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Aging Processes in Diamond-Like Carbon and Carbon/Metal Films

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Diamond and Diamond-like Films and Coatings

Part of the book series: NATO ASI Series ((NSSB,volume 266))

Abstract

Thin films deposited by nonequilibrium processes, such as in low pressure plasmas, are sensitive to aging due to the presence of free radicals, dangling bonds, defects, voids, internal stress and other features. Generally, several aspects of film stability or aging can be considered:

  1. A:

    spontaneous aging — internal material property characterized by the driving force to acquire minimum system energy without any intermediate agent;

  2. B:

    environmental aging — reaction with the ambient atmosphere (not “deliberately severe”);

  3. C:

    accelerated aging — post deposition treatment (deliberately severe) using various thermal, chemical, radiative, mechanical and other agents.

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References

  1. J.C. Angus, P. Koidl, S. Domitz, Carbon thin films, in: “Plasma Deposited Thin Films”, J. Mort, F. Jansen, eds., CRC Press, Boca Raton (1986).

    Google Scholar 

  2. H. Biederman, L. Martinu, Plasma polymer-metal composite films, in: “Plasma Deposition, Treatment and Etching of Polymers”, R. d’Agostino, ed., Academic Press, New York (1990).

    Google Scholar 

  3. J.M.E. Harper, J.J. Cuomo, R.J. Gambino and H.R. Kaufman, in: “Ion Bombardment Modification of Surfaces: Fundamentals and Applica-cations”, O. Auciello, R. Kelly, eds., Elsevier, Amsterdam (1984).

    Google Scholar 

  4. P. Koidl, Ch. Wild, B. Dischler, J. Wagner, M. Ramsteiner, in: “Amorphous Hydrogenated Carbon”, J.J. Pouch, S.A. Alterovitz, eds., Mater Sci. Forum, Vol. 52/53: 41 (1990).

    Google Scholar 

  5. L. Martinu, Amorphous carbon films, in: “High Energy Density Technologies in Materials Science”, F. Garbassi, E. Occhiello, eds., Kluwer Academic Publ., Dordrecht (1990).

    Google Scholar 

  6. C. Wild, P. Koidl, J. Wagner, Plasma deposition of a-C:H films: the role of process gas, plasma chemistry and plasma surface interactions, in: “Amorphous Hydrogenated Carbon Films”, P. Koidl, P. Oelhafen, eds., Proc. E-MRS, Vol. 17, Les Editions de Physique, Paris (1987).

    Google Scholar 

  7. J.C. Angus, F. Jansen, Dense “diamondlike” hydrocarbons as random covalent networks, J. Vac. Sci. Technol. A 6: 1778 (1988).

    Article  ADS  Google Scholar 

  8. H. Yasuda, “Plasma Polymerization”, Academic Press, New York (1985).

    Google Scholar 

  9. A.M. Wrobel, Aging process in plasma-polymerized organosilicon thin films, J. Macromol. Sci.-Chem. A22: 1089 (1985).

    Article  Google Scholar 

  10. L. Martinu, H. Biederman, J. Nedbal, Dielectric properties of fluoro-and chlorofluorocarbon films plasma polymerized in an RF glow discharge, Thin Solid Films 136: 11 (1986).

    Article  ADS  Google Scholar 

  11. J. Perrin, R.L. Siemens, E. Kay, Thermal transitions and dielectric relaxations in plasma-polymerized polytetrafluoroethylene, IBM Res. Rep. RJ 4792 (1985).

    Google Scholar 

  12. B. Dischler, Bonding and hydrogen incorporation in a-C:H studied by infrared spectroscopy, p. 189 in ref. 6.

    Google Scholar 

  13. C. Wild, P. Koidl, Network structure and thermal decomposition of plasma deposited a-C:H films studied by gas effusion spectroscopy, p. 207 in ref. 6.

    Google Scholar 

  14. S. Orzeszko, Bhola N. De, J.A. Woollam, J.J. Pouch, S.A. Alterovitz, D.C. Ingram, Thin film hermeticity: A quantitative analysis of diamondlike carbon using variable spectroscopic eliipsometry, J. Appl. Phvs. 64: 4175 (1988).

    Article  ADS  Google Scholar 

  15. C.J. Robinson, R.N. Payne, A.E. Bell, Hydrogenated amorphous carbon dielectric coatings for magneto-optic data storage media, J. Appl. Phys. 64: 4646 (1988).

    Article  ADS  Google Scholar 

  16. H. Biederman, L. Martinu, S. Nespurek, Aging effects in composite plasma polymer/metal films, in: Proc. 8th Int. Symp. Plasma Chem. (ISPC-8), K. Akashi, A. Kinbara, eds., Tokyo (1987), p. 1364.

    Google Scholar 

  17. L. Martinu, Optical response of composite plasma polymer/metal films in effective medium approach, Solar Energy Mater. 15: 21 (1987).

    Article  Google Scholar 

  18. R. dAgostino, L. Martinu, V. Pische, Effect of bias and temperature on the bulk and surface properties of gold containing plasma polymerized fluorocarbons, Plasma Chem. Plasma Process., in press.

    Google Scholar 

  19. L. Martinu, V. Pische, R. dAgostino, Surface Modification by plasma deposition of metal-filled polymers, in: Metallisation in Polymers, E. Sacher, J.J. Pireaux, S. Kowalczyk, eds., ACS Symp. Ser. 440, (1990), in press.

    Google Scholar 

  20. E. Kay, Ion and laser interactions as encountered in synthesis and utilisation of metal-containing polymers, Proc. E-MRS, Vol. 15, p. 355, Les Editions de Physique, Paris (1987).

    Google Scholar 

  21. D.I. Jones, A.D. Stewart, Properties of hydrogenated amorphous carbon films and the effects of doping, Phil. Mag. B 46: 423 (1982).

    Article  Google Scholar 

  22. R.E. Sah, B. Dischler, A. Bubenzer, P. Koidl, Amorphous carbon coatings prepared by high rate rf plasma deposition of fluorinated benzenes, Appl. Phys. Lett. 46: 739 (1985).

    Google Scholar 

  23. H. Biederman, L. Martinu, J. Zemek, Carbon and composite carbon metal films deposited from an rf discharge operated in organic gases, Vacuum 35: 447 (1985).

    Article  Google Scholar 

  24. C.P. Klages, R. Memming, Microstructure in physical properties of metal-containing hydrogenated carbon films, p. 609 in ref. 4.

    Google Scholar 

  25. C. Weissmantel, E. Ackerman, K. Bewilogna, G. Hecht, K. Kupfer, B. Rau, Structure property relationships of carbonaceous films grown under ion enhancement, J. Vac. Sci. Technol. A 4: 2892 (1986).

    Article  ADS  Google Scholar 

  26. H. Biederman, K. Kahoutek, Z. Chmel, V. Stary, R.P. Howson, Hard carbon and composite metal/hard carbon films prepared by a dc unbalanced planar magnetron, Vacuum 40: 251 (1990).

    Article  Google Scholar 

  27. N. Savvides, Diamondlike films and properties, p. 408 in ref. 4.

    Google Scholar 

  28. M.R. Wertheimer, M. Moisan, Comparison of microwave and lower frequency plasmas for thin film deposition and etching, J. Vac. Sci. Technol. A 3: 2643 (1985).

    Article  ADS  Google Scholar 

  29. R. Claude, M. Moisan, M.R. Wertheimer, Z. Zakrzewski, Comparison of microwave and lower frequency discharges for plasma polymeriza- tion, Plasma Chem. Plasma Process. 7: 451 (1987).

    Article  Google Scholar 

  30. L. Martinu, J.E. Klemberg-Sapieha, M.R. Wertheimer, Dual-mode microwave/radio frequency plasma deposition of dielectric thin films, Appl. Phys. Lett. 54, 2645 (1989).

    Google Scholar 

  31. J.E. Klemberg-Sapieha, O.M. Küttel, L. Martinu, M.R. Wertheimer, Dual microwave/radio frequency plasma deposition of functional coatings, Thin Solid Films, (1990) in press.

    Google Scholar 

  32. O.M. Küttel, J.E. Klemberg-Sapieha, L. Martinu, M.R. Wertheimer, Energy fluxes in mixed microwave radio frequency plasma, Thin Solid Films 193, (1990), in press.

    Google Scholar 

  33. O.M. Küttel, L. Martinu, D. Poitras, J.E. Klemberg-Sapieha, M.R. Wertheimer, Diamond-like carbon films deposited in dual microwave/radio frequency plasma, Proc. E-MRS Meeting, Strasbourg, November 1990, submitted.

    Google Scholar 

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© 1991 Plenum Press, New York

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Martinu, L. (1991). Aging Processes in Diamond-Like Carbon and Carbon/Metal Films. In: Clausing, R.E., Horton, L.L., Angus, J.C., Koidl, P. (eds) Diamond and Diamond-like Films and Coatings. NATO ASI Series, vol 266. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5967-8_29

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  • DOI: https://doi.org/10.1007/978-1-4684-5967-8_29

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-5969-2

  • Online ISBN: 978-1-4684-5967-8

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