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Electrochemistry of Metalloporphyrins Containing A Metal-Metal or Metal-Carbon Bond

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Redox Chemistry and Interfacial Behavior of Biological Molecules

Abstract

The synthesis, chemical properties, and electrochemistry of metalloporphyrins with metal-metal and metal-carbon bonds have recently been described in two extensive reviews1,2. Porphyrins are known to coordinate with most metallic and pseudo-metallic elements and, in theory, synthesis of numerous organometallic porphyrins is possible. However, to date, the synthesis of metal-carbon σ-bonded complexes has been limited to metalloporphyrins with the following central metals: Fe, Ru, Co, Rh, Ir, Ti, Al, Ga, In, Tl, Si, Ge, Sn and Zn. These organometallic complexes are of importance as model compounds for understanding the functions and relationships of several biologically important macromolecules, as well as for their chemical reactivity. The insertion of small molecules between the metal ion and the carbon atom of a metalloporphyrin may result in activation of the inserted molecule or may generate new monomeric or polymeric materials. In addition, metal-carbon σ-bonded porphyrins can act as precursors in the synthesis of metal-metal bonded derivatives.

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Authors and Affiliations

  1. Department of Chemistry, University of Houston, 4800 Calhoun Road, Houston, Texas, 77004, USA

    K. M. Kadish

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Editors and Affiliations

  1. The University of Oklahoma, Norman, Oklahoma, USA

    Glenn Dryhurst

  2. Yokohama National University, Yokohama, Japan

    Katsumi Niki

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© 1988 Plenum Press, New York

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Kadish, K.M. (1988). Electrochemistry of Metalloporphyrins Containing A Metal-Metal or Metal-Carbon Bond. In: Dryhurst, G., Niki, K. (eds) Redox Chemistry and Interfacial Behavior of Biological Molecules. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9534-2_2

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  • DOI: https://doi.org/10.1007/978-1-4615-9534-2_2

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