buchachenko, E. I. Sdobnov, S. R. Rafikov, and M. B. Neiman, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, p. 1118, 1963.

    Google Scholar 

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Neiman, M.B. (1965). Mechanism of the Thermooxidative Destruction and Stabilization of Polymers. In: Neiman, M.B. (eds) Aging and Stabilization of Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8549-7_2

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  • DOI: https://doi.org/10.1007/978-1-4615-8549-7_2

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