Abstract
The experimental isomer shifts for compounds of tin, antimony, tellurium, iodine and xenon have been compared with atomic Hartree-Fock density calculations for the chemically appropriate electronic configurations. This leads to values of δ<R2>/<R2> for each nucleus. In addition, the isomer shifts for isoelectronic pairs of compounds (e.g., SnO with Sb2O3, Sb2O3 with TeO2, etc.) have been compared to find ratios of δ<R2>/<R2> for adjacent nuclei. These ratios agree closely with those deduced from the first method. This agreement gives support to the simple chemical interpretation of the isomer shifts for this series of nuclei and at the same time supplies a technique for deducing electronic configurations from the measured shifts.
Work performed under the auspices of the US Atomic Energy Commission.
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Shenoy, G.K., Ruby, S.L. (1970). Systematic Interpretation of the Isomer Shifts in Tin, Antimony, Tellurium, Iodine, and Xenon. In: Gruverman, I.J. (eds) Mössbauer Effect Methodology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3156-8_5
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DOI: https://doi.org/10.1007/978-1-4684-3156-8_5
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