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Molecular Motion in Concentrated Polymer Systems: High-Frequency Behavior

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Polymers in Solution

Abstract

An understanding of the various types of molecular motion possible in polymer solutions has recently become possible by the correlation of various types of experimental observation with the predictions of theory. How changes in concentration influence the spectrum of high-frequency motions in solution and in the melt will be the underlying theme of this chapter.

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References

  1. P. A. Rouse, J. Chem. Phys. 21, 1272 (1953).

    Article  CAS  Google Scholar 

  2. B. H. Zimm, J. Chem. Phys. 24, 269 (1956).

    Article  CAS  Google Scholar 

  3. R. Simha and L. Ultracki, J. Polym. Sci. A2 (5), 853 (1967).

    Google Scholar 

  4. S. F. Edwards, Proc. Phys. Soc. (London) 88, 265 (1966).

    Article  CAS  Google Scholar 

  5. P. G. de Gennes, Macromolecules 9, 587 (1976).

    Article  Google Scholar 

  6. F. G. Wang and B. H. Zimm, J. Polym. Sci. Polym. Phys. 12, 1619 (1974).

    Article  CAS  Google Scholar 

  7. M. Daoud, J. P. Cotton, Farnoux B., G. Jannink, G. Sarma, H. Benoit, R. Duplessix, C. Picot, and P. G. de Gennes, Macromolecules 8, 804 (1975).

    Article  CAS  Google Scholar 

  8. S. F. Edwards and E. F. Jeffers, J. Chem. Soc. Faraday Trans 2 75, 1020 (1979).

    Article  CAS  Google Scholar 

  9. R. W. Richards, A. Maconnachie, and G. Allen, Polymer 19, 266 (1978).

    Article  CAS  Google Scholar 

  10. J. P. Cotton, M. Nierlich, F. Boue, M. Daoud, B. Farnoux, G. Jannink, R. Duplessix, and C. Picot, J. Chem. Phys. 65, 1101 (1976).

    Article  CAS  Google Scholar 

  11. R. W. Richards, A. Maconnachie, and G. Allen, Polymer 22, 147 (1981).

    Article  CAS  Google Scholar 

  12. E. Wyn-Jones, and R. A. Pethrick, Topics in Stereochemistry(E. L. Eliel and N. Allinger, eds.), Vol 5, p. 205, Wiley-Interscience, New York (1970).

    Google Scholar 

  13. W. H. Stockmayer (1967), Pure Appl. Chem. 15, 539 (1967).

    Article  Google Scholar 

  14. A. M. North and P. J. Phillips, Chem. Commun. 1340(1968).

    Google Scholar 

  15. K. Matsuo, Ph.D. thesis, MIT (1960).

    Google Scholar 

  16. H. Block, E. F. Hayes, and A. M. North, Trans. Faraday Soc. 66, 1095 (1970).

    Article  CAS  Google Scholar 

  17. T. W. Bates, K. J. Ivin, and G. Williams, Trans. Faraday Soc. 63, 1976 (1967).

    Article  CAS  Google Scholar 

  18. S. Mashimo, Macromolecules 9, 91 (1976).

    Article  CAS  Google Scholar 

  19. C. H. Porter, J. H. Lawler, and R. H. Boyd, Macromolecules 3, 308 (1970).

    Article  CAS  Google Scholar 

  20. C. H. Porter and R. H. Boyd, Macromolecules 4, 589 (1971).

    Article  CAS  Google Scholar 

  21. W. H. Stockmayer and K. Matsuo, Macromolecules 5, 766 (1972).

    Article  CAS  Google Scholar 

  22. W. H. Stockmayer, A. A. Jones, and T. L. Treadwell, Macromolecules 10, 762 (1977).

    Article  CAS  Google Scholar 

  23. M. A. Cochran, A. M. North, and R. A. Pethrick, J. Chem. Soc. Faraday Trans. 2 70, 215 (1974).

    Article  CAS  Google Scholar 

  24. H. Nomura, S. Kato, and Y. Miyahara, Nippon Kagahu Zasshi 88, 502 (1967).

    Article  CAS  Google Scholar 

  25. B. Froelich, B. Jasse, and L. Monnerie, Chem. Phys. Lett. 44, 159 (1976).

    Article  CAS  Google Scholar 

  26. B. Froelich, B. Jasse, C. Noel, and L. Monnerie, J. Chem. Soc. Faraday Trans. 2 74, 445 (1978).

    Article  CAS  Google Scholar 

  27. R. Duplessix, J. P. Cotton, H. Benoit, and C. Picot, Polymer 20, 1181 (1979).

    Article  CAS  Google Scholar 

  28. F. Boue, Diplome de Docteur These Universite Louis Pasteur, Strasbourg (1977).

    Google Scholar 

  29. J. H. Dunbar, A. M. North, R. A. Pethrick, and D. B. Steinhauer, J. Chem. Soc. Faraday 2 70, 1478 (1974).

    Google Scholar 

  30. M.A. Cochran, P. B. Jones, A. M. North, and R. A. Pethrick, Trans. Faraday Soc. 68, 1719 (1972).

    Article  CAS  Google Scholar 

  31. F. Laupretre, C. Noel, and L. Monnerie, J. Polym. Sci. Polym. Phys. 15, 2127 (1977).

    Article  CAS  Google Scholar 

  32. B. Valeur, L. Monnerie, and J. P. Jarry, J. Polym. Sci. Polym. Phys. 13, 675 (1975).

    Article  Google Scholar 

  33. B. Valuer, J. P. Jarry, F. Geny, and L. Monnerie, J. Polym. Sci. Polym. Phys. 13, 2251 (1975).

    Article  Google Scholar 

  34. F. Heatley and M. K. Cox, Polymer 18, 225 (1977).

    Article  CAS  Google Scholar 

  35. F. Heatley, A. Begum, and M. K. Cox, Polymer 18, 637 (1977).

    Article  CAS  Google Scholar 

  36. F. Heatley and B. Wood, Polymer 19, 1405 (1978).

    Article  CAS  Google Scholar 

  37. A. A. Jones, and W. H. Stockmayer, J. Polym. Sci. Polym. Phys. 15, 847 (1977).

    Article  CAS  Google Scholar 

  38. A. M. North, R. A. Pethrick, and I. Rhoney, J. Chem. Soc. Faraday Trans. 2 70, 223 (1974).

    Article  CAS  Google Scholar 

  39. A. V. Cunliffe and R. A. Pethrick, Polymer 21, 1025 (1980).

    Article  CAS  Google Scholar 

  40. J. H. Dunbar, R. A. Pethrick, A. M. North, and B. T. Poh, Polymer 21, 764 (1980).

    Article  CAS  Google Scholar 

  41. A. M. North, R. A. Pethrick, and B. T. Poh, Polymer 21, 772 (1980).

    Article  CAS  Google Scholar 

  42. K. J. Liu and R. Ullman, Polymer 6, 100 (1965).

    Article  CAS  Google Scholar 

  43. M. Kobayaski, K. Tsumura, and H. Tadokora, J. Polym. Sci. A2 (6), 1492 (1968).

    Google Scholar 

  44. W. R. Krigbaum, F. Mark, J. G. Pritchard, W. L. Hunter, and A. Ciferri, Makromol. Chem. 65, 101 (1963).

    Article  CAS  Google Scholar 

  45. C. Reiss and H. Benoit (1961). C. R. Acad. Sci. 253, 268 (1961).

    CAS  Google Scholar 

  46. R. J. Abraham and E. Bretschneider, Internal Rotation in Molecules(W. J. Orville Thomas, ed.), p. 481, Wiley, London (1974).

    Google Scholar 

  47. R. J. Abrahams, K. J. Pacjler, and P. L. Z. Weiss, Phys. Chem. 58, 257 (1968).

    Google Scholar 

  48. A. T. Bullock and G. G. Cameron, Structural Studies of Macromolecules by Spectroscope Methods(K. J. Ivin, ed.), p. 273, Wiley, New York (1976).

    Google Scholar 

  49. E. Helfand, J. Chem. Phys. 54, 4651 (1971).

    Article  Google Scholar 

  50. A. T. Bullock, G.G.Cameron, and P.M. Smith (1974). J. Chem. Soc. Faraday Trans. 2 70, 1202 (1974).

    Article  CAS  Google Scholar 

  51. J.I. Dunbar, A. M. North, R. A. Pethrick, and D. B. Steinhauer, J. Polym. Sci. Polym. Phys. 15, 263 (1977).

    Article  CAS  Google Scholar 

  52. A. M. North, Chem. Soc. Rev. 1, 49 (1972).

    Article  CAS  Google Scholar 

  53. J. P. Cohen-Added, A. Guillermo, and J. P. Messa, Polymer 20, 536 (1979).

    Article  Google Scholar 

  54. A. J. Matheson and B. J. Cooke, J. Chem. Soc. Faraday Trans. 2 72, 679 (1976).

    Article  Google Scholar 

  55. A. J. Matheson and B. J. Cooke, Faraday Symp. Chem. Soc. 6, 194 (1972).

    Article  Google Scholar 

  56. K. Osaki, Adv. Polym. Sci. 12, 1 (1978).

    Article  Google Scholar 

  57. W. N. Hunter and A. M. North, Polymer 20, 1179 (1979).

    Article  CAS  Google Scholar 

  58. P. G. de Gennes and L. A. Lazar, Rev. Phys. Chem. 33, 49 (1982).

    Article  Google Scholar 

  59. M. Doi and S. F. Edwards, J. Chem. Soc. Faraday Trans. 2 74, 1818 (1978).

    Article  CAS  Google Scholar 

  60. M. Doi (1980). J. Polym. Sci. Polym. Phys. 18, 1005 (1980).

    Article  CAS  Google Scholar 

  61. W. Bell, A. M. North, R. A. Pethrick, and B. T. Poh, J. Chem. Soc. Faraday Trans. 2 75, 1115 (1979).

    Article  CAS  Google Scholar 

  62. A. J. Barlow, G. Harrison, and J. Lamb, Proc. R. Soc. (London) Ser. A 282, 228 (1964).

    Article  CAS  Google Scholar 

  63. S. P. Chen and J. D. Ferry, Macromolecules 1, 270 (1968).

    Article  CAS  Google Scholar 

  64. J. E. Tanner, K. J. Liu, and J. E. Anderson, Macromolecules 4, 586 (1971).

    Article  CAS  Google Scholar 

  65. R. Kimmich, Polymer 18, 233 (1977).

    Article  CAS  Google Scholar 

  66. W. Grassley, J. Polym. Sci. Polym. Phys. 18, 27 (1980).

    Article  Google Scholar 

  67. H. Eyring, Science 199, 740 (1978).

    Article  CAS  Google Scholar 

  68. W. Bell and R. A. Pethrick, Acoust. Lett. 3, 156 (1980).

    CAS  Google Scholar 

  69. W. Bell, J. Daly, A. M. North, R. A. Pethrick, and B. T. Poh, J. Chem. Soc. Faraday Trans. 2 75, 1452 (1979).

    Article  CAS  Google Scholar 

  70. A. R. Eastwood, A. M. North, and R. A. Pethrick, unpublished data.

    Google Scholar 

  71. R. A. Pethrick, Aggregation Processes in Solution(E. Wyn Jones and J. Gormally, eds.), Elsevier, New York, Chapter 20 (1983).

    Google Scholar 

  72. R. A. Pethrick, J. Macromol. Sci. Rev. Macromol. Chem. C9, 91 (1973).

    Article  Google Scholar 

  73. D. Pugh and R. A. Pethrick, Chem. Britain 70 (1980).

    Google Scholar 

  74. D. A. Jones, M. Lopez de Haro, and D. Pugh, J. Polym. Sci. Polym. Phys. 16, 2215 (1975).

    Google Scholar 

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Authors and Affiliations

  1. Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, Scotland, UK

    Richard A. Pethrick

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  1. Richard A. Pethrick
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Editors and Affiliations

  1. University of Pennsylvania, Philadelphia, Pennsylvania, USA

    William C. Forsman

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Pethrick, R.A. (1986). Molecular Motion in Concentrated Polymer Systems: High-Frequency Behavior. In: Forsman, W.C. (eds) Polymers in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0465-2_5

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  • DOI: https://doi.org/10.1007/978-1-4899-0465-2_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0467-6

  • Online ISBN: 978-1-4899-0465-2

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