Skip to main content
SpringerLink
Log in

Molecular and Colloidal Structure of Coal Asphaltenes and Other Heavy Solvent Soluble Components

  • Chapter
Structures and Dynamics of Asphaltenes

Abstract

Coal is a complex organic substance in which aromatic and heteroaromatic rings with hydroxyl and alkyl groups are connected through the bonds such as methylene and ether, and naphthene rings. Coal has a wide range of chemical compositions and properties, and ASTM classification widely used defines anthracite, low, medium, and high-volatile bituminous coal, subbituminous coal, and lignite, according to their heating value, volatile matter and fixed carbon content. The carbon% of coal, expressed as dry and mineral matter free basis, is in the range of about 65–95% and increases with coal rank, i.e., from lignite to anthracite, with the accompanying decrease of oxygen and hydrogen %. Coal also generally includes a small percentage of minerals that can be removed by acid washing.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. Steedman, Fuel Process. Technol., 10, 209 (1985).

    Article  CAS  Google Scholar 

  2. V.I. Stenberg, R.J. Richard, J. Baltisberger, K.M. Patal, K. Raman, N.F. Woolsey, in “Coal Science,” M.L. Gorbaty, J.W. Larsen, I. Wender (Ed.) Academic Press, New York, Vol.2,125 (1982).

    Google Scholar 

  3. K. Iwata, H. Itoh, K. Ouchi, Fuel Process. Technol., 3, 25 (1980).

    Article  Google Scholar 

  4. M. Iino, T. Takanohashi, H. Ohsuga, K. Toda, Fuel, 67, 1639 (1988).

    Article  CAS  Google Scholar 

  5. M. Iino, H. Liu, N. Hosaka, H. Kurose, T. Takanohashi, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 42(1),248(1997).

    CAS  Google Scholar 

  6. M. Nishioka, Fuel, 72, 1719 (1993).

    Article  CAS  Google Scholar 

  7. B.C. Bockrath, R.P. Noceti, Fuel Process. Technol., 2, 143 (1979).

    Article  CAS  Google Scholar 

  8. L.A. Heredy, M.B. Neuwarth, Fuel, 41, 221 (1962).

    CAS  Google Scholar 

  9. K. Ouchi, K. Imuta, Y. Yamashita, Fuel, 44, 205 (1965).

    CAS  Google Scholar 

  10. L.J. Darlage, J.P. Weidner, S.S. Block, Fuel, 53, 54 (1974).

    Article  Google Scholar 

  11. G.A. Olah, M.R. Bruce, E.H. Edelson, A. Husain, Fuel, 63, 1130 (1984).

    Article  CAS  Google Scholar 

  12. H.W. Sternberg, C.L.D. Donne, P. Pantages, E.C. Moroni, R.E. Markby, Fuel, 50, 432 (1971).

    Article  CAS  Google Scholar 

  13. H.W. Stemberg, C.L.D. Donne, Fuel, 53, 172 (1974).

    Article  Google Scholar 

  14. N. Cyr, M. Gawlak, D. Carson, B. Ignasiak, Fuel, 62, 412 (1983).

    Article  CAS  Google Scholar 

  15. B. Ignasiak, D. Carson, M. Gawlak, Fuel, 58, 833 (1979).

    Article  CAS  Google Scholar 

  16. C.J. Collins, E.W. Hagaman, R.M. Jones, V.F. Raaen, Fuel, 60, 359 (1981).

    Article  CAS  Google Scholar 

  17. T.G. Squires, C.G. Venier, J.D. Hunt, J.C. Shei, B.F. Smith, Fuel, 61, 1170 (1982).

    Article  CAS  Google Scholar 

  18. R.R. Chambers Jr., D. Mckamey, Fuel, 63, 868 (1984).

    Article  CAS  Google Scholar 

  19. N.E. Cooke, R.P. Gaikwad, Fuel, 63, 1468 (1984).

    Article  CAS  Google Scholar 

  20. F.K. Schwager, B.M. Thamers, Anal. Chem., 49, 2363 (1978).

    Article  Google Scholar 

  21. A. Marzec, D. Bodzek, T. Krzyzanowska, in “Organic Chemistry of Coal,” ACS Symposium Series 71, J.W. Larsen (Ed.), Am. Chem. Soc, 71 (1978).

    Google Scholar 

  22. C.E. Snape, K.D. Bartle, Fuel, 63, 883 (1984).

    Article  CAS  Google Scholar 

  23. C.E. Snape, K.D. Bartle, Fuel, 64, 427 (1985).

    Article  CAS  Google Scholar 

  24. K. Ouchi, Fuel, 64, 427 (1985).

    Article  Google Scholar 

  25. J.R. Brown, W.R. Ladner, Fuel, 39, 87 (1960).

    CAS  Google Scholar 

  26. H.L. Retcofsky, R.A. Friedel, Fuel, 47, 487 (1968).

    CAS  Google Scholar 

  27. M. Kanda, M. Kooriki, Y. Sanada, Fuel, 57, 676 (1978).

    Article  CAS  Google Scholar 

  28. T.H. Fletcher, S. Bai, R.J. Pugmire, M.S. Solum, S. Wood, D.M. Grant, Energy & Fuels, 7, 734 (1993).

    Article  CAS  Google Scholar 

  29. S. Friedman, M.L. Kaufman, W.A. Steiner, I. Wender, Fuel, 40, 33 (1961).

    CAS  Google Scholar 

  30. M. Iino, T. Takanohashi, S. Obara, H. Tsueta, Y. Sanokawa, Fuel, 68, 1588 (1989).

    Article  CAS  Google Scholar 

  31. K.D. Bartle, T.G. Martin, D.F. Williams, Fuel, 54, 226 (1975).

    Article  CAS  Google Scholar 

  32. M. Makabe, K. Ouchi, Fuel, 58, 43 (1979).

    Article  CAS  Google Scholar 

  33. M. Makabe, K. Ouchi, Fuel Process. Technol., 2, 131 (1979).

    Article  CAS  Google Scholar 

  34. K. Ouchi, K. Suzuki, T. Katoh, H. Itoh, Fuel, 64, 133 (1985).

    Article  CAS  Google Scholar 

  35. T. Sakabe, K. Inoue, K. Ouchi, H. Honda, J. Fuel Soc. Jpn., 32, 610 (1953).

    Article  CAS  Google Scholar 

  36. K. Iwata, F. Mondragon, H. Itoh, K. Ouchi, Fuel, 63, 1528 (1984).

    Article  CAS  Google Scholar 

  37. M. Nomura, K. Matsubayashi, T. Ida, S. Murata, Fuel Process. Technol., 31, 169 (1992).

    Article  CAS  Google Scholar 

  38. J.M. Charlesworth, Fuel, 59, 865 (1980).

    Article  CAS  Google Scholar 

  39. P. Redlich, W.R. Jackson, F.P. Larkins, Fuel, 64, 1383 (1985).

    Article  CAS  Google Scholar 

  40. L.L. Anderson, K.E. Chung, R.J. Pugmire, J. Shabtai, in “New Approaches in Coal Chemistry.” ACS Symposium Series 169, B.D. Blaustein, B.C. Bockrath, S. Friedman (Eds.), Am. Chem. Soc, 2231981 (1978).

    Google Scholar 

  41. C.E. Snape, W.R. Ladner, Fuel Process. Technol., 8, 155 (1984).

    Article  CAS  Google Scholar 

  42. J.H. Shinn, Fuel, 63, 1187 (1984).

    Article  CAS  Google Scholar 

  43. K. Nakamura, T. Takanohashi, M. Iino, H. Kumagai, M. Sato, S. Yokoyama, Y. Sanada, Energy & Fuels, 9, 1003(1995).

    Article  CAS  Google Scholar 

  44. T. Katoh, K. Ouchi, Fuel, 64, 1260 (1985).

    Article  CAS  Google Scholar 

  45. T. Katoh, K. Ouchi, Fuel, 66, 58 (1987).

    Article  CAS  Google Scholar 

  46. T.F. Yen, Amer. Chem. Soc, Div. Pet. Chem., Prep., 24, 901 (1979).

    CAS  Google Scholar 

  47. O.C. Mullins, S. Mitra-Kirtley, J.V. Elp, S.P. Cramer, Applied Spectroscopy, 47, 1268 (1993).

    Article  CAS  Google Scholar 

  48. H.W. Sternberg, R. Raymond, F.K. Schweigehardt, Science, 188, 49 (1975).

    Article  CAS  Google Scholar 

  49. F.R. Brown, S. Friedman, L.E. Makovsky, F.K. Schweighardt, Appl. Spectrosc, 31, 241 (1977).

    Article  CAS  Google Scholar 

  50. S.R. Taylor, N.C. Li, Fuel, 57, 117 (1978).

    Article  CAS  Google Scholar 

  51. F.K. Schweighardt, R.A. Friedel, H.L. Retcofsky, Appl. Spectrosc, 30, 291 (1976).

    Article  CAS  Google Scholar 

  52. K.C. Tewari, N. Kan, D.M. Susco, N.C. Li, Anal. Chem., 51, 182 (1979).

    Article  CAS  Google Scholar 

  53. K.C. Tewari, J. Wang, N.C. Li, H.J.C. Yeh, Fuel, 58, 371 (1979).

    Article  CAS  Google Scholar 

  54. K.M. Patel, V.I. Stenberg, R.J. Baltisberger, N.F. Woolsey, K.J. Klabunde, Fuel, 59, 449 (1980).

    Article  CAS  Google Scholar 

  55. K.A. Gould, Fuel, 58, 550(1979).

    Article  CAS  Google Scholar 

  56. C.E. Snape, K.D. Bartle, Fuel, 58, 898 (1979).

    Article  CAS  Google Scholar 

  57. J.W. Larsen, A.J. Baskar, Energy & Fuel, 1, 230 (1987).

    Article  CAS  Google Scholar 

  58. K. Miura, K. Mae, F. Morozumi, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 42(1),209 (1997).

    CAS  Google Scholar 

  59. P.B. Hirsch, Proc Roy. Soc, A226, 143 (1954).

    Google Scholar 

  60. D.L. Wertz, M. Bissell, Energy & Fuels, 8, 613 (1994).

    Article  CAS  Google Scholar 

  61. I. Schwager, T.F. Yen, Fuel, 58, 219 (1979).

    Article  CAS  Google Scholar 

  62. E.M.Y. Quinga, J.W. Larsen, Energy & Fuels, 1, 300 (1987).

    Article  CAS  Google Scholar 

  63. M. Miyake, L.M. Stock, Energy & Fuel, 2, 815 (1988).

    Article  CAS  Google Scholar 

  64. H. Liu, T. Ishizuka, T. Takanohashi, M. Iino, Energy & Fuels, 7, 1108 (1993).

    Article  CAS  Google Scholar 

  65. M. Nishioka, L.A. Gebhard, B.G. Silbernagel, Fuel, 70, 341 (1991).

    Article  CAS  Google Scholar 

  66. S. Duber, J. mikosz, Fuel, 72, 267 (1993).

    Article  CAS  Google Scholar 

  67. H.L. Retcofsky, M.R. Hough, M.M. Maguire, R.B. Clarkson, Am. Chem. Soc. Adv. Chem. Ser., 192, 37 (1981).

    Article  CAS  Google Scholar 

  68. CM. White, C.E. Schmidt, Fuel, 66, 1030 (1987).

    Article  CAS  Google Scholar 

  69. H.-P. Hombach, Fuel, 61, 215(1982).

    Article  CAS  Google Scholar 

  70. J. W. Larsen, D. Lee, Fuel, 62, 918 (1983).

    Article  CAS  Google Scholar 

  71. D. Seyferth, D.P. Duncan, H.W. Sternberg, Fuel, 58, 74 (1979).

    Article  CAS  Google Scholar 

  72. Y. Sanokawa, T. Takanohashi, M. Iino, Fuel, 69, 1577 (1990).

    Article  CAS  Google Scholar 

  73. T. Ishizuka, T. Takanohashi, O. Ito, M. Iino, Fuel, 72, 579 (1993).

    Article  CAS  Google Scholar 

  74. I. Schwager, W.C. Lee, T.F. Yen, Anal. Chem.,49, 2363 (1977).

    Article  CAS  Google Scholar 

  75. H.-P. Hombach, Fuel, 60, 663 (1981).

    Article  CAS  Google Scholar 

  76. C.J. Collins, R. Triolo, M.H. Lietzke, Fuel, 63, 1202 (1984).

    Article  CAS  Google Scholar 

  77. J.W. Larsen, A.R. Lapucha, P.C. Wemett, W.A. Anderson, Energy & Fuel, 8, 258 (1994).

    Article  CAS  Google Scholar 

  78. W.C. Lee, I. Schwager, T.F. Yen, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 23(2), 37 (1978).

    CAS  Google Scholar 

  79. B.C. Bockrath, R.B. Lacount, R.P. Noceti, Fuel Process. Technol., 1, 217 (1978).

    Article  CAS  Google Scholar 

  80. B.C. Bockrath, R.B. Lacount, R.P. Noceti, Fuel, 59, 621 (1980).

    Article  CAS  Google Scholar 

  81. M.B. Jones, J.K. Argasinski, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 30(4), 250 (1985).

    CAS  Google Scholar 

  82. J.K. Argasinski, M.B. Jones, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 32(1), 604 (1987).

    CAS  Google Scholar 

  83. K. Hayasaka, T. Takanohashi, M. Iino, Energy & Fuels, 10, 262 (1996).

    Article  CAS  Google Scholar 

  84. E.Y. Sheu, M.M. De Tar, D.A. Storm, Fuel, 67, 1639 (1988).

    Article  Google Scholar 

  85. E.Y. Sheu, D.A. Storm, Fuel, 73, 1368 (1994).

    Article  CAS  Google Scholar 

  86. B. Ho, D. Brigs, Colloids Surf., 4, 285 (1982).

    Article  CAS  Google Scholar 

  87. I. Schwager, P.A. Farmanlan, J.T. Kwan, V.A. Weinberg, T.F. Yen, Anal. Chem., 55, 42 (1983).

    Article  CAS  Google Scholar 

  88. M. Kalliat, P.W. Schmidt, D.H. Finseth, Fuel, 63, 1178 (1984).

    Article  CAS  Google Scholar 

  89. G.D. Cody, P. Thiyagarajan, R.E. Botto, J.E. Hunt, R.E. Winans, Energy & Fuels, 8, 1370 (1994).

    Article  CAS  Google Scholar 

  90. P. Thiyagarajan, G.D. Cody, J.E. Hunt, R.E. Winans, Prepr. Pap.-Am. Chem. Soc, Div. Fuel Chem., 40(3),397(1995).

    CAS  Google Scholar 

  91. G.D. Cody, M. Obeng, P. Thiyagarajan, Energy & Fuels, 11, 495 (1997).

    Article  CAS  Google Scholar 

  92. G.A. Carlson, Energy & Fuels, 6, 771 (1992).

    Article  CAS  Google Scholar 

  93. J.L. Faulon, K.A. P.G. Hatcher, G.A. Carlson, K.A. Wenzel, Fuel Process. Technol., 34, 277 (1993).

    Article  CAS  Google Scholar 

  94. M. Nomura, K. Matsubayashi, T. Ida, S. Murata, Fuel Process. Technol., 31, 169 (1992).

    Article  CAS  Google Scholar 

  95. T. Takanohashi, M. Iino, K. Nakamura, Energy & Fuels, 8, 395 (1994).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Chemical Reaction Science, Tohoku University, Katahira 2-1-1, Aoba-Ku Sendai, 980-77, Japan

    Masashi Iino & Toshimasa Takanohashi

Authors
  1. Masashi Iino
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Toshimasa Takanohashi
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Schlumberger-Doll Research, Ridgefield, Connecticut, USA

    Oliver C. Mullins

  2. Texaco, Inc., Beacon, New York, USA

    Eric Y. Sheu

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Science+Business Media New York

About this chapter

Cite this chapter

Iino, M., Takanohashi, T. (1998). Molecular and Colloidal Structure of Coal Asphaltenes and Other Heavy Solvent Soluble Components. In: Mullins, O.C., Sheu, E.Y. (eds) Structures and Dynamics of Asphaltenes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1615-0_6

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-1615-0_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-1617-4

  • Online ISBN: 978-1-4899-1615-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation