Abstract
Developments in the chemical and petrochemical industries, advances in chemical engineering, the introduction of new products, advances in the technology of intermediates, and problems in energy conversion have created new corrosion problems, involving the failure of metallic materials under the influence of aggressive organic solvents. Failures of this type lead not only to a deterioration of the mechanical properties of structural material, but also to discoloration and unwanted changes of the solvent. Since organic solvents in most cases are poisonous, inflammable, and, in the presence of air, explosive, the demands on the corrosion resistance of the materials used are immense. Therefore, in discussing corrosion of metals in organic solvents problems arise which have no parallel in the field of corrosion in aqueous media.
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References
K. Schwabe, Acid Corrosion of Metals in Nonaqueous Solvents, Verlag Technik, Berlin (1952) [in German].
A. Bukowiecki, On the Corrosion Behaviour of Metals in Nonaqueous Liquids, Metall. 13, 536–540 (1959) [in German].
W. Schmidt, Corrosion of Metals and Alloys in Organic Media, Zashchita Metal. (Met. Prot.) 5, 608–617 (1969) [in Russian].
J. J. Demo, Effect of Low Concentrations of Acid and Water on the Corrosion of Metals in Organic Solvents, Chem. Eng. World 7, 115–124 (1972).
E. Heitz and C. M. v. Meysenbug, The Corrosion of Iron, Nickel, Copper, and Aluminum in Organic Solvents with Low Content of Mineralic Acids, Werkst. u. Korr. 16, 178–595 (1965) [in German].
E. Heitz, Basic Processes of Metal Corrosion in Organic Solvents I, Werkst. u. Korr. 21, 360–367 (1970) [in German].
E. Heitz, M. Huković, and K. H. Maier, Basic Processes of Metal Corrosion in Organic Solvents II, IS. 21, 457–462 (1970) [in German].
E. Price, in The Chemistry of Nonaqueous Solvents (J. J. Lagowski, ed.), Vol. I, pp. 67–96, Academic Press, New York (1966).
B. Case, in Reactions of Molecules at Electrodes (N. S. Hush, ed.), pp. 45–134, Wiley- Interscience, London (1971).
G. N. Lewis, M. Randall, K. S. Pitzer, and L. Brewer, Thermodynamics, McGraw-Hill, New York (1961).
A. W. Francis, Liquid-Liquid Equilibriums, Interscience, New York (1963).
A. W. Francis, Ternary Systems of Hydrogen Halides-Systems with Island Curves, J. Phys. Chem. 62, 579–584 (1958).
L. Alders, Liquid-Liquid Extraction, Elsevier, Amsterdam (1955).
International Critical Tables, McGraw-Hill, New York (1933).
Landolt-Börnstein, Data and Functions, 6th ed., Vol. II, Part 2, Springer, Berlin (1962, 1964) [in German].
A. W. Francis, Ternary Systems of Chlorine Compounds, J. Chem. Eng. Data 12, 381–386 (1967).
A. W. Francis, Ternary Systems Separating into Two Liquid Layers, in Solubilities of Inorganic and Organic Compounds (A. Seidell and W. F. Linke, eds.), Suppl. to 3rd ed., pp. 821–1122, Van Nostrand (1952).
N. A. Mikhailova, N. P. Zhuk, A. V. Turkovskaya, Yu. P. Adler, and A. I. Ratner, Corrosion Resistance of Aluminum in the System CH3COOH-HCOOH-H2O, Zashchita Metal. (Met. Prot.) 6, 387–396 (1970) [in Russian].
M. Stern and H. H. Uhlig, Corrosion of Aluminum by Carbon Tetrachloride, J. Electrochem. Soc. 99, 381–388 (1952).
I. M. Kolthoff, Review of Fundamentals of Polarography in Inert Organic Solvents, J. Polarogr. Soc. 10, 22–36 (1965).
K. Schwabe, Polarography in Nonaqueous Solutions, in Progress in Polarography (P. Zuman and I. M. Kolthoff, eds.), Vol. I, pp. 333–355, Interscience, New York (1962) [in German].
W. Huber, Titrations in Nonaqueous Solvents, Akad. Verlagsges., Frankfurt (1964) [in German].
R. G. Bates, in The Chemistry of Nonaqueous Solvents (J. J. Lagowski, ed.), Vol. I, pp. 97–128, Academic Press, New York (1966).
R. G. Bates, Determination of pH, John Wiley, New York (1964).
W. A. Pleskov, Electrode Potentials and Solvation Energies of Ions, Adv. Chem. (USSR) 16, 254 (1947) [in Russian].
H.-M. Koepp, H. Wendt, and H. Strehlow, Comparison of the Potential Series in Different Solvents, Z. Elektrochem. 64, 483–491 (1960) [in German].
E. Heitz, On the Reaction Mechanism of Transition Metals with Nonaqueous Monocarboxylic Acids, Habil. Schrift, University Frankfurt, Frankfurt (1968) [in German].
H. Strehlow, in The Chemistry of Nonaqueous Solvents (J. J. Lagowski, ed.), Vol. I, pp. 129–171, Academic Press, New York (1966).
C. L. LeBas and M. C. Day, EMF Measurements of the Ethanol-Hydrochloric Acid-Water System, J. Phys. Chem. 64, 465–467 (1960).
J. M. Austin, A. H. Hunt, F. A. Johnson, and N. N. Parton in Electrochemical Data (B. E. Conway, ed.), p. 301, Elsevier, Amsterdam (1952).
K. Schwabe and S. Ziegenbalg, On the Galvanic Cell: Pt,H2(l atm)/HCl, Hg2Cl2(s)/Hg in Organic Solvents and Their Mixtures with Water, I, Z. Elektrochem. 62, 172–178 (1958) [in German].
K. Schwabe and M. Kunz, On the Galvanic Cell: Pt,H2(l atm)/HCl,Hg2Cl2(s)/Hg in Organic Solvents and Their Mixtures with Water, IV, Z. Elektrochem. 64, 1188–1190 (1960) [in German].
K. Schwabe and N. F. Nhuan, On the Galvanic Cell: Pt,H2(1 atm)/HCl,Hg2Cl2(s)/Hg in Organic Solvents and Their Mixtures with Water, V, Z. Elektrochem. 65, 891–894 (1961) [in German].
H. S. Harned and J. O. Morrison, The Thermodynamics of Hydrochloric Acid in Dioxane-Water Mixtures from EMF Measurements, I. Standard Potentials, J. Am. Chem. Soc. 58, 1908–1911 (1936).
H. Kaesche, The Corrosion of Metals, Springer, Berlin (1966) [in German].
U. R. Evans, The Corrosion and Oxidation of Metals, Edward Arnold, London (1960); First Suppl. Vol. (1968).
K. J. Vetter, Electrochemical Kinetics, Academic Press, New York (1967).
L. L. Shreir (ed.), Corrosion, Vols. I, II, George Newnes, London (1963).
N. Hackerman, The Anodic Polarisation Behaviour of Metals in Hydrogen Fluorides, Corr. Sci. 1, 39–50 (1967).
A. K. Vijh, Correlation between Atomic Number and Electrochemical Behaviour: Anodic Dissolution of Metals in Hydrogen Fluoride, Electrochim. Acta 16, 441–445 (1971).
L. G. Gindin, W. A. Kasakowa, and I. N. Putilova, On the Influence of the Solvent on the Acid Corrosion of Metals, Dokl. Akad. Nauk SSSR 80, 777–780 (1951) [in Russian].
E. Heitz, On the Mechanism of Reactions of Transition Metals with Nonaqueous Monocarboxylic Acids, Ber. Bunsenges. Phys. Chem. 73, 1085–1093 (1969) [in German].
H.-E. Bühler and W. Schwenk, The Influence of Cold Work on the Anodic Dissolution and Cathodic Hydrogen Development during Corrosion of Different Metals and Alloys in Acids, Z. Metallkunde 56, 24–30 (1965) [in German].
W. J. Lorenz and G. Eichkorn, Influence of Subgrain Structure on the Mechanism of Anodic Iron Dissolution in Acidic Solutions, Ber. Bunsenges. Phys. Chem. 70, 99–106 (1966) [in German].
J. C. Scully (ed.), The Theory of Stress Corrosion Cracking in Alloys, NATO Scientific Affairs Div., Brussels (1971).
W. J. Lorenz, H. Yamaoka, and H. Fischer, On the Electrochemical Behavior of Iron in Hydrochloric Acid Solution, Ber. Bunsenges. Phys. Chem. 67, 932–943 (1963) [in German].
H. Gatos (ed.), The Surface Chemistry of Metals and Semiconductors, John Wiley, New York (1960).
N. Tanaka and R. Tamamushi, Kinetic Parameters of Electrode Reactions, Electrochim. Acta 9, 963–989 (1964).
R. M. Latanision and A.R.C. Westwood, in Advances in Corrosion Science and Technology (M. G. Fontana and R. W. Staehle, eds.), Vol. 1, pp. 51–145, Plenum Press, New York (1970).
C. P. Dillon, Role of Contaminants in Acetic Acid Corrosion, Mater. Prot. 4, 20–22 (1965).
E. Heitz and E. Constantinescu, On the Influence of Water on the Metal Corrosion in Carboxylic Acids, Corr. Sci. (in preparation).
J. O’M. Bockris and H. Kita, Analysis of Galvanostatic Transients and Application to the Iron Electrode Reaction, J. Electrochem. Soc. 108, 676–685 (1961).
K. E. Heusler, On the Mechanism of Electrochemical Deposition and Dissolution of Cobalt in Perchlorate Solutions, Z. Elektrochem. 66, 177–184 (1962) [in German].
W. J. Lorenz, The Influence of Halogenide Ions on the Anodic Dissolution of Iron, Corr. Sci. 5, 121–131 (1965) [in German].
K. Fischbeck, On the Application of the Warburg Apparatus for Corrosion Testing, Werkst. u. Korr. 15, 59–63 (1964) [in German].
K. Fischbeck and W. Friedemann, private communication.
A. Bukowiecki, Investigations on the Corrosion Behavior of Aluminum and its Alloys in Organic and Inorganic Bases, Werkst. u. Korr. 10, 91–105 (1959) [in German].
K. Brookmann, Investigations on the Corrosion Behavior of Aluminum in Organic Solvents, Aluminium 34 30–35 (1958) [in German].
E. G. Haney and W. R. Wearmouth, Effect of “Pure” Methanol on the Cracking of Titanium, Corrosion 25, 87–91 (1969).
K. Mori, A. Takamura, and T. Shimose, Stress Corrosion Cracking of Ti and Zr in HCl-Methanol Solutions, Corrosion 22, 29–31 (1966).
I. D. Meshcheryakova, T. P. Kashcheva, and M. L. Rutkovskij, Behavior of Titanium in Ethanol Water Solutions of Hydrogen Chloride, Zashchita Metal. (Met. Prot.) 6, 286–289 (1970) [in Russian].
V. I. Vigdorovich, L. E. Tzygankova, and R. I. Merkulova, Corrosion Aggressiveness of Acidic Glycerol Solutions, Zashchita Metal. (Met. Prot.) 8, 328–331 (1972) [in Russian].
L. E. Tzygankova, V. I. Vigdorovich, and I. T. Pchelnikov, Corrosion and Electrochemical Behavior of Certain Metals in Aqueous Ethylene Glycol Solutions of Sodium Chloride, Zashchita Metal. (Met. Prot.)6, 648–652 (1970) [in Russian]
V. I. Vigdorovich, I. T. Pchelnikov, and L. E. Tzygankova, Copper and Brass Corrosion in Acidic Ethyleneglycol Solutions, Zashchita Metal. (Met. Prot.) 8, 464–466 (1972) [in Russian].
L. E. Tzygankova, V. I. Vigdorovich, and N. V. Fillippova, Steel Corrosion in Ethanol Solutions of Hydrogen Chloride, Zashchita Metal. (Met. Prot.) 9, 321–323 (1973) [in Russian].
M. Allbutt and G. Tolley, The Dissolution of Metals in Dioxan-Water Solutions of Hydrochloric Acid, J. Appl. Chem. 11, 52–68 (1961).
J. J. Demo, Effect of Inorganic Contaminants on the Corrosion of Metals in Chlorinated Solvents, Corrosion 24, 139–149 (1968).
R. Bartoniĉek, Steel Corrosion in a Benzene Solution of Hydrochloric Acid, Coll. Czech. Chem. Commun. 30, 1747–1758 (1965) [in German].
V. H. Chistyakov and W. W. Shapurova, Corrosion of Steel in Chloroform and Dichloroethane, Isv. Vyssh. Uch. Zav., Khim. i Khim. Tekhnol. 7, 349–350 (1964) [in Russian].
A. Bukowiecki, Testing of Halogenated Hydrocarbons with Respect to Their Metal Attacking Properties, Schweizer Archiv 34, 363–366 (1968) [in German].
E. Heitz, On the Influence of Flow Rate on Corrosion in Liquid Media, in Proc. Steel Congr. pp. 731–747, Luxemburg (1968).
E. Heitz, Investigation of Transport Processes at Corrosion, Werkst. u. Korr. 15, 63–69 (1964) [in German].
E. Heitz and C. Loss, On the Mechanism of Erosion Corrosion in Liquid Media of High Flow Rate, in Proc. 5th Int. Congr. Metallic Corrosion, Tokyo (1972); Werkst. u. Korr. 24, 38–48 (1973) [in German].
H. Wiegand and H. Piltz, On the Relation between Cavitation and Corrosion, Werkst. u. Korr. 15, 212–220 (1964) [in German].
E. Heitz, Kinetic Investigations on the Corrosion of Nickel in Acidic Alcohol Solutions, Electrochim. Acta 10, 49–65 (1965) [in German].
E. Yeager, The Measurement of Polarisation, Tech. Rep. U.S. Office Naval Research, Pr. Nr. 359–277 (1960).
J. E. Draley, F. E. DeBoer, and C. A. Youngdahl, The Polarisation of Metals in Boiling, Distilled Water, J. Electrochem. Soc. 108, 622–628 (1961).
W. J. Schwerdtfeger, Current and Potential Relations for the Cathodic Protection of Steel in High Resistivity Environment, Corrosion 16, 209t–214t (1960).
D. A. Jones, Polarisation in High Resistivity Media, Corr. Sci. 8, 19–27 (1968).
E. Heitz, Measurement of the Corrosion Rate in Media of Low Conductivity, in Proc. EUROMESCOR Congr., Vol. I, Prag (1968) [in German].
K. Schwabe and W. Schmidt, Influence of Water on the Passivation of Nickel in Sulfuric Acid Solution, Corr. Sci. 10, 143–155 (1970)
M. Jähnchen, On the Anodic Behavior of Iron in Dimethyl Formamide and Dimethyl Sulfoxide with Sulfuric Acid and Changing Amounts of Water, Dissertation, TU Dresden (1972) [in German].
F. Mazza, Anodic Behavior and Corrosion of Titanium in Methanolic Solutions, Werkst. u. Korr. 20, 199–205 (1969) [in German].
A. I. Cinman, W. S. Kusub, and A. N. Katrevich, Influence of Water and of the Nature of the Electrolyte on the Anodic Activation of Titanium in Methanol Solutions, Electrochimiya 2, 557–562 (1966) [in Russian].
H. Böhni, Pitting Corrosion of Metallic Materials, Material u. Technik 1, 33–43 (1973) [in German].
F. Mansfeld, The Effect of Water on Passivity and Pitting of Titanium in Solutions of Methanol and Hydrogen Chloride, J. Electrochem. Soc. 118, 1412–1415 (1971).
K. Elayaperumal, P. K. De, and J. Balachandra, Stress Corrosion Cracking of Zirconium in CH3OH + HCL Solutions, Corr. Sci. 11, 579–589 (1971).
J. C. Cessna, Polarisation Admittance Study of Lithium Corrosion in Propylene Carbonate Solutions, Corrosion 27, 244–254 (1971).
L. B. Parsons, The Influence of Water on Certain Chemical Reactions, III. The Reactions between Certain Metals and Iodine, J. Am. Chem. Soc. 47, 1830–1835 (1925).
J. D. Minford, M. H. Brown, and R. H. Brown, Reaction of Aluminum and Carbon Tetrachloride, I, J. Electrochem. Soc. 106, 185–191 (1959).
R. H. Brown, E. H. Cook, M. H. Brown, and J. D. Minford, Reaction of Aluminum and Carbon Tetrachloride. II, J. Electrochem. Soc. 106, 192–199 (1959).
V. M. Chistyakov and S. A. Balezin, Mechanism of the Corrosion of Steel in Carbon Tetrachloride, Isv. Vyssh. Uch. Zav., Khim. i Khim. Tekhnol. 4, 955–961 (1961) [in Russian].
V. H. Chistyakov, Kinetics of Corrosion of Steel in Some Chlorinated Hydrocarbons, Zh. Prikl. Khim. 38, 1021–1026 (1965) [in Russian].
M. Salomon, Kinetics of Electrode Reactions, J. Electrochem. Soc. 113, 940–943 (1966).
E. Heitz, The Mechanism of Metallic Corrosion In Nonaqueous Monocarboxylic Acids, in Proc. 4th Int. Congr. Met. Corr., p. 533–536, Amsterdam (1969).
H. Göhr and A. Seiler, Galvanostatic Investigations into the System Ether-Grignard Reagent, Chem. Ing. Techn. 42, 196–199 (1970) [in German].
R. R. Dewald and O. H. Bezirjian, A Kinetic Study of the Reactions of Water with Sodium and Cesium in Methylamine, J. Phys. Chem. 74, 4155–4157 (1970).
J. R. Anderson and B. H. McConkey, Reactions of Methyl Chloride and of Methylene Chloride at Metal Surfaces-I. Reactions at a Sodium Surface, J. Catalysis 9, 263–277 (1967).
P. Neufeld and A. K. Chakrabarty, The Corrosion of Aluminum and Its Alloys in Anhydrous Phenol, Corr. Sci. 12, 517–525 (1972).
H. Gerischer and I. Wallem-Mattes, On the Mechanism of Dissolution of Gallium Arsenide by Oxydants, Z. Phys. Chem. NF 64 187–198 (1969) [in German].
D. Posadas, J. J. Podestá, and A. J. Arvia, Electrochemistry of Solvated Proton in Dimethylsulfoxide, II. Kinetics and Mechanisms of the Electrolytic Evolution of Hydrogen on Iron, Electrochim. Acta 15, 1225–1232 (1970).
D. Posadas, A. J. Arvia, and J. J. Podestá, Kinetics and Mechanism of the Iron Electrode in Solutions of HCl in Dimethylsulfoxide, Electrochim. Acta 16, 1025–1039 (1971).
D. Posadas, A. J. Arvia, and J. J. Podestá, The Passivation of Iron in Solutions of Hydrogen Chloride in Dimethylsulfoxide, Electrochim. Acta 16, 1041–1053 (1971).
A. I. Cinman and A. N. Katrevich, Corrosion of Steel in Dimethylformamide-Water Mixtures, Zashchita Metal. (Met. Prot.) 5, 517–523 (1969) [in Russian].
V. N. Dolinkin, G. V. Mikhailova, and L. A. Kuznetsova, Stability and Corrosive Activity of Dimethylformamide and Its Aqueous Solutions, Khim. Prom. 43, 359–360 (1967) [in Russian].
J. R. Aylward and E. M. Whitener, Dissolution of Zirconium in HCl-Methanol, J. Electrochem. Soc. 109, 87–91 (1962).
T. C. Franklin and C. R. Parsons, The Anodic Dissolution of Nickel in Acetonitrile, J. Electrochem. Soc. 109, 641–642 (1962).
H. H. Uhlig and R. Krutenat, Formation of Dissolved Atomic Hydrogen by Electrochemical Polarisation, J. Electrochem. Soc. 111, 1303–1306 (1964).
A. J. Johnson and L. L. Shreir, The Anodic Behaviour of U, Ti, Zr, Nb, and Ta in 3 M AlCl3-Diethyl Ether Solution, Corr. Sci. 5, 269–278 (1965).
A. R. Piggot, H. Leckie, and L. L. Shreir, Anodic Polarisation of Ti in Formic Acid, I. Anodic Behaviour of Ti in Relation to Anodizing Conditions, Corr. Sci. 5, 165–184 (1965).
Ya. M. Kolotyrkin and G. G. Kossyi, Influence of Water on Anodic Behavior of Cr in Methanolic Solutions of HCl, Zashchita Metal. 1, 272–276 (1965) [in Russian].
R. G. Keil and R. E. Salomon, Anodization of Vanadium in Acetic Acid Solutions, J. Electrochem. Soc. 115, 628–633 (1968).
M. Salomon, Medium Effects on the Rate of Hydrogen Evolution, J. Phys. Chem. 70, 3853–3856 (1966).
J. Bardolle and J.-P. Kauffman, Kinetic Investigations of Corrosion Phenomena during Reaction of Iron with Iodine in Different Organic Solvents, Compt. Rend. 266, 1598–1601 (1968) [in French].
J.-P. Kauffman and M. G. Chaudron, Investigations on the Influence of the Solvents on the Mode of Attack on Iron by Iodine in Different Organic Solvents, Compt. Rend. 266, 1272–1274 (1968) [in French].
T. R. Das, K. A. Venkatachalam, and P. S. Mene, Studies of Corrosion of Metals by Iodine and Ammonia in a Nonaqueous Solvent, Indian J. Appl. Chem. 27, 140–145 (1964).
D. Bauer and J. P. Beck, Electrochemistry of Oxygen and Its Reduction Products in Solvents and Molten Salts, J. Electroanalyt. Chem. 40, 233–254 (1972) [in French].
W. Jaenicke and P. H. Schweitzer, Exchange Currents of the Zn2 + /Zn(Hg) Electrode in Binary Mixtures of Water and Organic Solvents, Z. Phys. Chem. NF 52, 104–122 (1967) [in German].
M. H. Miles and H. Genscher, The Zn2 + /Zn(Hg) Electrode Reaction in Binary Mixtures of Water and n-Propanol, J. Electrochem. Soc. 118, 837–841 (1971).
H. Schneider and H. Strehlow, On the Selective Solvation of Ions in Mixtures of Solvents, III, Ber. Bunsenges. Phys. Chem. 69, 674–676 (1965) [in German].
F. Mansfeld, Passivity and Pitting of Al, Ni, Ti, and Stainless Steel in CH3OH + H2SO4, J. Electrochem. Soc. 120, 188–192 (1973).
R. W. Staehle, A. J. Forty, and D. van Rooyen (eds.), Fundamental Aspects of Stress Corrosion Cracking, NACE, Houston (1969).
M. O. Speidel and M. V. Hyatt, in Advances in Corrosion Science and Technology (M. G. Fontana and R. W. Staehle, eds.), Vol. 2. pp. 115–335, Plenum Press, New York (1972).
F. E. Watkinson and J. C. Scully, The Stress Corrosion Cracking of a High Purity Al-6Zn-3Mg Alloy, Corr. Sci. 12, 905–924 (1972).
S. W. Vorster, Corrosion of Al Alloys in CH3OH + CCl4, Corr. Sci. 9, 801–811 (1969).
E. Schmidt, H. Bieri, and K. Huber, On the Formation of Hydrides during Anodic Dissolution of Tantalum in Methanol, Corr. Sci. 5, 455–457 (1965) [in German].
I. A. Menzies and A. F. Averill, The Anodic Behaviour of Titanium in HCl-Methanol Solutions, Electrochim. Acta 13, 807–824 (1968).
J. R. Ambrose and J. Krüger, The Stress-Corrosion of Ti and Ti-8Al-1Mo-1V in Methanol Vapour, Corr. Sci. 8, 119–124 (1968).
B. F. Brown, C. T. Fujii, and E. P. Dahlberg, Methods for Studying the Solution Chemistry within Stress Corrosion Cracks, J. Electrochem. Soc. 116, 218–219 (1969).
J. R. Leith, J. W. Hightower, and G. G. Harkins, Stress Corrosion Cracking of Titanium: Some Surface Chemical Reactions in Methanol and Carbon Tetrachloride, Corrosion 26, 377–380 (1970).
J. C. Scully and D. T. Powell, The Stress Corrosion Cracking Mechanism of α-Titanium Alloys at Room Temperature, Corr. Sci. 10, 719–733 (1970).
J. Spurrier and J. C. Scully, Fractographic Aspects of the Stress Corrosion Cracking of Titanium in a Methanol-HCl Mixture, Corrosion 28, 453–463 (1972).
C. M. Chen, F. H. Beck, and M. G. Fontana, Stress Corrosion Cracking of Ti-8Al-1Mo-IV Alloy in Aqueous and Methanol Environment, Corrosion 27, 77–83 (1971).
C. M. Chen, F. H. Beck, and M. G. Fontana, Crevice Effect during Polarization of Ti-8Al-1Mo-1V Alloy in Aqueous and Methanol Environments, Corrosion 27, 234–238 (1971).
G. Sandoz, Stress Corrosion Cracking Susceptibility of a Titanium Alloy in a Non-electrolyte, Nature 214, 166–167 (1967).
L. Raymond and R. Y. Usell, Flaw Growth in Ti-6Al-4V in Freon Environments, Corrosion 25, 251–259 (1969).
E. P. Parry and D. H. Hern, Effect of Chloride on the Anodic Dissolution of Titanium in Methanolic Solutions, J. Electrochem. Soc. 119, 1141–1147 (1972).
F. H. Cooks, J. F. Russo, and S. A. Brummer, The Separation of Corrosion and Stress Effects in Stress Corrosion: Ti-Al-4V in Bromine-Methanol Solutions, Corrosion 24, 206–208 (1968).
Linda H. Lee, Corrosion of Copper in Fluorochemical Liquid Coolants, Corrosion 26, 529–532 (1970).
J. Llopis, L. Arizmendi, J. M. Gamboa, V. Martinez-Vilche, and P. Perez-Fernandez, Surface Reaction of Iron with Solutions of Phosphorous Organic Compounds, Corr. Sci. 5, 319–325 (1965).
C. Husen, in High-Temperature Metallic Corrosion of Sulfur and its Compounds (Z. A. Foroulis, ed.), pp. 187–207, Electrochem. Society, New York (1970).
A. S. Couper, High Temperature Mercaptan Corrosion of Steels, Corrosion, 396t–401t (1963).
W. Deuchler, private communication.
H. Gräfen, H. Münster private communication.
K. Risch, private communication; K. Risch, Experiences with Titanium Construction in Chemical Plants, Chem. Ing. Techn. 39, 385–390 (1967) [in German].
M.-E. Horn, private communication.
E. Rabald, private communication.
E. Heitz, unpublished results.
E. Rabald, H. Bretschneider, D. Behrens (eds.), Dechema-Werkstofftabelle Frankfurt (1953–1973) [in German].
E. Rabald, Alloyed Cast Iron in Chemical Plant Construction, Werkst. u. Korr. 7, 435–448 (1956) [in German]
R. J. Agnew, J. K. Truitt, and W. D. Robertson, Corrosion of Metals in Ethylene Glycol Solutions, Ind. Eng. Chem. 50, 649–656 (1958).
E. H. Cook, R. L. Horst, and W. W. Binger, Corrosion Studies of Aluminum in Chemical Process Operations, Corrosion 17, 25t–30t (1961).
H. O. Teeple, Corrosion by Some Organic Acids and Related Compounds, Corrosion 8, 14–28 (1952).
S. M. Gurevich, I. Kornilov, E. Zotova, V. Blachyk, and Y. Maximov, Investigations into the Corrosion Resistance of Ti Alloys of the Systems Ti-V-O and Ti-V-Al-O, Zashchita Metal. (Met. Prot.) 7, 159–160 (1971) [in Russian].
NACE Techn. Com. Rep., Corrosion by Acetic Acid, Corrosion 13, 757t-766t (1957).
H. Togano and K. Osato, Corrosion Test on the Construction Materials for Acetic Acid Synthesis from Methanol and Carbon Monoxide, Corrosion Engineering 10, 529–533 (1961) [in Japanese; cited from Corrosion Abstracts].
M. E. Straumanis and P. C. Chen, The Corrosion Behavior of Titanium, Metall. 7, 85–93 (1953) [in German].
A. A. Farkhadov, V. G. Asatryan, N. P. Abalyan, A. I. Belayev, and G. A. Orlovskaya, Corrosion of Copper and Stainless Steel in Aqueous Mixtures of Ethylacetate with Acetic Acid, Zashchita Metal. 4, 319–321 (1968) [in Russian].
V. G. Asatryan, A. A. Farkhadov, G. A. Orlovskaya, and A. M. Balayan, Investigation of the Corrosion of a Rectification Column for Acetic Acid during Vinyl Acetate Production, Zashchita Metal. 7, 304–309 (1971) [in Russian].
R. E. Metsik and E. I. Rokhumyagi, Investigation of Metal Corrosion during Production of Benzoic Acid by Oxidation of Toluene in Acetic Acid Solution, Zashchita Metal. 5, 445–447 (1969) [in Russian].
E. Rabald, Corrosion Guide, 2nd ed., Elsevier, Amsterdam (1968).
J. R. Lane, L. B. Golden, and W. L. Acherman, Corrosion Resistance of Titanium, Zirconium, and Stainless Steel in Organic Compounds, Ind. Eng. Chem. 5, 1067–1070 (1953).
J. Demiancok and J. Dimitrova, Corrosion Properties of Trichloroacetic Acid and Sodium Trichloroacetate, Chem. Prumysl. 18, 263–265 (1968) [in Slovenian].
H. Leyerzapf, private communication.
V. N. Dolinkin, G. V. Mikhaylova, and L. A. Kuznetsova, Stability and Corrosivity of Dimethylformamide and Its Aqueous Solutions, Khim. Prom. 5, 359–360 (1967) [in Russian].
B. G. Gasanov, and N. G. Klyuchnikov, Effect of Ethanolamine on Certain Ferrous and Nonferrous Metals, Uch. Zap. Mosk. Gos. Pedagog. Inst. im V. I. Lenina, 146, 170–175 (1960)
B. G. Gasanov, and N. G. Klyuchnikov[in Russian; cited from Chem. Abstr. 56, 3218i (1962)].
S. C. Sircar and D. R. Wiles, Kinetics of the Dissolution of Copper in Aqueous Solutions of Aliphatic Diamines, J. Electrochem. Soc. 107, 366–370 (1960).
M. M. Levkovich, V. D. Mezhov, N. P. Matsota, and A. P. Seitskij, Corrosive Action of Monoethanol Amine Solution, Chem. Prom. 42, 832–835 (1966) [in Russian].
Dechema-Erfahrungsaustausch, Werkst. u. Korr. 5, 419 (1954).
NACE, Corrosion Data Survey, Houston (1967).
V. M. Chistiakov and S. A. Balezin, Corrosion and Corrosion Inhibition of Carbon Steel in Carbon Tetrachloride, Tr. Vses. Mezhvaz. Nauchn. Kinf. po Vopr. Bor’ by s Korroziei, 345–352 (1962) [in Russian].
E. V. Cherevkova, Corrosion of Iron in Benzene Solutions of Butyric Acid, Zashchita Korroziei, 345–352 (1962) [in Russian].
R. Bartoniĉek, Materials Selection for the Mixture H2O/Hydrocarbon/HCl, Chem. Prmysl. 14, 515–520 (1964) [in Czech].
W. A. Derungs, Naphthenic Acid Corrosion: An Old Enemy of the Petroleum Industry, Corrosion 12, 617t–622t (1956).
R. W. Staehle, in The Theory of Stress Corrosion Cracking in Alloys (J. C. Scully, ed.), p. 225, NATO, Brussels (1971).
E.-M. Horn and T. Günther, Failures by Selective Corrosion of Stainless Steels, Chem. Ing. Techn. 41, 991–999 (1969);
T. Günther, Failures of Chemical Apparatus and Consequences for New Design, Chem. Ing. Techn. 42, 774–780 (1970) [in German].
L. L. Faingold, Corrosion of Carbon Steel in Electrolyte-Air and Electrolyte-Benzene Systems, Zashchita Metal. 6, 44–46 (1970) [in Russian].
I. L. Rozenfeld, K. A. Zhigalova, and V. N. Sadakova, Mechanism of Metal Corrosion in the Two-Phase System Electrolyte-Hydrocarbon, Dokl. Akad. Nauk SSSR 196, 1379–1382 (1971) [in Russian].
H. Kaesche, E. Längle, and J. Rückert, Electrochemical Investigations on Fuel Oil Soluble Inhibitors, Werkst. u. Korr. 22, 673–682 (1971) [in German].
E. P. Sidroin, S. A. Balezin, and I. V. Nikalskij, Embrittlement and Hydrogen Uptake of Steel in Formic Acid, Zashchita Metal. 7, 69–70 (1971) [in Russian].
Materials Selector, Mater. Eng. 74 (1972).
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© 1974 Plenum Press, New York
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Heitz, E. (1974). Corrosion of Metals in Organic Solvents. In: Fontana, M.G., Staehle, R.W. (eds) Advances in Corrosion Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9059-0_3
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