Abstract
The natural asphalts, of which Gilsonite is a representative, are modifiers used to increase the stiffness modulus of the asphalt concrete. For quality control purpose, recognizing if such material is present in the final blend is of an interest. The thin layer chromatography using a flame photometric detector (FPD), in addition to the typical flame ionization detector, was demonstrated hereby as a viable analytical tool for this problem. Gilsonite also contains the material soluble in solvent used in the development of the fraction referred to as aromatics. However, for straight run bitumen and Gilsonite the color of that fraction is different as well as their mobility. Due to the lower mobility of Gilsonite molecules on the stationary phase, the elution stops at different position than for fresh bitumen, convoluting the signal in the chromatogram region typically assigned for resins. The presence of Gilsonite is identifiable visually after the second development bath, but also with FPD from the final chromatogram.
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Change history
14 June 2019
The original version of the book was inadvertently published with incorrect information in chapter 38; the correction is given below. Page 243, text deleted in the fifth paragraph sixth line, ‘In the development, in so-called second bath, by nheptan/toluene (80:20% vol.)’ has been changed. Page 243, text added in the fifth paragraph sixth line, ‘In the development, in so-called second bath, by toluene/n-heptane (80:20% vol.)’ has been added. Page 244, text deleted in the third paragraph first line, ‘A series of 3 baths was prepared: (1) n-heptan – 30 min (9 cm), (2) nheptan/toluene (80:20% vol.)’ has been changed. Page 244, text added in the third paragraph first line, ‘A series of 3 baths was prepared: (1) n-heptan – 30 min (9 cm), (2) toluene/n-heptane (80:20% vol.)’ has been added.
References
Finnish Pavement Technology Advisory Council: Finnish Asphalt Specifications 2017. Premedia Helsinki Oy, Helsinki (2017)
Hansen, C.: Hansen Solubility Parameters - A user’s Handbook. CRC Press, Boca Raton, Fl (2007)
Higuerey, I., Orea, M., Pereira, P.: Estimation Of visbroken and selective catalytic steam cracked product stability using iatroscan TLC-FID. Fuel Chem. Div. Prepr. 47(2), 656–658 (2002)
Jiang, C., Larter, S., Noke, K., Snowdown, L.: TLC-FID (Iatroscan) analysis of heavy oil and tar sand samples. Org. Geochem. 39, 1210–1214 (2008)
Lehto, E.: Bitumin fraktiointi TLC/FID-menetelmällä [translation: Bitumen fractionation by TLC-FID method]. University of Oulu, Oulu (1988)
Lu, X., Kalman, B., Redelius, P.: A new test method for determination of wax content in crude oils, residues and bitumens. Fuel 87, 1543–1551 (2008)
Makowska, M., Hartikainen, A., Pellinen, T.: The oxidation of bitumen witnessed in-situ by infrared spectroscopy. Mater. Struct. 50, 189 (2017)
Masson, J.-F., Price, T., Collins, P.: Dynamics of bitumen fractions by thin-layer chromatography/flame ionization detection. Energy Fuels 15, 955–960 (2001)
McKenna, A.M., Marshall, A.G., Rodgers, R.P.: Heavy petroleum composition. 4. asphaltene compositional space. Energy Fuels 27, 1257–1267 (2013)
Ogasawa, M., Tsuruta, K., Arao, S.: Flame photometric detector for thin-layer chromatography. J. Chromatog. A 973(1–2), 151–158 (2002)
Paliukaite, M., Vaitkus, A., Zofka, A.: Evaluation of bitumen fractional composition depending on the crude oil type and production technology, Vilnus, Lithuania, 22–23 May 2014
Pellinen, T., Zofka, A., Marasteanu, M., Funk, N.: Asphalt mixture stiffness predictive models (with discussion). J. Assoc. Asphalt Paving Technol. From Proc. Tech. Sessions 76, 575–626 (2007)
Redelius, P.: Solubility parameters and bitumen. Fuel 79, 27–35 (2000)
Spangenberg, B., Poole, C., Weins, C.: Quantitative Thin-Layer Chromatography (A practical Survey). Springer, Berlin Heidelberg (2011)
Tabatabaee, H., Kurth, T.: Analytical investigation of the impact of a novel bio-based recycling agent on the colloidal stability of aged bitumen. Road Mater. Pavement Des. 18(sup2: EATA 2017), 131–140 (2017)
Teugels, W., Zwijsen, M.: Analysis of the generic composition. Appraisal of the Iatroskan method. Paper presented at the International Symposium Chemistry of Bitumens, Rome (1991)
Widyatmoko, I., Elliott, R.: Characteristics of elastomeric and plastomeric binders in contact with natural asphalts. Constr. Build. Mater. 22, 239–249 (2008)
Zofka, A., Maliszewska, D., Maliszewski, M., Boratynski, J.: Application of FTIR ATR method to examine the polymer content in the modified bitumen and to assess susceptibility of bitumen to ageing. Road Bridges 14, 163–174 (2015)
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Makowska, M., Pellinen, T. (2019). Qualitative Detection of the Presence of Gilsonite in the Bituminous Blends Based on Thin Layer Chromatography. In: Poulikakos, L., Cannone Falchetto, A., Wistuba, M., Hofko, B., Porot, L., Di Benedetto, H. (eds) RILEM 252-CMB Symposium. RILEM 252-CMB 2018. RILEM Bookseries, vol 20. Springer, Cham. https://doi.org/10.1007/978-3-030-00476-7_38
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DOI: https://doi.org/10.1007/978-3-030-00476-7_38
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