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Gas-Solid Reactions—Oxidation

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Treatise on Solid State Chemistry

Abstract

The oxidation of metals and alloys at elevated temperatures with fairly thick oxide layers (≥ 10-4 cm) is often caused by diffusion processes through the oxide layer, resulting in a parabolic rate law, first reported by Tammann(1) and later also noted by Pilling and Bed-worth(2) and interpreted by Wagner.(3) Diffusion-controlled oxidation, however, is detected only if a coherent and pore-free layer of the reaction product, e.g., an oxide, sulfide, or halogenide, is formed and if phase-boundary reactions are fast, i.e., at established equilibria at both interfaces.

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  1. Institute of Physical Chemistry, University of Göttingen, West Germany

    Karl Hauffe

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  1. Research and Patents, Bell Laboratories, Murray Hill, New Jersey, USA

    N. B. Hannay (Vice President) (Vice President)

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Hauffe, K. (1976). Gas-Solid Reactions—Oxidation. In: Hannay, N.B. (eds) Treatise on Solid State Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8082-5_8

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