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Carbonimidoyl Dihalides

  • Chapter
The Chemistry of Imidoyl Halides
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Abstract

In 1874 Sell and Zierold (137) obtained phenylcarbonimidoyl dichloride I in the reaction of phenylisothiocyanate II with chlorine. Several years later, Nef (108,109)prepared carbonimidoyl dichlorides by addition of chlorine to isocyanides, such as phenyl isocyanide III. This relationship between I and isocyanides (isonitriles) led to the frequently used term isocyanide dichlorides for the compounds under discussion.

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Ulrich, H. (1968). Carbonimidoyl Dihalides. In: The Chemistry of Imidoyl Halides. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8947-7_2

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