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Diffusion Path Networks in Oxides

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Kinetics of Reactions in Ionic Systems

Part of the book series: Materials Science Research ((MSR))

Abstract

An understanding of diffusion mechanisms in oxides, particularly cation diffusion, must take account of the various possible paths which an atom may follow in going from one normally occupied site to another equivalent site. Such paths may be branched and will likely include stops at metastable points along the way. This chapter describes methods whereby path networks within oxides can be characterized, and discusses diffusion in the structures NaCl, ZnS, FeS, and BeO.

Work performed under the auspices of the U.S. Atomic Energy Commission

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References

  1. R. H. Condit and C. E. Birchenall, “Self-Diffusion of Iron and Sulfur in Ferrous Sulfide,” Air Force Office of Scientific Research Technical Note 60–245, Contract No. AF 49(638)-533, Princeton University. Also University Microfilms, Ann Arbor, Michigan, L. C. Card No. Mic. 60–4974.

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  2. R. H. Condit and Y. Hashimoto, “Self-Diffusion of Beryllium in Polycrystalline Beryllium Oxide,” J. Am. Ceram. Soc. 50: 425–432 (1967).

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  3. R. H. Condit and D. N. Beshers, “Interstitial Diffusion in the B.C.C. Lattice,” Metal- lurg. Trans. AIME 239: 680–683 (1967).

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  4. L. Azaroff, J. Appl. Phys. 32: 1658–65 (1961).

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© 1969 Springer Science+Business Media New York

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Condit, R.H. (1969). Diffusion Path Networks in Oxides. In: Gray, T.J., Fréchette, V.D. (eds) Kinetics of Reactions in Ionic Systems. Materials Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6461-8_15

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  • DOI: https://doi.org/10.1007/978-1-4899-6461-8_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-6224-9

  • Online ISBN: 978-1-4899-6461-8

  • eBook Packages: Springer Book Archive

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