Abstract
The spectra of titanium and carbon in the homogeneity range of titanium carbide (TiC0.54-1.0) were measured in small composition stages, under high resolution conditions. The carbide specimens were synthesized from high-purity raw materials under conditions conducive to the presence of a minimum amount of dissolved gases and free carbon in them. The combination of the K and L spectra of titanium, which are responsible for the p and d states of the metal, with the Kα band of carbon in the homogeneous carbides, which reflects mainly the 2p electron states of the carbon atom, enabled a number of considerations to be advanced in regard to the structure of the valence band of the carbide crystal and to the effect of carbon concentration on the energy spectrum.
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Literature Cited
M. P. Arbuzov and B. V. Khaenko, Poroshkovaya Met., No. 8 (1968).
M. A. Blokhin and A. T. Shuvaev, Izv. Akad.Nauk SSSR, Fiz., 26:429 (1962).
E. E. Vainshtein, X-Ray Spectra of Atoms in Molecules of Chemical Compounds and Alloys [in Russian], Nauka, Moscow and Leningrad (1966).
E. A. Zhurakovskii and E. E. Vainshtein, Dokl. Akad. Nauk SSSR, Vol. 122, No. 3 (1958);
E. A. Zhurakovskii and E. E. Vainshtein, Dokl. Akad. Nauk SSSR, Vol. 127, No. 3 (1959);
E. A. Zhurakovskii and E. E. Vainshtein, Dokl. Akad. Nauk SSSR, Vol. 129, No. 6 (1959);
E. A. Zhurakovskii and E. E. Vainshtein, Dokl. Akad. Nauk SSSR, Vol. 140, No. 3 (1961).
Yu. P. Irkhin, Fiz. Metal, i Metalloved., 11:10 (1961).
A. P. Lukirskii and I. A. Brytov, Optika i Spektroskopiya, No. 12 (1966).
A. P. Lukirskii, Author’s Summary of Doctor’s Thesis, LGU, Leningrad (1963).
G. V. Samsonov and Ya. S. Umanskii, Hard Compounds of Refractory Metals [in Russian], Metallurgizdat, Moscow (1958).
Ya. S. Umanskii, Carbides in Hard Alloys [in Russian], Metallurgizdat, Moscow (1947).
A. T. Shuvaev, Author’s Summary of Candidate’s Thesis, RGU, Rostov-on-Don (1964).
H. Biltz, Z. Physik, 153:338 (1958).
F. G. Chalklin, Proc. Roy. Soc., 194:1036 (1948).
C. A. Coulson and P. Taylor, Proc. Phys. Soc., 65(10):42A (1952).
V. Erne and A. C. Switendick, Phys. Rev., 137:6A (1965).
C. T. Kimball, J. Chem. Phys., 8:188 (1940).
R. C. Lye and E. M. Logothetis, Phys. Rev., 147:2 (1966).
P. Costa and R. R. Conte, International Symposium on Compounds of Interest in Nuclear Reactor Technology (1964), pp. 3–27.
D. A. Robins, Powder Metallurgy, 2:172 (1958).
R. Kiessling, Powder Metallurgy, 3:177 (1959).
E. Dempsey, Phil. Mag., 8:285 (1963).
N. Engel, Trans. Am. Soc. Metals, 57:610 (1964).
Yu. N. Surovoi, L. A. Shvartsman, and V. I. Alekseev, Fiz. Metal. Metalloved., 20:80 (1965).
W. H. Phillipp, NASA, TN D-3533 (1966).
W. S. Williams, Science, 152:34 (1966).
E. K. Storms, The Refractory Carbides, Academic Press, New York and London (1967).
H. J. Goldschmidt, Interstitial Alloys, Butterworths, London (1967).
J. E. Holliday, J. Appl. Phys., 38:4720 (1967).
D. W. Fisher and W. L. Baun, J. Appl. Phys., 39:4757 (1968).
S. P. Denker, J. Less-Common Metals, 14:4 (1968).
L. Ramquist, J. Anal., Vol. 153 (1969).
L. N. Dobretsov, Electronic and Ionic Emission [in Russian], Moscow and Leningrad (1952).
N. S. Burernikova, Uspekhi Fiz. Nauk, 65:351 (1958).
L.N. Branscomb and D. S. Burch, Phys. Rev., 111:504 (1958).
B. Edlen, J. Chem. Phys., 33:98 (1960).
V.I. Vedeneev et al., Ionization Potentials and Electron Affinity [in Russian], Izd. Akad. Nauk SSSR, Moscow (1962).
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Zhurakovskii, E.A. (1974). The Energy Structures of Titanium Carbide. In: Samsonov, G.V. (eds) Refractory Carbides. Studies in Soviet Science. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8598-1_21
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DOI: https://doi.org/10.1007/978-1-4684-8598-1_21
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