Abstract
Many chemical reactions of water-soluble polymers are possible, depending on the presence of reactive groups attached to a polymer chain able to combine with other water-soluble polymers (polymeric or otherwise) under conditions which do not significantly degrade the polymer. Since the property of water solubility implies the presence of a substantial number of polar groups in the molecule, the potential and, indeed, the actual degree of complexity of chemical behaviour is considerable. It is therefore worth establishing some simple principles, common to most water-soluble polymers, which describe the actual or possible cross-linking reactions. In general, and with a considerable degree of over-simplification, ‘chemical modification’ can be considered as a part-way stage towards the cross-linking which results in a more rigid, and possibly less soluble, molecular structure.
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General Reading
H. Morawetz, ‘Macromolecules in Solution’. 2nd. Ed. 1975:New York. John Wiley & Sons.
R.L. Davidson (Ed.), ‘Handbook of Water-soluble Gums and Resins’ 3rd. Ed. 1980: New York. McGraw-Hill.
N.M. Bikales (Ed.), ‘Water-Soluble Polymers’ (A.C.S. Symposium, 1972) 1973:New York. Plenum Press.
S.P. Rowland (Ed.), ‘Water in Polymers’ (A.C.S. Symposium, 1979) 1980: New York. American Chemical Society.
S.C. Temin, ‘Cross-linking’ in ‘Encyclopedia of Polymer Science & Technology’ (Ed. by H.F. Mark et al.) 1966:New York. John Wiley & Sons. Vol. 4, 331–398.
E.A. MacGregor and C.T. Greenwood, ‘Polymers in Nature’. 1980:Chiehester John Wiley & Sons.
A.G. Ward and A. Courts (Eds.), ‘Science and Technology of. Gelatin’ 1977: London. Academic Press.
A. Veis, ‘Macromolecular chemistry of Gelatin’. 1965:New York. Academic Press.
R.A. Milch, ‘Reaction of certain aliphatic aldehydes with gelatin’ Gerontologia, 1964/1965, 10, 117–136.
Synthetic hydroxy-polymers
C.A. Finch (Ed.), ‘Polyvinyl Alcohol: Properties and Applications’ 1973:Chiehester. Wiley-Interscience.
O. Wichterle, ‘Hydrogels’ in ‘Encyclopedia of Polymer Science & Technology’ (Ed. by H.F. Mark et al.) 1971:New York. John Wiley & Sons. vol.15, pp.273–291.
M.F. Refugo, ‘Contact Lenses’, ‘Encyclopedia of Polymer Science & Technology’.,1977, Suppl. vol.1, pp.195–219.
M.F. Refugo, ‘Contact Lenses’ in ‘Encyclopedia of Chemical Technology’ (Ed. M.F. Grayson et al.) 1979:New York. John Wiley & Sons. Vol.6, pp.720–742.
D.C. Pedley, P.J. Skelly and B.J. Tighe, ‘Hydrogels in biomedical applications’ Br.polym.J.,1980, 12, 99–110.
Miscellaneous
G. Manecke and P. Reuter, ‘Reactions on and with Polymers’ Pure & Applied Chenu, 1979,51, 2313–2330.
Y.L. Metzler (Ed.), ‘Water Soluble Polymers — Developments since 1978’ (summary of U.S. Patent literature) 1981: Park Ridge, New Jersey: Noyes Data Corporation (and earlier volumes).
References
P.J. Flory, J. Amer.chem.Soc, 1941, 63, 3083.
W.H. Stockmayer, J.chem.Phys., 1945, 11, 45.
M. Gordon and J. A. Torkington, Pure & Applied Chem., 1981, 53, 1461.
P.J. Flory, ‘Principles of Polymer Science’. 1953:Ithaca. Cornell University Press. pp.356–361.
W. Kuhn and G. Balmer, J.polymer Sci., 1962, 57, 311; K.W. Kilb, ibid.,1959, 38, 403.
A.G. Ward and A. Courts (Eds.), ‘Science and Technology of Gelatin’, 1977:London. Academic Press.
P.J. Flory and J. Reiher, J.chem.Phys.,1943,11,521.
P.J. Flory, Disc. Faraday Soc., 1974, 57, 1.
J. A. Radley (Ed.), ‘Industrial Uses of Starch and its Derivatives’. 1976: London, Applied Science Publishers.
J. A. Radley (Ed.), ‘Starch and its Derivatives’, 1968:London. Chapman & Hall.
J. T. Marsh, ‘Self-Smoothing Fabrics’, 1962:London. Chapman & Hall.
A.H. Nissan, G. Khunger and S.S. Sterstein, in ‘Encyclopedia of Polymer Science & Technology’ (Ed. by H.F. Mark et al.), 1965: New York. John Wiley & Sons, Vol.3, pp.131–226.
S.P. Rowland, ‘Cellulose — Distribution of Substituents’, Encyclopedia of Polymer Science & Technology, 1977, Suppl. Vol. 1, 146–175.
G. Stainsby, in Ref 6, p.179.
R.C. Clark and A. Courts, in Ref.6, p.209.
F. Sanger, Biochem.J., 1945, 39, 507.
T.C. Mullen, J.soc.Leather Trades chem., 1962, 46, 162.
E.g. Fuji Photo Film Co., Brit.Pat. 1,022,656 (1966).
Ref.6, p.218.
A.W. Kenchington, Biochem.J., 1958, 68, 458.
Agfa A.G., Belg.Pat. 662,606 (1965).
D.G. Hoare and D.E. Koshland, J. Amer.chem.Soc., 1966, 88, 2507.
See D.M. Burness and J. Pouradier in ‘Theory of the Photographic Process’ (Ed.T.H. James) 4th. Ed. 1977:New York. Macmillan. pp. 77–87.
E.g.H. Sera, T. Ishii, J. Yamaguchi and H. Shiraishi (to Fuji Photo Film Co.), U.S.Pat.4,173,481 (1979).
K. Emoto, K. Yabuta, K. Yamashita and K. Futaki (to Mitsubishi Paper Mills), U.S.Pat. 4,134,770 (1979).
Gevaert Photo-Producten N.V., Brit.Pat. 990, 275 (1965).
P. Alexander, M. Fox, K.A. Stacey and L.F. Smith, Biochem.J., 1952, 52, 177.
H. Bestian, Ann.chim.,1950, 506, 210.
See Ref. 6, pp.226,229, and also R.J. Croome and D.B. Thomas(to P. Leiner & Sons Ltd.) U.S.Pat.4,072,624 (1978).
E.g. C.F.H. Allen, R.H. Talbot, J. Yuderson and D.A. Smith, U.S.Pat. 3,047,394 (1962); VEB Filmfabrik Agfa Wolfen, Ger.Pat.1, 085, 663 (1960); D.M. Burness, U.S.Pat.3, 189,459 (1965).
W.O. Kenyon, D.A. Smith, and E.W. Taylor, U.S.Pat.3, 220, 864 (1965).
B.H. Kress, U.S.Pat.2, 868, 773 (1959).
A. Courts and P. Homan, J.appl.polymer Sci., 1972, 22, 1253, and also Ref. 6, p.232.
B.E. Tabor, J.appl.polymer Sci., 1968, 12, 1967.
I.D. Robinson, J.appl.polymer Sci. 1964, 8, 1903.
P. Davis and B.R. Tabor, J.polymer Sci., A, 1963, 1, 799.
J. H. Bowes and C.W. Cater, Biochim.biophys. Acta, 1968, 168, 341; J.appl.Chem.,1965, 15, 296.
J. H. Bowes, C.W. Cater, and M.J. Ellis, J. Amer.leather Chem.Assoc., 1965, 60, 275.
E.g. R.A. Jeffreys, B.E. Tabor, and D.M. Burness, U.S.Pat.3,034,894 (1962), 3,057,723 (1962),3,062,652 (1962); Kodak Ltd., Brit.Pat. 921, 120 (1963), 928, 591 (1963).
C.F.H. Allen and T.M. Laakso, U.S.Pat.2, 726, 162 (1955); 2, 816, 125 (1957).
C.F.H. Allen and B.H. Carroll, U.S.Pat.2, 725, 295 (1955).
N. Yamamoto and Y. Oishi, U.S.Pat. 3, 325, 287 (1967).
R. Ohi, N. Yamamoto and K. Hori, in ‘Photographic Gelatin’ (Ed. R.H. Cox) 1972:London. Academic Press.
In R.L. Whistler, ‘Industrial Gums’, 1973:New York. Academic Press.
See, e.g. B.K. Green (to National Cash Register Co. Inc)U.S.Pat. Reissue 24, 899 (1960); 2,800,457.
A. Kondo, ‘Microcapsule Processing and Technology’ 1979:New York. Marcel Dekker Inc.
R.E. Sparkes, ‘Microencapsulation’ in ‘Encyclopedia of Chemical Technology’ 3rd. Ed. (Ed. M. Grayson et al.) 1981:New York. John Wiley & Sons. Vol. 15.
Ref. 6, p.238.
For detailed References, see especially K. Noro in ‘Polyvinyl Alcohol: Properties and Applications’ (Ed. C.A. Finch). 1973: Chiehester. John Wiley & Sons. Chapters 3 and 4.
A.S. Dunn, Chem. & Ind.,1980,801.
See, e.g. J. G. Pritchard ‘Poly(vinyl alcohol): Basic Properties and Uses’ 1970:London. Gordon & Breach.
C.A. Finch, ‘Polyvinyl Alcohol: Properties and Applications’ 1973:Chichester. John Wiley & Sons. Chapter 9.
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Finch, C.A. (1983). Chemical Modification and Some Cross-linking Reactions of Water-Soluble Polymers. In: Finch, C.A. (eds) Chemistry and Technology of Water-Soluble Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9661-2_5
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DOI: https://doi.org/10.1007/978-1-4757-9661-2_5
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