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Electrochemical Generation of Free Radical Ions and Use of Electron Paramagnetic Resonance for Their Investigation

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Progress in Electrochemistry of Organic Compounds 1

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Abstract

Among the numerous methods used for the preparation of organic free radicals the most widespread have been the following [1–6]: 1) Thermal decomposition; 2) electric discharge in gases; 3) electron bombardment; 4) radiolysis with γ-rays; 5) photolysis. Alongside these methods in the last 10 years there has also been a rapid development of the electrochemical methods for generation of free radicals, which has a number of special characteristics and advantages over the other methods. Most frequently used for electrolytic generation of free radicals is electrolytic reduction, and more rarely electrolytic oxidation; as a rule radical anions are obtained in the first case and radical cations in the second:

$$R + e \to {R^{\cdot - }};{\text{ }}R - e \to {R^{\cdot + }}.$$

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Authors
  1. Ya. P. Stradyn’
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  2. R. A. Gavar
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  1. Institute of Electrochemistry, Academy of Sciences of the U.S.S.R., Moscow, Russia

    A. N. Frumkin  & A. B. Érshler  & 

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© 1971 Plenum Publishing Company Ltd.

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Stradyn’, Y.P., Gavar, R.A. (1971). Electrochemical Generation of Free Radical Ions and Use of Electron Paramagnetic Resonance for Their Investigation. In: Frumkin, A.N., Érshler, A.B. (eds) Progress in Electrochemistry of Organic Compounds 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3339-5_1

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  • DOI: https://doi.org/10.1007/978-1-4684-3339-5_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3341-8

  • Online ISBN: 978-1-4684-3339-5

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