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Analytical Applications of Polymer-Modified Electrodes

  • Chapter
Electroactive Polymer Electrochemistry

Abstract

Before the advent of modified electrodes, electrochemistry was restricted by the range of electrode materials available and burdened with problems associated with the adsorption of a wide variety of compounds at their surfaces. In the early 1970s several groups realized that the deliberate modification of electrode surfaces could be used to tailor the electrode for specific applications. The pioneering work of Lane and Hubbard(1) on the modification of platinum electrodes with adsorbed unsaturated monomers was followed by the development of general schemes for the covalent attachment of monolayers to electrode surfaces via silanization reactions(2–4) or cyanuric chloride derivatization of electrodes.(5) For many applications it was realized that films thicker than monolayers would be beneficial. This led to the modification of electrodes with polymer films, first demonstrated by Miller’s group,(6,7) who prepared polymers containing such redox groups as quinones and nitroaromatics.

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Leech, D. (1996). Analytical Applications of Polymer-Modified Electrodes. In: Lyons, M.E.G. (eds) Electroactive Polymer Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1715-7_6

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