Abstract
The increasing activity in Mössbauer effect research has resnite the publication and analysis of Mössbauer spectra of several hunderd different substances, and this new field of spectroscopy is beginning to be used as a standard analytical tool, Quantitative analysis in the presence of several phases, some of which may have overlapping lines, presents a number of problems. A method of analysis involving, compurerbased spectrum stripping is described, and examp pplications are discussed. A family of computer programs processes Mössbauer spectra for use as unknowns and reference standards and performs the stripping calculations. Reference spectra can be either least-squares-fit Lorentzian representations or tabulated functions (spectra not suitable for fitting) Appropriate amounts of any number of reference spectra are subtracted from the unknowns with the amounts being varied interatively until the residuals become satisfactorily small. This approach has been particularly useful in analyzing certain meteorite spectra, where as many as six distinct iron-containing phases have been observed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
G. K. Wertheim, Mssbauer Effect: Principles and Applications (Academic Press, New York, 1964).
A. H. Muir, Jr., K. J. Ando, and H. M. Coogan, Mossbat. 1 Data Index 1958–1965 (Interscience Publishers, New York, 1966).
Applications of the Mössbauer Effect in Chemistry - d Physics,“ Intern. At. Energy Agency, Tech. Rept. Ser, No. 50. 1996
L J. Gruverman, Ed.,Mössbauer Effect Methodology, 13 (Plenum Press, New York, 1965–1967)
E. L. Sprenkel-Segel and S. S. Hanna, Geochim. Conn Icta 28:1913 (1964).
A. H. Muir, Jr., A. C. Micheletti, and M. Blander., the 30th Annual Meeting of the Meteorological Society, M(National Aeronautics and Space Administration, 1
W. C. Davidon, Argonne National Laboratory R.:7o. m. 1959, unpublished.
Radiochemical Methods of Analysis (Proceedings the Syr n on Radiochemical Methods of Analysis, Salzburg, 1964), Vol. II, Sec.11.5 (International Atomic Energy Agency, Vienna, 1965).
R. L. Heath, R. G. Helmer, L. A. Schmittroth, and C. A. C: ziez cl. nstr. Methods 47:281 (1967); also, R. G. Helmer, R. L. Heath. Lroth, G. A. Jayne, and L. M. Wagner, Nucl. Instr..; and H. D. Graber and D. D. Watson, Nucl. Instr. Methodg
D. A. Shirley, M. Kaplan, and P. Axel, Phys. Rev
G. A. Bykov and Pham Zuy Hein, Zh. Eksperim. i reor. Ti. 47 (1962); English transi., Soviet Phys. JETP 16:646 (1963).
R. S. Preston, S. S. Hanna, and J. Heberie, Phys. Rev 126:2207 (1962).
G. Lang, Nucl. Instr. Methods 24:425 (1963).
D. A. O’Connor, Nucl. Instr. Methods 21:318 (1963).
R. M. Housley, N. E. Erickson, and J. G. Dash, Nuel. Instr, Methods 27:29 (1964).
S. Margulies and J. R. Ehrman, Nuel. Instr, Methods 12:131 (1961); also, S. Margulies, P. Debrunner, and H. Frauerifelder, Nucl,Instr, Methods 21:217 (1963).
J. Heberle, Nucl. Instr. Methods 58:90 (1968); also, D. W. Haferneister and E. B. Shera, /Niue/. or. Methods 41:133 (1966); and S. L. Ruby and J. M. Hicks, Rev. Set Instr 33:27 (1962).
R. M. Housley and R. W. Grant (to be published)
R. M. Housley, Nucl. Instr. Methods 35:77 (1965).
Programmer’s Reference Manual S-C 4020 Comcuttrom- berg-Carlson Document No. 9500056, 1964, rev. 1960, mi.
A. C. Micheletti and A. H. Muir, Jr. (to be public
H. Wiedersich, J. W. Savage, H. Muir, Jr., and 1 1, Swarthout, Mineral. Hag 36:643 (1968)
S. Hafner and M. Kalvius, Z. Krist 123:443 (1966).
A. Gerard and M. Delmelie, Compt. Rend 259:1756 (1’’’); also, Geo-iIntern 1:336 (1964).
E. L. Sprenkel-Segel and S. S. Hanna, “Mbssbaui of Ie Iron Minerals,” in: Mössbauer Effect Methodology, I J. Call Ed. (Plenum Press, New York, 1966), p. 113.
E. L. Sprenkel-Segel and G. J. Perlow, Icarus 8:66 (1“
E. L. Sprenkel-Segel, private communication.
U. Gonser, R. W. Grant, A. H. Muir, Jr., and H. W:edersicb, Acta Met 14:259 (1966).
A. A. Temperley and H. W. Lefevre, J. Phys. Chem,Solids 27:85 (1966).
M. Abdel Gawad, private communication.
M. J. Rossiter and A. E. M. Hodgson, J. Inorg, Nigel. Cher 27:63 (1965).
C. L. Herzenberg and D. Toms. J. Geophys Res 71:2661
B. Mason, Am. Mineralogist 52:307 (1967).
A. FI. Muir, Jr., and M. Abdel Gawad (to be publish
C. E. Johnson, M. S. Ridout, and T. E. Cranshaw, Pro,Pro,4. Soc, (London) 81:1079 (1963).
B. J. Evans, S. Ghose, and S. Hafner, J. Gem 75:306 (1967)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1968 Springer Science+Business Media New York
About this paper
Cite this paper
Muir, A.H. (1968). Analysis of Complex Mössbauer Spectra by Stripping Techniques. In: Gruverman, I.J. (eds) Mössbauer Effect Methodology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1550-7_5
Download citation
DOI: https://doi.org/10.1007/978-1-4757-1550-7_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-1552-1
Online ISBN: 978-1-4757-1550-7
eBook Packages: Springer Book Archive